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Org Chem Lab Review

Total questions: 100

Worksheet time: 3hrs 20mins

Name
Class
Date
1.

Acetylene is a colorless and odor less gas.

a)

T

b)

F

2.

Complete combustion of hydrocarbons produces carbon dioxide and water molecule.

a)

T

b)

F

3.

Acetylene can be used as artificial ripening of fruits.

a)

T

b)

F

4.

If there is no change in color when red litmus is used indicates the presence of phenolic group.

a)

T

b)

F

5.

Double bond is composed of one strong sigma bond and a weak pi bond.

a)

T

b)

F

6.

Alkanes with 17 carbons or more are solid at room temperature.

a)

T

b)

F

7.

Methane is formed when decaying vegetable matter is covered with carbon dioxide and water.

a)

T

b)

F

8.

The chief source of hydrocarbons are petroleum and natural gas.

a)

T

b)

F

9.

A fruity odor indicates the presence of esters.

a)

T

b)

F

10.

Presence of orange color using bromine water test indicates the presence of saturated compounds.

a)

T

b)

F

11.

Glycerin is chemically known as:

a)

glycerol

b)

propenal

c)

trihydric alcohol

d)

propane-1,2,3-triol

12.

Which among the following can be used to detect unsaturation?

a)

Baeyer's test

b)

Charring test

c)

Schiff's test

d)

Friedel-Crats test

e)

Lucas test

13.

Napthalene in Friedel-crafts test produces:

a)

blue

b)

purple

c)

red

d)

yellow

14.

Chemical reaction for alkene includes which among the following?

1.Glycol formation

2.Formation of dihalide

3. Formation of metal acetylides

a)

1, 2 and 3

b)

1 and 2

c)

1 and 3

d)

3 only

15.

Natural gas contains the following except:

a)

hydrogen

b)

minerals

c)

carbon

d)

sulfur

e)

oxygen

16.

RCH2CH3 is a general formula for compounds called:

a)

alkane

b)

alkene

c)

cycloalkene

d)

alkyne

17.

The formula CnH2n represents:

a)

alkane

b)

cycloalkene

c)

alkyne

d)

alkene

18.

An ester is reaction between acid and alcohol.

a)

T

b)

F

19.

What is the type of the chemical methyl ethanoate:

a)

ketone

b)

aldehyde

c)

ester

d)

ether

20.

Which among the following is used as the catalyst for Friedel-crats test:

a)

ceric ammonium chloride

b)

ammonium hydroxide

c)

aluminum chloride

d)

dry cupric oxide

21.

______ refers to the organic compound consisting entirely of hydrogen and carbons only.

a)

salts

b)

hydrocarbons

c)

alkali

d)

acids

22.

Used as a solvent for fats, resins and alkaloids and as starting material for the synthesis of aromatic compounds:

a)

acetylene

b)

benzene

c)

ethylene

d)

naphthalene

23.

A 10 C alkane most likely has the following chemical formula:

a)

C10H24

b)

C10H20

c)

C10H22

d)

C10H18

24.

The chemical CH3OCH3 is an example of what type of organic compound?

a)

aldehyde

b)

ester

c)

ether

d)

acid

25.

Which among the following is correct about alkenes:

1.Also called as olefins

2.Used as anti-knock fuels

3. Compounds of alkenes can be used as general anesthetics

a)

1, 2 and 3

b)

2 and 3

c)

1 and 3

d)

1 and 2

26.

Who among the following listed below discover the structure of benzene?

a)

August Kekule

b)

Friedrich Wohler

c)

Friedlieb Ferdinand Runge

d)

Jons Jakob Berzelius

27.

Alkanes:

1. Also called as paraffins

2. Combustible

3. Prone to addition reaction

a)

1,2,3

b)

2 only

c)

1 only

d)

1 and 2

28.

Halogenated HC can be used as:

a)

antibiotic

b)

vaccine

c)

anesthetic agents

d)

disinfectant

29.

Organic compounds consisting of straight chains of saturated carbon atoms are called _______.

a)

aromatic

b)

aliphatic

c)

cyclic

d)

heterocyclic

30.

Which among the following statement is/are correct about methane:

1. Also known as marsh gas

2. It is gas at room temperature

3. Considered as the simplest alkene

4. It has the chemical formula of C4H8

a)

3 and 4

b)

1 and 2

c)

1, 2 and 3

d)

2 and 3

31.

Benzene:

1.C6H6

2.has alternating single and double bonds 3. can be used as local anesthetic 4.Traditionally used as antiseptic and disinfectant

a)

1 and 2

b)

1, 2, 3, 4

c)

1, 2 and 4

d)

1, 2 and 3

32.

Reaction common to alkenes:

1. Formation of metal acetylides

2. Formation of anhydrides

3. Addition of of hydroxyl group

a)

2 only

b)

1 only

c)

2 and 3

d)

1 and 3

33.

Which among the following is true about methanol?

