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WorksheetsTopic 6 SL Chemistry Kinetics
Total questions: 43
Worksheet time: 3hrs 17mins
calcium carbonate is added to hydrochloric acid.
Which graph represents the production of carbon dioxide when excess calcium carbonate is added to the same volume of hydrochloric acid of double concentration?
A
B
C
D
The graph shows the Maxwell–Boltzmann energy distribution curve for a given gas at a certain temperature.
The maximum is higher and to the left of A.
The maximum is higher and to the right of A.
The maximum is lower and to the right of A.
The maximum is lower and to the left of A.
Which properties can be monitored to determine the rate of the reaction?
Fe (s) + CuSO4 (aq) → Cu (s) + FeSO4 (aq)
I. change in volume
II. change in temperature
III. change in colour
I and II only
I and III only
II and III only
I, II and III
Which will increase the rate of reaction between calcium carbonate and hydrochloric acid?
I. an increase in temperature
II. an increase in concentration of hydrochloric acid
III. an increase in particle size of calcium carbonate
I and II only
I and III only
II and III only
I, II and III
Which is the activation energy of the forward reaction?
A
B
C
D
The same amount of two gases, X and Y, are in two identical containers at the same temperature. What is the difference between the gases?
X has the higher molar mass.
Y has the higher molar mass.
X has the higher average kinetic energy.
Y has the higher average kinetic energy.
Several reactions of calcium carbonate with dilute hydrochloric acid are carried out at the same temperature.
CaCO3 (s) + 2HCl (aq) → CaCl2 (aq) + H2O (l) + CO2 (g)
Which reaction has the greatest rate?
Concentration of HCl - HIGHER; Surface area of same mass of CaCO3 (s) - LARGER
Concentration of HCl - LOWER; Surface area of same mass of CaCO3 (s) - SMALLER
Concentration of HCl - LOWER; Surface area of same mass of CaCO3 (s) - LARGER
Concentration of HCl - HIGHER; Surface area of same mass of CaCO3 (s) - SMALLER
Which conditions are required for the reaction between two molecules?
I. a collision
II. E ≥ Ea
III. proper orientation
I and II only
I and III only
II and III only
I, II and III
The dotted line represents the formation of oxygen, O2 (g), from the uncatalysed complete decomposition of hydrogen peroxide, H2O2 (aq). Which curve represents a catalysed reaction under the same conditions?
A
B
C
D
What is the activation energy of the reverse reaction?
A
B
C
D
Samples of sodium carbonate powder were reacted with separate samples of excess hydrochloric acid.
Na2CO3 (s) + 2HCl (aq) → CO2 (g) + 2NaCl (aq) + H2O (l)
Reaction I: 1.0 g Na2CO3 (s) added to 0.50 mol dm−3 HCl (aq)
Reaction II: 1.0 g Na2CO3 (s) added to 2.0 mol dm−3 HCl (aq)
What is the same for reactions I and II?
Initial rate of reaction
Total mass of CO2 produced
Total reaction time
Average rate of production of CO2
What decreases the activation energy of a reaction?
Increasing the temperature
Adding a catalyst
Adding more reactants
Increasing collision frequency of reactants
Which change increases the rate of formation of hydrogen when zinc reacts with excess hydrochloric acid, assuming all other conditions remain the same?
Zn(s) + 2HCl(aq) → ZnCl2(aq) + H2(g)
Adding water to the hydrochloric acid
Decreasing the temperature
Increasing the volume of hydrochloric acid
Decreasing the size of the zinc particles while keeping the total mass of zinc the same
Which statements are correct?
I. The activation energy of a reaction is not affected by temperature.
II. A catalyst reduces the enthalpy change of a reaction.
III. Catalysts provide alternative reaction pathways.
I and II only
and III only
II and III only
I, II and III
The potential energy profile for the reversible reaction, X + Y → Z is shown.
Which arrow represents the activation energy for the reverse reaction, Z → X + Y, with a catalyst?
