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WorksheetsIB Spectroscopic Identificatinon
Total questions: 20
Worksheet time: 9mins
Calculate the index of hydrogen deficiency for a compound with the molecular formula C6H6O.
1
2
3
4
Deduce the index of hydrogen deficiency of ethylamine, C2H5NH2.
0
1
2
3
Cholesterol has the molecular formula C27H46O.
What is the index of hydrogen deficiency of cholesterol?
3
6
4
5
Retinal has the molecular formula C20H28O. It contains five C=C double bonds and one C=O bond. How many rings does retinal possess?
1
2
3
4
A hydrocarbon contains 85.7% carbon by mass. Its 1H NMR spectrum shows two signals in the ratio of 3:1.
Which compound is consistent with this data?
but-1-ene
2-methylprop-1-ene
propane
propene
What information can be obtained from the number of peaks in the H NMR spectrum of a compound?
The number of different chemical environments occupied by the protons in one molecule of the compound.
The number of hydrogen atoms in one molecule of the compound.
The number of different functional groups in one molecule of the compound
the number of carbon atoms in one molecule of the compound
Which region of the electromagnetic spectrum has the longest wavelength?
ultraviolet
infrared
radio
visible
It is used to identify the bonds in a molecule.
Infrared spectroscopy
mass spectroscopy
x ray crystallography
NMR
It is used to determine relative atomic and molecular masses.
infrared spectroscopy
mass spectroscopy
NMR
index of hydrogen deficiency
In a mass spectrum, the fragment with the highest mass belongs to _________.
electron
molecule
anion
molecular ion
Its fragment has a mass of 15.
OH-
H2O
COOH-
CH3+
Which of the following can be absorbed by certain nuclei, causing them to reverse their spin?
microwaves
infrared radiation
radio waves
x rays
This causes molecules to increase their rotational energy which gives information about bond lengths.
radio waves
microwaves
infrared radiation
X rays
It causes a bond to stretch or bend.
radio waves
microwaves
infrared radiation
X rays
This technique gives information about the functional groups present in the compound.
Mass spectroscopy
Infrared radiation
proton nuclear magnetic resonance
index of hydrogen deficiency
Identify the bonds which will produce strong absorptions in the IR region of the electromagnetic spectrum.
I. C - O bond
II. C = C bond
III. C = O bond
I and II only
I and III only
II and III only
all of the above
The nucleus which is lined up with its magnetic field against the external magnetic field has a lower energy spin state.
True
False
Hydrogen nuclei in different chemical environments have different chemical shifts.
True
False
It is the standard used in nuclear magnetic resonance spectroscopy.
methyl propane
tetramethylsilane
benzene
sulfuric acid
The H NMR spectrum of a compound exhibits three major peaks and the splitting patterns below.
Chemical shift/ppm Peak area
1.0 -------- 3
2.0 -------- 3
2.3 -------- 2
CH3CH2CH3
CH3CH2CHO
CH3CH2COCH3
CH3CH2CH2CH2CH3
