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Topic 6 SL Chemistry Kinetics

Total questions: 43

Worksheet time: 3hrs 17mins

Name
Class
Date
1.

calcium carbonate is added to hydrochloric acid.

Which graph represents the production of carbon dioxide when excess calcium carbonate is added to the same volume of hydrochloric acid of double concentration?

a)

A

b)

B

c)

C

d)

D

2.

The graph shows the Maxwell–Boltzmann energy distribution curve for a given gas at a certain temperature.

a)

The maximum is higher and to the left of A.

b)

The maximum is higher and to the right of A.

c)

The maximum is lower and to the right of A.

d)

The maximum is lower and to the left of A.

3.

Which properties can be monitored to determine the rate of the reaction?

Fe (s) + CuSO4 (aq) → Cu (s) + FeSO4 (aq)

I. change in volume

II. change in temperature

III. change in colour

a)

I and II only

b)

I and III only

c)

II and III only

d)

I, II and III

4.

Which will increase the rate of reaction between calcium carbonate and hydrochloric acid?

I. an increase in temperature

II. an increase in concentration of hydrochloric acid

III. an increase in particle size of calcium carbonate

a)

I and II only

b)

I and III only

c)

II and III only

d)

I, II and III

5.

Which is the activation energy of the forward reaction?

a)

A

b)

B

c)

C

d)

D

6.

The same amount of two gases, X and Y, are in two identical containers at the same temperature. What is the difference between the gases?

a)

X has the higher molar mass.

b)

Y has the higher molar mass.

c)

X has the higher average kinetic energy.

d)

Y has the higher average kinetic energy.

7.

Several reactions of calcium carbonate with dilute hydrochloric acid are carried out at the same temperature.

CaCO3 (s) + 2HCl (aq) → CaCl2 (aq) + H2O (l) + CO2 (g)

Which reaction has the greatest rate?

a)

Concentration of HCl - HIGHER; Surface area of same mass of CaCO3 (s) - LARGER

b)

Concentration of HCl - LOWER; Surface area of same mass of CaCO3 (s) - SMALLER

c)

Concentration of HCl - LOWER; Surface area of same mass of CaCO3 (s) - LARGER

d)

Concentration of HCl - HIGHER; Surface area of same mass of CaCO3 (s) - SMALLER

8.

Which conditions are required for the reaction between two molecules?

I. a collision

II. E ≥ Ea

III. proper orientation

a)

I and II only

b)

I and III only

c)

II and III only

d)

I, II and III

9.

The dotted line represents the formation of oxygen, O2 (g), from the uncatalysed complete decomposition of hydrogen peroxide, H2O2 (aq). Which curve represents a catalysed reaction under the same conditions?

a)

A

b)

B

c)

C

d)

D

10.

What is the activation energy of the reverse reaction?

a)

A

b)

B

c)

C

d)

D

11.

Samples of sodium carbonate powder were reacted with separate samples of excess hydrochloric acid.

Na2CO3 (s) + 2HCl (aq) → CO2 (g) + 2NaCl (aq) + H2O (l)

Reaction I: 1.0 g Na2CO3 (s) added to 0.50 mol dm−3 HCl (aq)

Reaction II: 1.0 g Na2CO3 (s) added to 2.0 mol dm−3 HCl (aq)

What is the same for reactions I and II?

a)

Initial rate of reaction

b)

Total mass of CO2 produced

c)

Total reaction time

d)

Average rate of production of CO2

12.

What decreases the activation energy of a reaction?

a)

Increasing the temperature

b)

Adding a catalyst

c)

Adding more reactants

d)

Increasing collision frequency of reactants

13.

Which change increases the rate of formation of hydrogen when zinc reacts with excess hydrochloric acid, assuming all other conditions remain the same?

Zn(s) + 2HCl(aq) → ZnCl2(aq) + H2(g)

a)

Adding water to the hydrochloric acid

b)

Decreasing the temperature

c)

Increasing the volume of hydrochloric acid

d)

Decreasing the size of the zinc particles while keeping the total mass of zinc the same

14.

Which statements are correct?

I. The activation energy of a reaction is not affected by temperature.

II. A catalyst reduces the enthalpy change of a reaction.

III. Catalysts provide alternative reaction pathways.

a)

I and II only

b)

and III only

c)

II and III only

d)

I, II and III

15.

The potential energy profile for the reversible reaction, X + Y → Z is shown.

Which arrow represents the activation energy for the reverse reaction, Z → X + Y, with a catalyst?

a)

A

b)

B

c)

C

d)

D

16.