A
B
C
D
Which factors can affect the rate of reaction?
I. Particle size of solid reactant
II. Concentration of reacting solution
III. Pressure of reacting gas
I and II only
I and III only
II and III only
I, II and III
The diagram shows the energy profile for a catalysed and uncatalysed reaction. Which represents the enthalpy change, ΔH, and the activation energy, Ea, for the catalysed reaction?
ΔH = z. ; Ea = x + z
ΔH = z ; Ea = z + y
ΔH = -z ; Ea = x
ΔH = z + x ; Ea = x
Excess magnesium powder was added to a beaker containing hydrochloric acid, HCl (aq).
The mass of the beaker and its contents was recorded and plotted against time (line I). Which change could give line II?
Doubling the mass of powdered Mg
Using the same mass of Mg ribbon
Increasing the temperature
Using the same volume of more concentrated HCl
Copper catalyses the reaction between zinc and dilute sulfuric acid.
Zn(s) + H2SO4(aq) → ZnSO4(aq) + H2(g)
Why does copper affect the reaction?
Decreases the activation energy
Increases the activation energy
Increases the enthalpy change
Decreases the enthalpy change
100 cm3 of 10% hydrogen peroxide solution decomposes at 298 K to form water and oxygen.
H2O2(aq) → H2O(l) + O2(g)
The dotted line graph represents the volume of oxygen produced.
Which graph represents the decomposition of an equal volume of a 20% solution under the same conditions?
A
B
C
D
CaCO3(s) + 2HCl(aq) → CaCl2(aq) + H2O(l) + CO2(g)
Which change does not increase the initial rate of reaction when CaCO3(s) is added to excess HCl(aq)?
Decrease in the size of the CaCO3(s) particles
Increase in the temperature of the reaction mixture
Increase in the concentration of HCl(aq), keeping the same volume
Increase in the volume of HCl(aq), keeping the same concentration
For the reaction R → P, which letter represents the activation energy for the catalysed reverse reaction?
A
B
C
D
Which conditions must be met for a reaction to take place?
I. Reactants collide with sufficient energy.
II. Reactants collide with correct orientation.
III. Reactants must be in the same state.
I and II only
I and III only
II and III only
I, II and III
Which experimental methods could be used to observe the progress of the following reaction?
Cr2O72-(aq) + 6I-(aq) + 14H+(aq) → 2Cr3+(aq) + 3I2(aq) + 7H2O(l)
I. Change in colour
II. Change in mass
III. Change in electrical conductivity
I and II only
I and III only
II and III only
I, II and III
Graph 1 shows a plot of volume of CO2 (g) against time for the reaction of CaCO3 (s) with 1.00 moldm−3 HCl (aq). The acid is the limiting reagent and entirely covers the lumps of CaCO3 (s).
Which set of conditions is most likely to give the data plotted in graph 2 when the same mass of CaCO3 (s) is reacted with the same volume of HCl (aq) at the same temperature?
Size of lumps - LARGER; Concentration of Acid mol/L - 1.00
Size of lumps - SMALLER; Concentration of Acid mol/L - 0.05
Size of lumps - SMALLER; Concentration of Acid mol/L - 1.00
Size of lumps - LARGER; Concentration of Acid mol/L - 0.05
Which variable is best to use when determining the rate of decomposition of hydrogen peroxide? 2H2O2 (l)→ 2H2O (l) + O2 (g)
Volume of solution
Volume of gas
pH of solution
Conductivity of solution
Which is a correct unit for expressing the rate of a reaction?
mol dm-3 s-1
mol dm-3 s
mol s
mol-1 dm3 s-1
100cm3 of a 1.00 mol dm-3 solution of hydrochloric acid is added to 2.00 g of small pieces of calcium carbonate at 20 °C. The volume of carbon dioxide produced against time is plotted to give curve P. Which change will produce curve Q, given that calcium carbonate is always the limiting reagent?
