WorksheetsCarbonyl compounds
Total questions: 30
Worksheet time: 3600secs
Which of the following alcohols can be oxidised to 2-methyl-3-pentanone?
CH3CH2CH(OH)CH3
CH3CH(OH)CH2CH2CH3
(CH3)3CCH(OH)CH3
(CH3)2CHCH(OH)CH2CH3
The following reaction scheme shows how propene can be prepared from propanal in two stages using reagents X and Y. Which of the following are the reagents X and Y?
X Y
CH3CH2CHO → CH3CH2CH2OH → H3CH=CH2
X: LiAlH4 ; Y: KOH, ethanol, reflux
X: NaBH4 ; Y: conc.H2SO4, heat
X: dillute H2SO4 ; Y: conc.ethanol, reflux
X: dillute H2SO4 ; Y: KOH, ethanol, reflux
On heating compound X with acidified KMnO4, compound Y is obtained. Compound Y does not react with Fehling’s solution. X and Y are most likely to be,
Compound X Compound Y
CH3COCH3 CH3COOH
CH3CH(OH)CH3 CH3COCH3
CH3CH2CH2OH CH3COCH3
CH3CH2CH2OH CH3CH2CHO
Acetone reacts with HCN to form a cyanohydrin. It is an example of
Electrophilic addition
Electrophilic substituition
Nucleophilic addition
Nucleophilic substituition
Which reagent would you choose to convert 1-pentanol to pentanal?
PCC in CH2Cl2
K2Cr2O7 with aqueous H2SO4
KMnO4 with aqueous H2SO4
KOH, ethanol, reflux
When aldehyde is heated with Fehling's solution, it gives a precipitate of
Cu2O
CuO
Cu2O & CuO
Cu
1. Iodoform test: Yellow precipitate
2. Tollens' test: No observable change
3. 2,4-DNPH: yellow precipitate
Which compound will have the above observations?
CH3CH2CHO
C6H5CHO
CH3CH2COCH3
CH3COOH
Which statement about butanone is correct?
Butanone reacts to form silver mirror with Tollen's Reagent
Butanone can be prepared by reduction of 1-butanol
Butanone forms brick red precipitate with Fehling’s solution
Butanone's C=O bond is polar with O δ–
Choose a suitable reagent that can be used to prepare 3-methylpentan-3-ol from butanone.
A. CH3MgBr
B. CH3CH2MgBr
C. CH3CH2CH2MgBr
D. CH3CH2CH(CH3)MgBr
A germinal diol is produced when a ketone is added to
A. H2O
B. OH-
C. CH3OH
D. CH3CHO
What is the functional group are present in PARACETAMOL ?
hydroxyl, amino, carbonyl
carboxyl, aromatic ring, amino
hydroxyl, aromatic ring, carbonyl
hydroxyl, aromatic ring, amide
Aldehydes and ketones form hydrazone with which of the following reagent
Semicarbazide
2,4-dinitro Phenylhydrazine
Hydroxylamine
None
Acetaldehyde and methanol undergo crossed aldol condensation and form
3 hydroxypropanol
3 hydroxy ethanol
2 hydroxy propanal
None
Catalyst SnCl / HCl 2 is used in
Stephen's reduction
Cannizzaro reaction
Clemmensen's reduction
Rosenmund's reduction
Which one of the following pairs is not correctly matched
C=O_Clemmensons reduction_> >CH2
>C=O Wolf Kishner Reduction> >CHOH
-COCl Resunmund's reduction> - CHO
-C = N Stefen's Reduction> -CHO
Which of the following will not give the iodoform test
Acetophenone
Ethanal
Benzophenone
Ethanol
Which of the following will not undergo aldol condensation
Acetaldehyde
Propanaldehyde
Benzaldehyde
Trideuteroacetaldehyde
Ketones undergo aldol condensation and form
Alpha hydroxy ketone
Beta hydroxy ketone
Beta hydroxy aldehyde
None
Aldol product undergo dehydration and form
Alkane
Alkene
Ethane
Methane
The Clemmenson reduction of acetone yields
Ethanol
Ethanal
Propane
Propanol
in crossed cannizzaro reaction two different aldehydes have
alpha hydrogen
no alpha hydrogen
alpha carbons
none
catalyst used for benzoin condensation
kCN
OH
NaOH
HCL
Choose the best reagent in the missing box for carrying out the following reaction
PCC, CH2Cl2
CH3MgBr in ether, then H3O+
m-ClC6H4CO3H
warm H2SO4/H2O
NaOCH3, CH3OH
All of the following reagents can bring about the above transformation except
MnO2
[(CH3)3CO]3AI/Acetone
CrO3/Pyridine/HC
KMnO4/OH-
A hydrocarbon X(C7H12) on ozonolysis followed by the treatment with (CH3)2S gives C7H12O2 which gives positive Tollen’s test as well as positive iodoform test. The compound below satisfying the criteria of X is
A hydrocarbon X has molecular formula C5H10 X on treatment with B2H6 in H2O2 /NaOH gives an optically active C5H12O which on treatment with CrO3/HCI / pyridine gives C5H10O which is still chiral. Which of the following can be a product of reductive ozonolysis of X?
What is the final major product of the reaction
