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IB Spectroscopic Identificatinon

Total questions: 20

Worksheet time: 9mins

Name
Class
Date
1.

Calculate the index of hydrogen deficiency for a compound with the molecular formula C6H6O.

a)

1

b)

2

c)

3

d)

4

2.

Deduce the index of hydrogen deficiency of ethylamine, C2H5NH2.

a)

0

b)

1

c)

2

d)

3

3.

Cholesterol has the molecular formula C27H46O.

What is the index of hydrogen deficiency of cholesterol?

a)

3

b)

6

c)

4

d)

5

4.

Retinal has the molecular formula C20H28O. It contains five C=C double bonds and one C=O bond. How many rings does retinal possess?

a)

1

b)

2

c)

3

d)

4

5.

A hydrocarbon contains 85.7% carbon by mass. Its 1H NMR spectrum shows two signals in the ratio of 3:1.

Which compound is consistent with this data?

a)

but-1-ene

b)

2-methylprop-1-ene

c)

propane

d)

propene

6.

What information can be obtained from the number of peaks in the H NMR spectrum of a compound?

a)

The number of different chemical environments occupied by the protons in one molecule of the compound.

b)

The number of hydrogen atoms in one molecule of the compound.

c)

The number of different functional groups in one molecule of the compound

d)

the number of carbon atoms in one molecule of the compound

7.

Which region of the electromagnetic spectrum has the longest wavelength?

a)

ultraviolet

b)

infrared

c)

radio

d)

visible

8.

It is used to identify the bonds in a molecule.

a)

Infrared spectroscopy

b)

mass spectroscopy

c)

x ray crystallography

d)

NMR

9.

It is used to determine relative atomic and molecular masses.

a)

infrared spectroscopy

b)

mass spectroscopy

c)

NMR

d)

index of hydrogen deficiency

10.

In a mass spectrum, the fragment with the highest mass belongs to _________.

a)

electron

b)

molecule

c)

anion

d)

molecular ion

11.

Its fragment has a mass of 15.

a)

OH-

b)

H2O

c)

COOH-

d)

CH3+

12.

Which of the following can be absorbed by certain nuclei, causing them to reverse their spin?

a)

microwaves

b)

infrared radiation

c)

radio waves

d)

x rays

13.

This causes molecules to increase their rotational energy which gives information about bond lengths.

a)

radio waves

b)

microwaves

c)

infrared radiation

d)

X rays

14.

It causes a bond to stretch or bend.

a)

radio waves

b)

microwaves

c)

infrared radiation

d)

X rays

15.

This technique gives information about the functional groups present in the compound.

a)

Mass spectroscopy

b)

Infrared radiation

c)

proton nuclear magnetic resonance

d)

index of hydrogen deficiency

16.

Identify the bonds which will produce strong absorptions in the IR region of the electromagnetic spectrum.

I. C - O bond

II. C = C bond

III. C = O bond

a)

I and II only

b)

I and III only

c)

II and III only

d)

all of the above

17.

The nucleus which is lined up with its magnetic field against the external magnetic field has a lower energy spin state.

a)

True

b)

False

18.

Hydrogen nuclei in different chemical environments have different chemical shifts.

a)

True

b)

False

19.

It is the standard used in nuclear magnetic resonance spectroscopy.

a)

methyl propane

b)

tetramethylsilane

c)

benzene

d)

sulfuric acid

20.

The H NMR spectrum of a compound exhibits three major peaks and the splitting patterns below.

Chemical shift/ppm Peak area
1.0         --------     3
2.0         --------     3
2.3         --------     2

a)

CH3CH2CH3

b)

CH3CH2CHO

c)

CH3CH2COCH3

d)

CH3CH2CH2CH2CH3