Increasing the volume of the hydrochloric acid to 200 cm3
Increasing the mass of calcium carbonate to 4.00 g
Increasing the concentration of the hydrochloric acid to 2.00 mol dm-3
Replacing the 2.00 g of small pieces of calcium carbonate with 2.00 g of larger pieces of calcium carbonate
Which quantity can be changed by the use of a catalyst?
I and II only
I and III only
II and III only
I, II and III
Why does the rate of a reaction increase when the temperature is increased?
I. The activation energy decreases.
II. There are more particles with energy equal to or greater than the activation energy.
III. The frequency of collisions between particles increases.
I and II only
I and III only
II and III only
I, II and III
The diagram represents the Maxwell‒Boltzmann energy distribution curve of the reactants for a chemical reaction with different activation energies, and .
What is the reason why the rate of the reaction with activation energy energy Ea2 is greater?
More frequent collisions between the particles occur.
More energetic collisions between the particles occur.
A catalyst has been added.
The temperature is higher.
Which change increases the rate of a chemical reaction?
Increasing the size of solid reactant particles
Decreasing the concentration of aqueous reactants
Increasing the surface area of a solid reactant
Decreasing the pressure of gaseous reactants
Which is not affected by an increase in temperature?
Rate of reaction
Collision frequency
Collision geometry
% of molecules with E ≥ Ea
Which factors can increase the rate of a chemical reaction?
I. Increasing the pressure in gaseous reactions
II. Increasing the temperature in gaseous reactions
III. Increasing the particle size of a solid in a reaction
I and II only
I and III only
II and III only
I, II and III
Which statement best describes and explains the effect of a catalyst on the rate of a chemical reaction?
The rate increases because the frequency of collisions between particles increases.
The rate increases because more colliding particles have the energy needed to react.
The rate increases because the activation energy increases.
The rate increases because more molecules are present.
Which statements explain the increase in the rate of a reaction when the temperature is increased?
I. More particles have energy greater than the activation energy.
II. The frequency of collisions increases.
III. The activation energy decreases.
I and II only
I and III only
II and III only
I, II and III
In which flask will the reaction between 2.0 g of magnesium carbonate and 25 cm3 1.0 mol dm–3 hydrochloric acid occur most rapidly?
A
B
C
D
Which statement about the kinetic theory is not correct?
The particles in ice vibrate about fixed points.
The particles in steam have more energy than the particles in ice.
All the particles in water have the same amount of energy at 298 K.
Evaporation of water occurs at all temperatures between 273 K and 373 K when the atmospheric pressure is 101 kPa.
Which changes increase the rate of the reaction below? C4H10 (g) + Cl2 (g) → C4H9Cl (l) + HCl (g)
I. Increase of pressure
II. Increase of temperature
III. Removal of HCl (g)
I and II only
I and III only
II and III only
I, II and III
Which of the following can increase the rate of a chemical reaction?
I. Increasing the temperature
II. Adding a catalyst
III. Increasing the concentration of reactants
I and II only
I and III only
II and III only
I, II and III
Hydrochloric acid is reacted with large pieces of calcium carbonate, the reaction is then repeated using calcium carbonate powder. How does this change affect the activation energy and the collision frequency?
Activation energy - INCREASES ; Collision frequency - INCREASES
Activation energy - STAYS CONSTANT ; Collision frequency - INCREASES
Activation energy - INCREASES ; Collision frequency - STAYS CONSTANT
Activation energy - STAYS CONSTANT ; Collision frequency - STAYS CONSTANT
Which statement is true about using sulfuric acid as a catalyst in this reaction?
I. The catalyst increases the rate of reaction.
II. The catalyst lowers the activation energy for the reaction.
III. The catalyst has been consumed at the end of the chemical reaction.
I and II only
I and III only
II and III only
I, II and III
What is the best definition of rate of reaction?
The time it takes to use up all the reactants
The rate at which all the reactants are used up
The time it takes for one of the reactants to be used up
The increase in concentration of a product per unit time
