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AP Chem 6.1, 6.2 Review

Total questions: 24

Worksheet time: 34mins

Name
Class
Date
1.

In a system, 60 Joules of heat are absorbed by the system, while the system does 50 Joules of work. Use ΔE=q+w\Delta E = q + w to calculate the total internal energy change of this system.

+q  A system gains heat  

-q  A system loses heat

+w Work is done on the system

-w  Work is done by the system

a)

1010 J

b)

10-10 J

c)

110110 J

d)

110-110 J

2.

A system releases 100 Joules of heat, while 70 Joules of work are done on the system. Use ΔE=q+w\Delta E = q + w to calculate the total internal energy change of this system.

+q  A system gains heat  

-q  A system loses heat

+w Work is done on the system

-w  Work is done by the system

a)

3030 J

b)

30-30 J

c)

170170 J

d)

170-170 J

3.

During formation of chemical bonds energy is __________.

a)

released

b)

absorbed

c)

conserved without change

d)

converted entirely to work

4.

The breaking of chemical bonds is a(n) __________ process.

a)

exothermic

b)

endothermic

c)

isothermal

d)

adiabatic

5.

Stretching a rubber band until it breaks is a(n) __________ process.

a)

endothermic

b)

exothermic

c)

isothermal

d)

adiabatic

6.

Releasing a stretched rubber band is a(n) __________ process.

a)

endothermic

b)

exothermic

c)

isothermal

d)

adiabatic

7.

Select all steps that are endothermic in the process table:

Hint: Which steps require an input of energy?

Process 1: Na(s) → Na(g)

Process 2: Na(g) → Na⁺(g) + e⁻

Process 3: F₂(g) → 2F(g)

Process 4: F(g) + e⁻ → F⁻(g).

a)

Process 1: Na(s) → Na(g)

b)

Process 2: Na(g) → Na⁺(g) + e⁻

c)

Process 3: F₂(g) → 2F(g)

d)

Process 4: F(g) + e⁻ → F⁻(g)

8.

In which direction does thermal energy (heat) travel in the reaction-energy diagram showing products at lower potential energy than reactants?

Hint: The system is the reaction. The surroundings are anything outside of the reaction such as a beaker or the air.

a)

from the surrounds to the system

b)

from the system to the surroundings

c)

heat does not travel

9.

An experiment was performed in an insulated container and the temperature increased inside the container. Which diagram demonstrates this experiment?

Option A shows an endothermic profile (products higher than reactants with an upward ΔH arrow).

Option B shows an exothermic profile (products lower than reactants with a downward ΔH arrow).

a)

A

b)

B

10.

In the spring, blossoms on cherry trees can be damaged when temperatures fall below -2°C. When the forecast calls for air temperatures to be below -5°C for a few hours one night, a farmer sprays his blossoming cherry trees with water, claiming that the blossoms will be protected by the water as it freezes. Which of the following is a correct scientific justification for spraying water on the blossoms to protect them from temperatures below -2°C?

a)

Water on the blossoms will not freeze unless the air temperature falls significantly below -5°C.

b)

Water is a good thermal conductor that transfers heat from the cold air to the blossoms, keeping the blossoms from going below -2°C.

c)

The freezing of water is an endothermic process; thus, water that freezes on the blossoms absorbs heat from the atmosphere, which in turn keeps the blossoms above 0°C.

d)

The freezing of water is an exothermic process; thus, water that freezes on the blossoms releases heat to keep the blossoms at or above -2°C.

11.
Which letter corresponds to the energy of the products?
a)
A
b)
B
c)
C
d)
D
12.
Which letter corresponds to the activation energy of the forward reaction?
a)
A
b)
B
c)
C
d)
D
13.

This reaction would be considered ......

a)

endothermic.

b)

exothermic.

14.

which is exothermic?

a)

temperature decreases

b)

breaking bonds

c)

system releasing heat to surroundings

d)

chemical reaction

15.

Energy is required to ________bonds.

a)

form

b)

break

16.
Is this reaction endothermic or exothermic?
a)
endothermic 
b)
exothermic
17.

What is the ΔH of this reaction?

a)

40 kJ

b)

20 kJ

c)

80 kJ

d)

-60 kJ

18.
What letter represents ΔH?
a)
A
b)
B
c)
C
d)
D
19.

What is the sign of ΔH for all endothermic reactions?

a)
Positive
b)
Negative
c)

zero

20.

What is the ΔH of this energy profile?

a)

-100 kJ

b)

+100 kJ

c)

+50 kJ

d)

-50 kJ

21.

What is the approximate ΔH for this energy profile?

a)

-100 kJ

b)

+800 kJ

c)

+400 kJ

d)

-75 kJ

22.
What is the activation energy?
a)

+100 kJ

b)

-175 kJ

c)

-50 kJ

d)

+75 kJ

23.

A chemical reaction that releases heat from the system to the surroundings.

a)

endothermic reaction

b)

exothermic reaction

c)

synthesis reaction

d)

decomposition

24.

What does it mean when a reaction has a high activation energy?

a)

the reaction is exothermic

b)

that reaction does not take place

c)

the reaction is fast

d)

the reaction is slow