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Worksheets

CHM 101

Total questions: 62

Worksheet time: 34mins

Name
Class
Date
1.

A student observes that rubidium reacts explosively with water, but lithium fizzes gently. This difference is BEST explained by:

a)

Higher electronegativity of Li

b)

Larger atomic radius and lower ionization energy of Rb

c)

Rb having fewer valence electrons

d)

Li having a higher nuclear charge

2.

In a flame test lab, sodium emits bright yellow light, while potassium gives violet. The ease of electron excitation in K is due to:

a)

Higher ionization energy

b)

Greater shielding and larger atomic size

c)

Smaller atomic radius

d)

More protons in nucleus

3.

A chemist compares first ionization energies of Mg (738 kJ/mol) and Al (577 kJ/mol). The drop occurs because:

a)

Al has a stable 3s² configuration

b)

Mg’s 3s electrons are harder to remove than Al’s 3p¹

c)

Al has lower atomic mass

d)

Mg is a nonmetal

4.

Which atom would MOST readily form a 2+ ion in ionic compounds?

a)

F

b)

O

c)

Ca

d)

Cl

5.

In a semiconductor lab, an element with config [Ar]4s²3d¹⁰4p³ is used. Its electronegativity is expected to be:

a)

Higher than Ge, lower than Br

b)

Highest in Period 4

c)

Same as Ca

d)

Zero

6.

A student claims oxygen has higher first IE than nitrogen because it has more protons. This is:

a)

Correct

b)

Incorrect

c)

True only in compounds

d)

Depends on temperature

7.

Which process requires the LEAST energy?

a)

Removing 1st electron from He

b)

Removing 1st electron from Cs

c)

Removing 2nd electron from Mg

d)

Removing 3rd electron from Al

8.

During electrolysis, a technician needs an element that easily loses electrons to form cations. Best choice:

a)

F

b)

Ne

c)

K

d)

S

9.

An unknown element forms X³⁺ and has 3 valence electrons. It likely belongs to:

a)

Group 13

b)

Group 3

c)

Group 15

d)

d-block

10.

Why is atomic radius of Cl smaller than S?

a)

Cl has more electron shielding

b)

Cl has higher nuclear charge pulling electrons closer

c)

S has more protons

d)

Cl is a gas

11.

A student mixes 2.0 mol H₂ and 1.0 mol O₂ to make water. After reaction, gas remaining is:

a)

1.0 mol H₂

b)

0.5 mol O₂

c)

1.0 mol O₂

d)

No gas left

12.

In a car airbag, 2NaN₃ → 2Na + 3N₂. To produce 67.2 L N₂ at STP, mass of NaN₃ needed is:

a)

65 g

b)

130 g

c)

195 g

d)

39 g

13.

A lab prepares CO₂ using NaHCO₃ + HCl → NaCl + H₂O + CO₂. If 8.4 g NaHCO₃ (MM=84) is used, theoretical CO₂ is:

a)

2.2 g

b)

4.4 g

c)

1.1 g

d)

8.8 g

14.

A student uses 5.0 g Mg and 5.0 g O₂ to make MgO. Limiting reactant is:

a)

Mg

b)

O₂

c)

MgO

d)

Neither

15.

In 2Al + 3Cl₂ → 2AlCl₃, with 54 g Al and 213 g Cl₂, excess reactant mass left is:

a)

0 g

b)

71 g

c)

142 g

d)

35.5 g

16.

A pharmaceutical chemist synthesizes aspirin. Theoretical yield = 10.0 g, actual = 7.8 g. % yield is:

a)

22%

b)

78%

c)

87%

d)

128%

17.

Why might % yield exceed 100% in student labs?

a)

Perfect technique

b)

Wet or impure product

c)

Complete reaction

d)

Accurate weighing

18.

In rocket fuel: N₂H₄ + O₂ → N₂ + 2H₂O. 32 g N₂H₄ (MM=32) requires ___ g O₂.

a)

16

b)

32

c)

64

d)

8

19.

A student balances Cu + HNO₃ → Cu(NO₃)₂ + NO₂ + H₂O. Correct coefficients:

a)

1,4,1,2,2

b)

2,6,2,2,3

c)

1,6,1,4,3

d)

3,8,3,2,4

20.

In 4NH₃ + 5O₂ → 4NO + 6H₂O, 4 mol NH₃ produces ___ mol H₂O.

a)

4

b)

5

c)

6

d)

10

21.

A chemist notes that Be resists oxidation more than B. Reason:

a)

Be has lower IE

b)

Be has stable 2s² configuration

c)

B is a metal

d)

Be has larger radius

22.

Across Period 2, which property increases NON-uniformly due to electron repulsion?

a)

Atomic radius

b)

First ionization energy

c)

Metallic character

d)

Shielding

23.

Which pair violates periodic EN trend?

a)

EN: Li < Be

b)

EN: B < C

c)

EN: N < O

d)

EN: F > O

24.

A student measures atomic radii: Ca > Mg > Be. This illustrates:

a)

Period trend

b)

Group trend

c)

d-block contraction

d)

Anomaly

25.

An element with high IE, high EN, and small radius is likely a:

a)

Alkali metal

b)

Halogen

c)

Noble gas

d)

Alkaline earth

26.

In NH₃ synthesis, excess N₂ is used to:

4 lines
27.

th high IE, high EN, and small radius is likely a:

a)

Alkali metal

b)

Halogen

c)

Noble gas

d)

Alkaline earth

28.

In NH₃ synthesis, excess N₂ is used to:

a)

Increase % yield of NH₃

b)

Make H₂ limiting

c)

Reduce cost

d)

Speed up reaction

29.

