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Leaving Certificate Chemistry: Families of Organic Compounds

Total questions: 80

Worksheet time: 56mins

Name
Class
Date
1.

A compound in which one or more of the hydrogen atoms in an alkane molecule have been replaced by halogen (Group VII) atoms.

(a)  

2.

The common name (as opposed to IUPAC name) for CHCl3.

(a)  

3.

The IUPAC name for CHCl3.

(a)  

4.

Name the compound CH3CH2CHClCH3.

(a)  

5.

Which compound has the higher boiling point?

A: CH2Cl2

B: CH3Cl

a)

A

b)

B

6.

In general, as the length of a carbon chain increases, do the number of van der Waals forces increase or decrease?

a)

Increase

b)

Decrease

7.

As the length of a carbon chain increases in a molecule, the strength of hydrogen bonding also increases. True or False?

a)

True

b)

False

8.

An atom or group of atoms responsible for the characteristic properties of an organic compound.

(a)  

9.

Which compound has the higher boiling point?

A: Methanol

B: Propanol

a)

Methanol

b)

Propanol

10.

Which intermolecular force is the strongest?

a)

van der Waals forces

b)

Hydrogen bonding

c)

London forces

d)

Dipole-dipole forces

11.

An alcohol where the carbon atom joined to the -OH group is bonded to only one other carbon atom.

a)

Primary alcohol

b)

Secondary alcohol

c)

Tertiary alcohol

d)

Quaternary alcohol

12.

An alcohol where the carbon atom joined to the -OH group is bonded to two other carbon atoms.

a)

Primary alcohol

b)

Secondary alcohol

c)

Tertiary alcohol

d)

Quaternary alcohol

13.

An alcohol where the carbon atom joined to the -OH group is bonded to three other carbon atoms.

a)

Primary alcohol

b)

Secondary alcohol

c)

Tertiary alcohol

d)

Quaternary alcohol

14.

Classify the alcohol:

Ethanol

a)

Primary alcohol

b)

Secondary alcohol

c)

Tertiary alcohol

d)

Quaternary alcohol

15.

Classify the alcohol:

Propan-2-ol

a)

Primary alcohol

b)

Secondary alcohol

c)

Tertiary alcohol

d)

Quaternary alcohol

16.

Classify the alcohol:

2-methylpropan-2-ol

a)

Primary alcohol

b)

Secondary alcohol

c)

Tertiary alcohol

d)

Quaternary alcohol

17.

Which of the following is an application of ethanol (an alcohol)?

a)

Fuel

b)

Solvent

c)

Making other solvents e.g. for making esters used in nail-polish reover

d)

All of these

18.

Classify the carbon chain in an alcohol as either polar or non-polar.

a)

Polar

b)

Non-polar

19.

Classify the -OH group in an alcohol as either polar or non-polar.

a)

Polar

b)

Non-polar

20.

Ethanol is soluble in water. True or False?

a)

True

b)

False

21.

Hexane is soluble in water. True or False?

a)

True

b)

False

22.

Classify the geometry, about the functional-group carbon atom, in alkanes.

a)

Planar

b)

Linear

c)

Tetrahedral

d)

Pyramidal

23.

Classify the geometry, about the functional-group carbon atom, in alkenes.

a)

Planar

b)

Linear

c)

Tetrahedral

d)

Pyramidal

24.

Classify the geometry, about the functional-group carbon atom, in alkynes.

a)

Planar

b)

Linear

c)

Tetrahedral

d)

Pyramidal

25.

Classify the geometry, about the functional-group carbon atom, in aldehydes.

a)

Planar

b)

Linear

c)

Tetrahedral

d)

Pyramidal

26.

Classify the geometry, about the functional-group carbon atom, in ketones.

a)

Planar

b)

Linear

c)

Tetrahedral

d)

Pyramidal

27.

Classify the geometry, about the functional-group carbon atom, in carboxylic acids.

a)

Planar

b)

Linear

c)

Tetrahedral

d)

Pyramidal

28.

Name the compound with formula: CH3CHO

a)

Ethanal

b)

Ethanol

c)

Ethanone

d)

Ethanoic acid

29.

Name the compound with formula: C3H7CHO

a)

Butanal

b)

Butanol

c)

Butanone

d)

Butanoic acid

30.

What type of intermolecular force is observed in aldehydes?

A: van der Waals forces

B: Hydrogen bonding

C: London forces

D: Dipole-dipole forces

a)

van der Waals forces

b)

Hydrogen bonding

c)

London forces

d)

Dipole-dipole forces

31.

What type of intermolecular force is observed in aldehydes?

a)

van der Waals forces

b)

Hydrogen bonding

c)

London forces

d)

Dipole-dipole forces

32.

Compounds with the same molecular formaula but different structural formula are known as structural (a)   .

33.

What is the bond angle, about the functional-group carbon atom, in carboxylic acids?

a)

90o

b)

120o

c)

109.5o

d)

107o

34.

Which of the following compounds represents the compound with the formula C3H7COOH?

a)

Ethanoic acid

b)

Propanoic acid

c)

Butanoic acid

d)

Methanoic acid

35.

The name of the carboxylic acid injected by ants when they bite.

a)

Ethanoic acid

b)

Propanoic acid

c)

Butanoic acid

d)

Methanoic acid

36.

The name of the aromatic compound with formula C6H5COOH. Applications of this compound include food preservatives and antiseptic medicines.

