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Carbonyl Compounds

Total questions: 20

Worksheet time: 18mins

Name
Class
Date
1.
What is the name of this carbonyl compound?
a)
pentan-2-one
b)
hexan-5-one
c)
pentan-3-one
d)
hexan-2-one
2.

When reacted with a strong reducing agent, aldehydes turn into

a)

carboxylic acids

b)

ketones

c)

primary alcohols

d)

secondary alcohols

3.
Propanone is very soluble in water because
a)
it is non-polar
b)
it can form hydrogen bond with water molecule
c)
water is a polar solvent
d)
the dipole-dipole interactions are weak between propane and water
4.

Name this carbonyl compound according to IUPAC nomenclature:

a)

3-benzyl-3,3-methylbutanone

b)

3,3-dimethyl-4-phenylbutanone

c)

3-methyl-3-phenylbutan-2-one

d)

2-phenyl-3,3-dimethylbutan-2-one

5.

Which of the following alcohols can be oxidised to 2-methyl-3-pentanone?

a)

CH3CH2CH(OH)CH3

b)

CH3CH(OH)CH2CH2CH3

c)

(CH3)3CCH(OH)CH3

d)

(CH3)2CHCH(OH)CH2CH3

6.

Which reagent would you choose to convert 1-pentanol to pentanal?

a)

PCC in CH2Cl2

b)

K2Cr2O7 with aqueous H2SO4

c)

KMnO4 with aqueous H2SO4

d)

KOH, ethanol, reflux

7.

The following reaction scheme shows how propene can be prepared from propanal in two stages using reagents X and Y. Which of the following are the reagents X and Y?


X Y

CH3CH2CHO → CH3CH2CH2OH → H3CH=CH2

a)

X: LiAlH4 ; Y: KOH, ethanol, reflux

b)

X: NaBH4 ; Y: conc.H2SO4, heat

c)

X: dillute H2SO4 ; Y: conc.ethanol, reflux

d)

X: dillute H2SO4 ; Y: KOH, ethanol, reflux

8.

On heating compound X with acidified KMnO4, compound Y is obtained. Compound Y does not react with Fehling’s solution. X and Y are most likely to be,


Compound X Compound Y

a)

CH3COCH3 CH3COOH

b)

CH3CH(OH)CH3 CH3COCH3

c)

CH3CH2CH2OH CH3COCH3

d)

CH3CH2CH2OH CH3CH2CHO

9.

Which substance would test positively with 2,4-DNPH but negatively with Tollens’ reagent?

a)

Propanal

b)

Propanone

c)

Propanoic acid

d)

1-propanol

10.

Acetone reacts with HCN to form a cyanohydrin. It is an example of

a)

Electrophilic addition

b)

Electrophilic substituition

c)

Nucleophilic addition

d)

Nucleophilic substituition

11.

Carbonyl compounds CANNOT be synthesized through

a)

oxidation of primary alcohol

b)

oxidation of secondary alcohol

c)

oxidation of tertiary alcohol

12.

Which of the following is NOT a carbonyl compound?

a)
b)
c)
d)
13.

An organic compound forms a light yellow precipitate when reacted with alkaline excess iodine solution.

State the name of chemical test.

a)

Iodoform test

b)

Baeyer’s test

c)

Tollen’s test

d)

Brady’s test

14.

What is the positive observation for Brady’s test?

a)

brick red precipitate

b)

silver mirror precipitate

c)

light yellow precipitate

d)

yellow or orange precipitate

15.

Arrange the boiling point of the following compounds in increasing order.


Ethane, ethanol, ethanal

a)

Ethane<ethanal<ethanol

b)

Ethanol<ethanal<ethane

c)

Ethanal<ethanol<ethane

d)

Ethane<ethanol<ethanal

16.

Identify the product formed for the reaction of 4-methylcyclohexanone with HCN.

a)

b)

c)

d)

17.
Aldehyde reacts with Tollen's reagent forming:
a)
Yellow precipitate
b)
Brick-red precipitate
c)
Purple solution
d)
Silver mirror
18.

2-butanol heated with acidified KMnO4 solution produced

a)

butanone

b)

butanoic acid

c)

butene

d)

butane

19.
Which of the following groups can be classified as carbonyls?
a)
aldehydes
b)
ketones
c)
esters
d)
aldehydes and ketones
20.

Identify the correct structure for 4-amino-3-benzyl-2,2-dimethylpentanedial

a)

b)

c)

d)