Which factors can affect the rate of reaction?

I. Particle size of solid reactant

II. Concentration of reacting solution

III. Pressure of reacting gas

a)

I and II only

b)

I and III only

c)

II and III only

d)

I, II and III

17.

The diagram shows the energy profile for a catalysed and uncatalysed reaction. Which represents the enthalpy change, ΔH, and the activation energy, Ea, for the catalysed reaction?

a)

ΔH = z. ; Ea = x + z

b)

ΔH = z ; Ea = z + y

c)

ΔH = -z ; Ea = x

d)

ΔH = z + x ; Ea = x

18.

Excess magnesium powder was added to a beaker containing hydrochloric acid, HCl (aq).

The mass of the beaker and its contents was recorded and plotted against time (line I). Which change could give line II?

a)

Doubling the mass of powdered Mg

b)

Using the same mass of Mg ribbon

c)

Increasing the temperature

d)

Using the same volume of more concentrated HCl

19.

Copper catalyses the reaction between zinc and dilute sulfuric acid.

Zn(s) + H2SO4(aq) → ZnSO4(aq) + H2(g)

Why does copper affect the reaction?

a)

Decreases the activation energy

b)

Increases the activation energy

c)

Increases the enthalpy change

d)

Decreases the enthalpy change

20.

100 cm3 of 10% hydrogen peroxide solution decomposes at 298 K to form water and oxygen.

H2O2(aq) → H2O(l) + O2(g)

The dotted line graph represents the volume of oxygen produced.

Which graph represents the decomposition of an equal volume of a 20% solution under the same conditions?

a)

A

b)

B

c)

C

d)

D

21.

CaCO3(s) + 2HCl(aq) → CaCl2(aq) + H2O(l) + CO2(g)

Which change does not increase the initial rate of reaction when CaCO3(s) is added to excess HCl(aq)?

a)

Decrease in the size of the CaCO3(s) particles

b)

Increase in the temperature of the reaction mixture

c)

Increase in the concentration of HCl(aq), keeping the same volume

d)

Increase in the volume of HCl(aq), keeping the same concentration

22.

For the reaction RP, which letter represents the activation energy for the catalysed reverse reaction?

a)

A

b)

B

c)

C

d)

D

23.

Which conditions must be met for a reaction to take place?

I. Reactants collide with sufficient energy.

II. Reactants collide with correct orientation.

III. Reactants must be in the same state.

a)

I and II only

b)

I and III only

c)

II and III only

d)

I, II and III

24.

Which experimental methods could be used to observe the progress of the following reaction?

Cr2O72-(aq) + 6I-(aq) + 14H+(aq) → 2Cr3+(aq) + 3I2(aq) + 7H2O(l)

I. Change in colour

II. Change in mass

III. Change in electrical conductivity

a)

I and II only

b)

I and III only

c)

II and III only

d)

I, II and III

25.

Graph 1 shows a plot of volume of CO2 (g) against time for the reaction of CaCO3 (s) with 1.00 moldm−3 HCl (aq). The acid is the limiting reagent and entirely covers the lumps of CaCO3 (s).

Which set of conditions is most likely to give the data plotted in graph 2 when the same mass of CaCO3 (s) is reacted with the same volume of HCl (aq) at the same temperature?

a)

Size of lumps - LARGER; Concentration of Acid mol/L - 1.00

b)

Size of lumps - SMALLER; Concentration of Acid mol/L - 0.05

c)

Size of lumps - SMALLER; Concentration of Acid mol/L - 1.00

d)

Size of lumps - LARGER; Concentration of Acid mol/L - 0.05

26.

Which variable is best to use when determining the rate of decomposition of hydrogen peroxide? 2H2O2 (l) 2H2O (l) + O2 (g)2H_2O_2\ \left(l\right)\rightarrow_{\ }2H_2O\ \left(l\right)\ +\ O_2\ \left(g\right)  

a)

Volume of solution

b)

Volume of gas

c)

pH of solution

d)

Conductivity of solution

27.

Which is a correct unit for expressing the rate of a reaction?

a)

mol dm-3 s-1

b)

mol dm-3 s

c)

mol s

d)

mol-1 dm3 s-1

28.

100cm3 of a 1.00 mol dm-3 solution of hydrochloric acid is added to 2.00 g of small pieces of calcium carbonate at 20 °C. The volume of carbon dioxide produced against time is plotted to give curve P. Which change will produce curve Q, given that calcium carbonate is always the limiting reagent?

a)

Increasing the volume of the hydrochloric acid to 200 cm3

b)

Increasing the mass of calcium carbonate to 4.00 g

c)

Increasing the concentration of the hydrochloric acid to 2.00 mol dm-3

d)

Replacing the 2.00 g of small pieces of calcium carbonate with 2.00 g of larger pieces of calcium carbonate

29.

