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Unit 12 Kinetics & Equilibrium

Total questions: 55

Worksheet time: 3hrs 56mins

Name
Class
Date
1.
Grinding a seltzer tablet into powder increases the rate of reaction due to increased
a)
concentration
b)
surface area
c)
temperature
d)
reactants
2.
Increasing the concentration increases the speed of reaction by
a)
lowering activation energy
b)
increasing collisions
c)
speeding up the reactants
d)
exposing more reactant
3.
Which of the following slows down the rate of a chemical reaction?
a)
Place the reactants in hot water
b)
Place the products in ice bath
c)
Place the reactants in a ice bath
d)
Keep stirring the reactants with a stirring rod
4.
The following graph shows two different reaction pathways for the same overall reaction at the same temperature. Which pathway is slower and why?
a)
Red, because the activation energy is larger
b)
Blue, because the activation energy is lower
c)
both reaction progress at the same rate
5.

Why does a higher concentration increase the rate of reaction?

a)

it increases the amount of reactants

b)

it lowers the activation energy

c)

it increases the energy of particle collisions

d)

it increases the frequency of particle collisions

6.
What makes an effective collision?
a)
When molecules collide.
b)
When molecules collide with the proper orientation.
c)
When molecules collide with proper orientation and enough kinetic energy.
d)
High Temperature.
7.

The minimum amount of energy needed for colliding particles to react is called

a)

Chemical Energy

b)

Kinetic Energy

c)

Activation Energy

d)

Potential Energy

8.
What type of reaction is this?
a)
Endothermic
b)
Exothermic
9.
What letter represents the activation energy?
a)
A
b)
B
c)
C
d)
D
10.
Is this reaction endothermic or exothermic?
a)
endothermic 
b)
exothermic
11.
What letter represents ΔH?
a)
A
b)
B
c)
C
d)
D
12.

What is the change of the heat of the reaction (ΔH)?

a)

-40 kJ

b)

-20 kJ

c)

100 kJ

d)

60 kJ

13.
What is the activation energy?
a)
100 kJ
b)
175 kJ
c)
50 kJ
d)
75 kJ
14.
This symbol indicates that a reaction is ____________
a)
reversible
b)
irreversible
15.
What are the two factors to look for when determining if the reaction is at equilibrium?
a)
Forward reaction rate is faster than the reverse and concentrations are equal
b)
Forward and reverse reaction rates are equal and concentration is conctant
c)
Forward and revers reaction rates are equal and concentration is equal
d)
Forward reaction rate is faster than the reverse and concentration is equal
16.

Identify the incorrect statement about achieving equilibrium.

a)

achieved when product and reactant concentrations are equal

b)

achieved when forward and reverse reaction rates are same

c)

achieved when concentration of reactants is stable/constant

d)

achieved when concentration ratio of reactants to products becomes stable, thus fixing the equilibrium constant (equilibrium position)

17.
At what time the reaction reached equilibrium?
a)
t1
b)
t2
c)
t3
d)
t4
18.
How do catalysts increase the rate of reaction?
a)
The frequency of collisions is the increased
b)
the activation energy is lowered
c)
the energy of collisions is increased
d)
Both the frequency and energy of collisions is increased
19.

Which of the following are true

a)

At t3, there are more reactants than products

b)

The equilibrium constant lies to the right

c)

At t3; the amount of reactants and products are equal

d)

At t2; the forward and reverse reaction rates are equal

e)

at t1, the forward reaction rate is slowing and the reverse reaction rate is increasing

20.

Which statement correctly describes an endothermic chemical reaction?

a)

The products have lower potential energy than the reactants, and the ΔH is positive

b)

The products have lower potential energy than the reactants, and the ΔH is negative

c)

The products have higher potential energy than the reactants, and the ΔH is positive

d)

The products have higher potential energy than the reactants, and the ΔH is negative

21.

Which balanced equation represents an endothermic reaction?

a)

N2(g) + 3H2(g) --> 2NH3(g)

b)

N2(g) + O2(g) --> 2NO(g)

c)

CH4(g) + 2O2(g) --> CO2(g) + 2H2O(l)

d)

C(s) + O2(g) --> CO2(g)

22.

A solution at equilibrium must be

a)

concentrated

b)

saturated

c)

unsaturated

d)

diluted

23.

Given the reaction


S(s) + O2(g) --> SO2(g) + energy


Which diagram best represents the potential energy changes for this reaction?

a)

a

b)

b

c)

c

d)

d

24.

The potential energy diagram below represents a reaction.


Which arrow represents the activation energy of the forward reaction

a)

A

b)

B

c)

C

d)

D

25.

Given the potential energy diagram for the chemical reaction:


Which statement correctly describes the energy changes that occur in the forward reaction

a)

The activation energy is 50kJ and the reaction is exothermic

b)

The activation energy is 50kJ and the reaction is endothermic

c)

The activation energy is 10kJ and the reaction is exothermic

d)

The activation energy is 10kJ and the reaction is endothermic

26.

The ______________is required to break the bonds of the reactants.

a)

Carbonic energy

b)

Activation energy

c)

Plutonic energy

d)

Energi Gaib

27.