1. Also known as the wood alcohol

2. Can be used as nasal decongestant

3. Can be used as antifreeze

4. Reduce to formaldehyde that can be used as embalming agent

a)

1, 2 and 3

b)

2, 3 and 4

c)

1 and 3

d)

1, 2, 3, 4

34.

Which among the following can be used as alkalinizing reagent (base on the discussion – M8 and M9)

a)

potassium hydroxide

b)

ammonium hydroxide

c)

sodium bicarbonate

d)

ammonium ceric nitrate

e)

sodium hydroxide

35.

Who discovered phenol in 1834?

a)

Joseph Lister

b)

Friedlieb Ferdinand Runge

c)

August Friedrich Kekule

d)

Jons Jakob Berzelius

36.

What is the reagent used as dehydrating reagent for acrolein test?

a)

Glycerol

b)

Potassium bisulfate

c)

Propenal

d)

Anhydrous sodium sulfate

37.

In Lucas test, for secondary alcohol mostly likely produces which among the following?

a)

here is no cloudiness

b)

Cloudiness appears within 5 to 10 minutes

c)

Cloudiness appears only on heating

d)

Cloudiness appears immediately

38.

Initial oxidation of primary alcohol produces which among the following?

a)

ketone

b)

aldehyde

c)

acid

d)

ester

39.

Which among the following are considered as phenolics?

1. Hydrolyzable Tannins

2. Alkaloids like caffeine

3. Lignins

4. Condensed tannins

a)

2 and 4

b)

1, 3 and 4

c)

2 and 3

d)

1, 2, 3, 4

40.

Dehydration of alcohol with concentrated sulfuric acid can produce:

a)

ether

b)

alkene

c)

carboxylic acid

d)

ester

41.

Which among the following statement is correct about phenols?

1. Also called as carbolic acid

2. Sometimes called as carbonic acid

3. Used by Joseph Lister as antiseptic/disinfectant during surgery

4. Toxicity can be managed with glycerin

a)

1, 2, 3, 4

b)

2, 3 and 4

c)

3 and 4

d)

1, 3 and 4

42.

Which among the following is considered to be the widely consumed recreational drug?

a)

Marijuana

b)

Cocaine

c)

Ethanol

d)

Methamphetamine

43.

Alcohol can be used as which among the following?

1.Disinfectant

2. Antiseptic

3. Solvent

4. CNS depressant

a)

2 and 3

b)

1 and 2

c)

1, 2, 3, 4

d)

1 and 3

44.

Oxidation of this substance leads to the formation of the toxic metabolite oxalic acid (in the form of oxalates):

a)

ethylene glycol

b)

isopropyl alcohol

c)

mineral oil

d)

glycerol

45.

Which among the following is correct about alcohol?

1. It has -OH attached to an alkyl group

2. Very polar and can form intermolecular H-bonds

3. They have higher melting points as compared to HC with same MW

4. Phenol is an example of quaternary alcohols

a)

1, 2 and 3

b)

1 and 2

c)

3 and 4

d)

2, 3 and 4

46.

Which among amino acid contains a phenolic ring?

a)

threonine

b)

tyrosine

c)

tryptophan

d)

phenylalanine

47.

Which among the following enzyme is responsible for the metabolism of alcohol to acetaldehyde?

a)

alcohol dehydrogenase

b)

reductase

c)

aldehyde dehydrogenase

d)

zymase

48.

Test with copper is used for:

a)

glycerol

b)

isopropyl alcohol

c)

methanol

d)

ethanol

49.

Which among the following is true about ethyl alcohol, except:

1. Also known as the grain alcohol In pharmacy

2. it is simply called as alcohol

3. It also known as the boxwood alcohol

4. Other name is spiritus vini rectificatus

a)

3 and 4

b)

1 and 2

c)

3 only

d)

2 and 3

50.

Which among the following pair is/are correctly matched?

Cresols = trihydric

Catechols = dihydric

Phloroglucinol = monohydric

a)

2 only

b)

1 and 3

c)

2 and 3

d)

1 and 2

51.

2,4,6 tribromophenol is ________.

a)

a colorless solution

b)

a white precipitate

c)

liberation of white fumes

d)

a yellow precipitate

52.

Tribromophenol absorbs visible light.

a)

T

b)

F

53.

Excessive use of alcohol may cause the destruction of liver, a condition known as alcohosis

a)

T

b)

F

54.

Menthol can be used in cough preparations and nasal sprays as decongestants.

a)

T

b)

F

55.

The carbon found on methanol is called as the “carbinol” carbon.

a)

T

b)

F

56.

Phenols can be synthesized by hydrolysis of sodium benzene sulfonate.

a)

T

b)

F

57.

95% ethyl alcohol is more effective than the 70% alcohol as antiseptic

a)

T

b)

F

58.

Phenol is prepared in the laboratory by a diazotization of primary aromatic amines.

a)

T

b)

F

59.