Which quantity can be changed by the use of a catalyst?

a)

I and II only

b)

I and III only

c)

II and III only

d)

I, II and III

30.

Why does the rate of a reaction increase when the temperature is increased?

I. The activation energy decreases.

II. There are more particles with energy equal to or greater than the activation energy.

III. The frequency of collisions between particles increases.

a)

I and II only

b)

I and III only

c)

II and III only

d)

I, II and III

31.

The diagram represents the Maxwell‒Boltzmann energy distribution curve of the reactants for a chemical reaction with different activation energies, and .

What is the reason why the rate of the reaction with activation energy energy Ea2 is greater?

a)

More frequent collisions between the particles occur.

b)

More energetic collisions between the particles occur.

c)

A catalyst has been added.

d)

The temperature is higher.

32.

Which change increases the rate of a chemical reaction?

a)

Increasing the size of solid reactant particles

b)

Decreasing the concentration of aqueous reactants

c)

Increasing the surface area of a solid reactant

d)

Decreasing the pressure of gaseous reactants

33.

Which is not affected by an increase in temperature?

a)

Rate of reaction

b)

Collision frequency

c)

Collision geometry

d)

% of molecules with E ≥ Ea

34.

Which factors can increase the rate of a chemical reaction?

I. Increasing the pressure in gaseous reactions

II. Increasing the temperature in gaseous reactions

III. Increasing the particle size of a solid in a reaction

a)

I and II only

b)

I and III only

c)

II and III only

d)

I, II and III

35.

Which statement best describes and explains the effect of a catalyst on the rate of a chemical reaction?

a)

The rate increases because the frequency of collisions between particles increases.

b)

The rate increases because more colliding particles have the energy needed to react.

c)

The rate increases because the activation energy increases.

d)

The rate increases because more molecules are present.

36.

Which statements explain the increase in the rate of a reaction when the temperature is increased?

I. More particles have energy greater than the activation energy.

II. The frequency of collisions increases.

III. The activation energy decreases.

a)

I and II only

b)

I and III only

c)

II and III only

d)

I, II and III

37.

In which flask will the reaction between 2.0 g of magnesium carbonate and 25 cm3 1.0 mol dm–3 hydrochloric acid occur most rapidly?

a)

A

b)

B

c)

C

d)

D

38.

Which statement about the kinetic theory is not correct?

a)

The particles in ice vibrate about fixed points.

b)

The particles in steam have more energy than the particles in ice.

c)

All the particles in water have the same amount of energy at 298 K.

d)

Evaporation of water occurs at all temperatures between 273 K and 373 K when the atmospheric pressure is 101 kPa.

39.

Which changes increase the rate of the reaction below? C4H10 (g) + Cl2 (g)  →  C4H9Cl (l) + HCl (g)

I. Increase of pressure

II. Increase of temperature

III. Removal of HCl (g)

a)

I and II only

b)

I and III only

c)

II and III only

d)

I, II and III

40.

Which of the following can increase the rate of a chemical reaction?

I. Increasing the temperature

II. Adding a catalyst

III. Increasing the concentration of reactants

a)

I and II only

b)

I and III only

c)

II and III only

d)

I, II and III

41.

Hydrochloric acid is reacted with large pieces of calcium carbonate, the reaction is then repeated using calcium carbonate powder. How does this change affect the activation energy and the collision frequency?

a)

Activation energy - INCREASES ; Collision frequency - INCREASES

b)

Activation energy - STAYS CONSTANT ; Collision frequency - INCREASES

c)

Activation energy - INCREASES ; Collision frequency - STAYS CONSTANT

d)

Activation energy - STAYS CONSTANT ; Collision frequency - STAYS CONSTANT

42.

Which statement is true about using sulfuric acid as a catalyst in this reaction?

I. The catalyst increases the rate of reaction.

II. The catalyst lowers the activation energy for the reaction.

III. The catalyst has been consumed at the end of the chemical reaction.

a)

I and II only

b)

I and III only

c)

II and III only

d)

I, II and III

43.

What is the best definition of rate of reaction?

a)

The time it takes to use up all the reactants

b)

The rate at which all the reactants are used up

c)

The time it takes for one of the reactants to be used up

d)

The increase in concentration of a product per unit time