Which of the following regarding an endothermic reaction is correct?

a)

Chemical energy is transformed to heat energy

b)

The temperature of the surroundings rises

c)

Heat is released

d)

The energy content of the product is higher than the energy content of the reactants

28.

Which symbol below represents the heat of reaction?

a)
b)
c)
d)
29.

When barium hydroxide is mixed with ammonium nitrate, 377 kJ of heat energy is absorbed by the system. What is the heat of reaction?

a)

+377 kJ

b)

-377 kJ

30.

When a quantity of methane gas is burned, 3822 kJ of energy is released. What is the heat of reaction?

a)

+3822 kJ

b)

-3822 kJ

31.

The amount of heat energy change in a reaction is called the _____

a)

bonding energy

b)

heat of reaction

c)

specific heat

d)

heat capacity

32.

To write the thermochemical equation for an endothermic reaction, where will you write the number for the heat of reaction?

a)

on the Product side

b)

on the Reactant side

33.

To write a thermochemical equation for an exothermic reaction, where will you write the number for the heat of reaction?

a)

on the Product side

b)

on the Reactant side

34.

Is this equation endothermic or exothermic?

a)

endothermic

b)

exothermic

35.

Is this reaction endothermic or exothermic?

a)

endothermic

b)

exothermic

36.

How does a catalyst work in speeding up a reaction?

a)

By lowering the activation energy or reaction

b)

by giving them more energy

c)

by making them more available

37.
What does NOT happen when the temperature is increased?
a)
Particles collide more often
b)
Particles collide with more energy
c)
Particles move faster
d)
More particles collide in the correct orientation
38.

Why does a higher concentration increase the rate of reaction?

a)

it increases the amount of reactants

b)

it lowers the activation energy

c)

it increases the energy of particle collisions

d)

it increases the frequency of particle collisions

39.

Why does a higher temperature increase the rate of a reaction?

a)

it increases both the frequency and energy of particle collisions

b)

it only increases the frequency of particle collisions

c)

it only increases the energy of particle collisions

d)

it reduces the activation energy of the reaction

40.
What makes an effective collision?
a)
When molecules collide.
b)
When molecules collide with the proper orientation.
c)
When molecules collide with proper orientation and enough kinetic energy.
d)
High Temperature.
41.
Located on the left side of the reaction
a)
reactants
b)
products
42.

How much energy is produced in the reaction between aluminum and oxygen as written on Table I

a)

-3351 kj

b)

-890.4 kj

c)

-6072 kj

d)

-2219.2 kj

43.

How much energy is produced in the combustion reaction of 2 mol CH3OH with O2 on Table I?

a)

-1452 kj

b)

-2904 kj

c)

-726 kJ

d)

-890.4 kj

44.

How much energy is produced in the combustion reaction of 1 mol C8H18 with 25 mol O2 on Table I?

a)

-10943 kJ

b)

-5471.5 kj

c)

-21886 kj

d)

-1452 kj

45.

How much energy is produced in the combustion reaction of 2 mol C8H18 with 25 mol O2 on Table I?

a)

-10943 kJ

b)

-5471.5 kj

c)

-21886 kj

d)

-1452 kj

46.

Based on Table I, which compound dissolves in water by an exothermic process?

a)

NaCl

b)

NaOH

c)

NH4Cl

d)

NH4NO3

47.
Le Chaltelier's Principle states that if a chemical system at equilibrium is stressed,
a)
the system will adjust to increase the stress
b)
the system will adjust to reduce the stress
c)
the system will not adjust
48.
For the reaction...
SO2(g) + O2(g) <−>  SO3(g)
If the concentration of 
SO2(g)  is increased, the equilibrium of the reaction will ___________.
a)
shift to the left
b)
shift to the right
c)
not shift
49.
For the reaction...
SO2(g) + O2(g) <−>  SO3(g)

If the equilibrium shifts to the right, the concentration of O2(g) will ___________.
a)
increase
b)
decrease
c)
remain the same
50.
For the reaction...
energy +  N2(g)  +  O2(g)  <−>  2NO(g)
If  O2(g) is removed, the  concentration of N2 will _______.
a)
increase
b)
decrease
c)
remain the same
d)
double
51.
A +  B <--> C + D   ΔH= 151kJ
Rewrite the above equation with energy as a reactant or product:
a)
A +  B <--> C + D + energy
b)
A +  B + energy <--> C + D 
52.
For the reaction...
heat  +  N2(g)  +  O2(g)  <−>  2NO(g)
If the heat is removed to the chemical system, the equilibrium will _______.
a)
shift to the left
b)
shift to the right
c)
not shift
53.
For the reaction...
N2 (g) +  3 H2 (g) <−> 2 NH3 (g)

If the pressure in the system is increased, the reaction will __________________.
a)
 shift to the left
b)
shift to the right
c)
not shift
54.
When  ΔH  is negative it represents a(n)
a)
exothermic reaction 
b)
endothermic reaction 
55.
What would happen to the position of the equilibrium when Oxygen is added to the system?
 2SO3(g) 2SO2(g) + O2(g) 
a)
SOwill increase 
b)
SO3 will decrease 
c)
SO2 will increase
d)
none of the above