Base on structure, isopropyl alcohol is an example of secondary alcohol.

a)

T

b)

F

60.

Naturally occurring phenols are sometimes basic.

a)

T

b)

F

61.

Complete oxidation of primary alcohol produces an aldehyde.

a)

False

b)

True

62.

The boiling point of phenol is 40.5°C.

a)

T

b)

F

63.

Fruit juices can be converted to alcohol with the help of yeast.

a)

T

b)

F

64.

Phenols can react with peroxy- and hydroxy- radicals thereby producing anti-oxidant property.

a)

T

b)

F

65.

The end reaction for chromic acid test is the conversion from orange to green or blue.

a)

T

b)

F

66.

Iodoform test is an example of halogenation reaction wherein methyl ketone is reduced to acid and iodoform.

a)

False

b)

True

67.

Indophenol is colored red or brown when added with water.

a)

T

b)

F

68.

Phenol is an example of protoplasmic poison.

a)

T

b)

F

69.

The expected result with Millon’s test is yellow precipitate.

a)

T

b)

F

70.

Which among the following is/are use of formalin?

a)

antibiotics

b)

anti-viral

c)

anti-infective:)

d)

embalming

71.

Which among the following is produced when ethanol was oxidized by alcohol dehydrogenase?

a)

formaldehyde

b)

chloroform

c)

acetaldehyde

d)

paraldehyde

72.

Which among the following carboxylic acid were produced by red ant’s bite?

a)

acetic acid

b)

formic acid

c)

benzoic acid

d)

propionic acid

73.

Which among the following test differentiates types of amines?

a)

Liebermann's test

b)

reaction with nitrous acid

c)

Lucas test

d)

Schiff's test

74.

________are formed when one hydrogen atom in ammonia is substituted by an alkyl or aromatic group.

a)

nitroalkanes

b)

anhydrides

c)

secondary amines

d)

primary amines

75.

Haloforms are trihalogen derivatives of:

a)

ethane

b)

propane

c)

butane

d)

methane

76.

When a fatty acid reacts with an alkali, the process is called as (a)   .

77.

The following compounds yield a violet color to ferric chloride test, except:

a)

salicylic acid

b)

acetylsalicylic acid

c)

benzoic acid

d)

methyl salicylate

78.

Formation of a peptide bond is an example of:

a)

glycosidic bond

b)

amide bond

c)

mighty bond:'(

d)

ester bond

79.

Quaternary amines can be used as:

a)

keratolytic

b)

anti-cancer

c)

antifungal

d)

soaps

80.

A dicarboxylic acid used as rust and stain remover:

a)

tartaric acid

b)

acetone

c)

formalin

d)

oxalic acid

81.

EDTA is chemically:

a)

amine

b)

ester

c)

example of ketone

d)

aldehyde

82.

Household vinegar is chemically _______.

a)

CH3COOH

b)

CH3OCH3

c)

CH3CH2COOH

d)

HCHCOOH

83.

What is the dehydrating reagent used for Molisch test?

a)

sulfuric acid

b)

nitric acid

c)

Potassium bisulfite

d)

furfural

84.

Oxidation of secondary alcohol yields which among the following?

a)

amide

b)

esters

c)

aldehydes

d)

ketones

85.

The mechanism of sodium bisulfite test is:

a)

electrophillic substitution

b)

hydrolysis

c)

nucleophillic substitution

d)

reduction

86.

Deprotonation of carboxylic acid yields a carbonyl group.

a)

True

b)

False

87.

Monosaccharides can be classified as aldoses or ketoses.

a)

T

b)

F

88.

Presence of ketone bodies in the urine is a sign that the patient is suffering from diabetes mellitus.

a)

T

b)

F

89.

Complete oxidation of ethanol produces acetaldehyde which is responsible for hangover.

a)

T

b)

F

90.

Prontosil is an example of brilliant azo red dye that can be used as antibacterial.

a)

T

b)

F

91.

Carboxylic acid molecules are polar due to the presence of two electronegative oxygen atoms.

a)

True

b)

False

92.

Some organic acids are naturally produced in the human body.

a)

True

b)

False

93.

This sodium bisulfate, aldehydes and methyl ketones can form water soluble salts of bisulfates.

a)

T

b)

F

94.

The α-carbon of carboxylic acid can be converted to amines via Hell-Volhard-Zelinsky reaction.

a)

T

b)

F

95.

Schiff’s test is a differentiating test for ketones and aldehydes because aldehydes are readily oxidized when compared to ketones.

a)

T

b)

F

96.

Dimethylamine is an example of secondary amine.

a)

T

b)

F

97.

Chloral can be used as CNS stimulant thus capable of inducing sleep.

a)

T

b)

F

98.

For tests of amino group, litmus test expected result is red indicating acidic in nature

a)

T

b)

F

99.

Biuret test = peptide bond

a)

T

b)

F

100.

Ninhydrin test=alpha amino acid

a)

T

b)

F