(a)  

37.

The ester functional group contains one oxygen atom. True or False?

a)

True

b)

False

38.

The ketone functional group contains two oxygen atoms. True or False?

a)

True

b)

False

39.

The aldehyde functional group contains two oxygen atoms. True or False?

a)

True

b)

False

40.

The aldehyde functional group contains one oxygen atom. True or False?

a)

True

b)

False

41.

The ketone functional group contains one oxygen atom. True or False?

a)

True

b)

False

42.

Identify the functional group shown.

a)

Alkane

b)

Alkene

c)

Alkyne

d)

Alcohol

43.

Identify the functional group shown.

a)

Alkane

b)

Alkene

c)

Alkyne

d)

Alcohol

44.

Identify the functional group shown.

a)

Alkane

b)

Alkene

c)

Alkyne

d)

Alcohol

45.

Identify the functional group shown.

a)

Ketone

b)

Ester

c)

Aldehyde

d)

Alcohol

46.

Identify the functional group shown.

a)

Ketone

b)

Ester

c)

Carboxylic acid

d)

Alcohol

47.

Identify the functional group shown.

a)

Ketone

b)

Ester

c)

Carboxylic acid

d)

Alcohol

48.

Identify the functional group shown.

a)

Ketone

b)

Ester

c)

Carboxylic acid

d)

Aldehyde

49.

Identify the functional group shown.

a)

Ketone

b)

Ester

c)

Carboxylic acid

d)

Aldehyde

50.

Identify the functional group shown.

(a)  

51.

Identify the functional group shown.

(a)  

52.

Identify the functional group shown.

(a)  

53.

Identify the functional group shown.

(a)  

54.

Identify the functional group shown.

(a)  

55.

Identify the functional group shown.

(a)  

56.

Identify the functional group shown.

(a)  

57.

Identify the functional group shown.

(a)  

58.

A (a)   reaction is a chemical reaction in which two molecules combine to form a larger molecule with the loss of a smaller molecule such as water.

59.

Which of the following is the general formula for the alkanes?

a)

CnH2n+2

b)

CnH2n

c)

CnH2n-2

d)

CnHn+2

60.

Which of the following is the general formula for the alkenes?

a)

CnH2n+2

b)

CnH2n

c)

CnH2n-2

d)

CnHn+2

61.

Which of the following is the general formula for the alkynes?

a)

CnH2n+2

b)

CnH2n

c)

CnH2n-2

d)

CnHn+2

62.

In an esterification reaction, the water is formed...

a)

From the OH of the acid combining with the H of the alcohol O-H

b)

From the H of the acid combining with the OH of the alcohol O-H

c)

From the OH of the acid combining with the OH of the alcohol O-H

d)

From the COOH of the acid combining with the OH of the alcohol O-H

63.

Give the IUPAC name for the ester formed from the following carboxylic acid-alcohol combinations:

methanol and methanoic acid

Remember: ester names comprise 2 separate words.

(a)  

64.

Give the IUPAC name for the ester formed from the following carboxylic acid-alcohol combinations:

methanol and ethanoic acid

Remember: ester names comprise 2 separate words.

(a)  

65.

Give the IUPAC name for the ester formed from the following carboxylic acid-alcohol combinations:

propanol and ethanoic acid

Remember: ester names comprise 2 separate words.

(a)  

66.

Give the IUPAC name for the ester formed from the following carboxylic acid-alcohol combinations:

propanol and propanoic acid

Remember: ester names comprise 2 separate words.

(a)  

67.

Give the IUPAC name for the ester formed from the following carboxylic acid-alcohol combinations:

methanol and propanoic acid

Remember: ester names comprise 2 separate words.

(a)  

68.

Give the IUPAC name for the ester formed from the following carboxylic acid-alcohol combinations:

propanol and methanoic acid

Remember: ester names comprise 2 separate words.

(a)  

69.

Give the IUPAC name for the ester formed from the following carboxylic acid-alcohol combinations:

ethanol and ethanoic acid

Remember: ester names comprise 2 separate words.

(a)  

70.

The pi electrons in benzene are said to be (a)   .

Note: one word answer

71.

What type of orbitals contain the pi electrons in benzene?

a)

s-orbitals

b)

p-orbitals

c)

d-orbitals

d)

f-orbitals

72.

All of the following compounds are classified as (a)   compounds:

DDT, Naphthalene, Benzene, Aspirin, Ibuprofen, Salbutamol, Paracetamol, Vanillin, Toluene etc.

Note: one-word answer

73.

In benzene, the delocalised electrons afford the benzene molecule extra (a)   .

74.

___________ __________ is a separation process used to isolate compounds at temperatures below their decomposition temperatures.

(a)  

75.

(a)   liquids are liquids that do not mix with each other.

76.

(a)   are dispersions of oil droplets of one liquid in another liquid in which it is not soluble.

77.

(a)   is the main constituent of oil of cloves.

78.

A (a)   funnel is used to separate the organic layer from the aqueous (inorganic) layer in liquid-liquid (solvent) extraction.

79.

Following solvent extraction, in organic synthesis, a compound such as magnesium sulfate is added to the organic layer. Magnesium sulfate acts as a ________ ________.

(a)  

80.

Solubility of alcohols, aldehydes, ketones and esters (in water) decreases as the length of the carbon chain...

a)

Increases

b)

Decreases