A student recovers 3.2 g Cu from 4.0 g CuO using H₂. % yield is: (MM Cu=64, CuO=80)

a)

80%

b)

100%

c)

64%

d)

50%

30.

Which reaction has 1:1 mole ratio of reactants?

a)

H₂ + Cl₂ → 2HCl

b)

2H₂ + O₂ → 2H₂O

c)

N₂ + 3H₂ → 2NH₃

d)

C + O₂ → CO₂

31.

A technician uses 10 g CaCO₃ to produce CO₂. Max CO₂ (g) is: (MM CaCO₃=100)

a)

2.2

b)

4.4

c)

1.1

d)

8.8

32.

In 2KClO₃ → 2KCl + 3O₂, 245 g KClO₃ (MM=122.5) gives ___ L O₂ at STP.

a)

22.4

b)

33.6

c)

67.2

d)

44.8

33.

Which ion is smaller than its parent atom?

a)

O²⁻

b)

F⁻

c)

Na⁺

d)

Cl⁻

34.

Why does He have higher IE than H?

a)

More protons, same shell

b)

Larger size

c)

Shielding

d)

It’s a gas

35.

EN of Si is ~1.8, P is ~2.1. This supports:

a)

EN decreases across period

b)

EN increases across period

c)

EN constant in p-block

d)

No trend

36.

An element with config [Kr]5s²4d¹⁰5p³ is in:

a)

Period 5, Group 15

b)

Period 4, Group 13

c)

d-block

d)

f-block

37.

A student uses 6.9 g Na and 7.1 g Cl₂. Limiting reactant? (MM Na=23, Cl₂=71)

a)

Na

b)

Cl₂

c)

Neither

d)

Both

38.

Theoretical yield = 50 g, actual = 45 g. % yield =

a)

5%

b)

10%

c)

90%

d)

111%

39.

In C + O₂ → CO₂, 12 g C requires ___ g O₂.

a)

16

b)

32

c)

8

d)

64

40.

Which requires balancing by fractional coefficients?

a)

H₂ + O₂ → H₂O

b)

CH₄ + O₂ → CO₂ + H₂O

c)

Both

d)

Neither

41.

Mass of Al to produce 3.36 L H₂ at STP (2Al + 6HCl → 2AlCl₃ + 3H₂):

a)

2.7 g

b)

5.4 g

c)

1.35 g

d)

4.05 g

42.

2.0 mol Fe reacts with 2.0 mol Cl₂ → FeCl₃. Product moles =

a)

1.33

b)

2.0

c)

3.0

d)

1.0

43.

Down Group 17, reactivity decreases because:

a)

EN and IE decrease

b)

Atomic size increases, harder to gain e⁻

c)

Shielding decreases

d)

Nuclear charge drops

44.

Which oxide gives alkaline solution in water?

a)

CO₂

b)

SO₃

c)

Na₂O

d)

P₄O₁₀

45.

A sudden jump in IE after 3rd removal suggests:

a)

Group 3

b)

Group 13

c)

Group 2

d)

Group 15

46.

In Fe₂O₃ + 3CO → 2Fe + 3CO₂, 160 g Fe₂O₃ produces ___ g Fe.

a)

56

b)

112

c)

224

d)

28

47.

Actual yield < theoretical due to:

a)

Side reaction forming Fe₃O₄

b)

Incomplete reduction

c)

Gas escape

d)

All

48.

Which has highest IE in Period 2?

a)

Li

b)

C

c)

N

d)

Ne

49.

EN difference >1.7 usually indicates:

a)

Covalent bond

b)

Polar covalent

c)

Ionic bond

d)

Metallic bond

50.

Why is Ar’s atomic radius larger than Cl’s?

a)

Ar has more protons

b)

Cl has higher EN

c)

Ar’s radius is van der Waals (non-bonded)

d)

Cl is diatomic

51.

In Ba + Cl₂ → BaCl₂, 137 g Ba + 71 g Cl₂ → product mass =

a)

208 g

b)

137 g

c)

71 g

d)

279 g

52.

A student gets 8.5 g MgO from 4.8 g Mg. % yield? (MM Mg=24, MgO=40)

a)

85%

b)

100%

c)

50%

d)

75%

53.

Which element would least likely form an anion?

a)

I

b)

O

c)

K

d)

S

54.

In combustion of ethanol: C₂H₅OH + 3O₂ → 2CO₂ + 3H₂O. 46 g ethanol gives ___ g H₂O.

a)

18

b)

36

c)

54

d)

72

55.

Atomic radius trend explains why:

a)

Cs is more reactive than Li

b)

F is less reactive than I

c)

Mg has higher IE than Na

d)

All

56.

Which is NOT a periodic property?

a)

Density

b)

IE

c)

EN

d)

Atomic radius

57.

In 2H₂S + 3O₂ → 2SO₂ + 2H₂O, 34 g H₂S (MM=34) requires ___ g O₂.

a)

32

b)

48

c)

96

d)

64

58.

A student calculates 10 g product, gets 12 g. Likely error:

a)

Product not dry

b)

Spillage

c)

Incomplete reaction

d)

Wrong molar mass

59.

Why is O²⁻ larger than F⁻?

a)

O²⁻ has more protons

b)

O²⁻ has greater electron-electron repulsion

c)

F⁻ is covalent

d)

O is smaller atom

60.

In Zn + 2HCl → ZnCl₂ + H₂, 6.5 g Zn (MM=65) gives ___ L H₂ at STP.

a)

1.12

b)

2.24

c)

3.36

d)

4.48

61.

Which has lowest EN?

a)

F

b)

O

c)

C

d)

Cs

62.

A sudden drop in IE between Group 2 and 13 is due to:

a)

s→p orbital transition

b)

Increased nuclear charge

c)

Smaller size of Group 13

d)

Shielding decrease