WorksheetsChemistry Unit 3 IB
Total questions: 99
Worksheet time: 59mins
elements in the periodic table are placed in order of increasing......
mass number
relative atomic mass
atomic mass
relative mass number
why can we assume we've found all the natural elements
there are no gaps in the sequence of the periodic table
everything on the periodic table fits perfectly together
the atomic number increases
because none more can be found
columns are also known as...
periods
groups
rows are also known as...
periods
groups
elements whose valence electrons occupy an s-sublevel are in the...
metals section
first period
first group
s-block
identify the blue block
s-block
p-block
d-block
f-block
identify the yellow block
s-block
p-block
d-block
f-block
identify the red block
s-block
p-block
d-block
f-block
identify the green block
s-block
p-block
d-block
f-block
electron configuration of sodium
3s2
3s1
3p2
4s2
Characteristics of metals
Low conductivity
not ductile + malleable
gas at room temp
good conductors of heat and electric current
brittle + dull
Characteristics of non-metals
Low conductivity
not ductile + malleable
gas at room temp
good conductors of heat and electric current
brittle + dull
metalloids
Elements that have properties of both metals (physically) and nonmetals (chemically).
Elements that have properties of both metals (chemically) and nonmetals (physically).
Elements that have properties of metals
Elements that have properties of nonmetals
lathanoides and actinoides
found in s-block
found in p-block
found in d-block
found in f-block
what are the metalloids
As, Sb, Te
B, Si, Ge, As, Sb, Te
B, Si, Ge,
B, Si, Gn, As, Sb, Ti
Which properties increase in value when descending group 1?
I. First ionization energy
II. Atomic radius
III. Reactivity with water
I and II only
I and III only
II and III only
I, II and III
Ionization energy _____ across period
increases
decreases
Electron Affinity _____ across period
increases
decreases
Atomic Radius _____ across period
increases
decreases
Atomic Radius _____ down the group
increases
decreases
Electron Affinity _____ down the group
increases
decreases
Ionization Energy _____ down the group
increases
decreases
non-metallic character _____ diagonally across the group
increases
decreases
metallic character _____ diagonally across the group
increases
decreases
Effective Nuclear Charge _____ across period
increases
decreases
relative charge experienced by outer-electrons is _____ than/to full nuclear charge
less
more
equal
Why is the relative charge experienced by outer-electrons less than full nuclear charge of the atom?
electrons are attracted by inner electrons
electrons are further away from the nucleus
electrons are further away from the protons
electrons are repelled by inner electrons
trends in ionic radius
positive ions smaller than parent ions, formation of positive ions involves loss of outer shell
negative ions are larger than parent ions, addition of electrons into shell increased repulsion between electrons in outer principle energy causing electrons to move further apart
ionic radii decreases from groups 1-14 for positive ions due to increase in nuclear charge across the period, increased attraction between nucleus + electrons pulls outer shell closer to nucleus
ionic radii decreases for negative ions groups 14-17, due to increase in nuclear charge across period, positive ions are smaller than negative ions
ionic radii increase down a group as number of electron energy levels increase
ionization energy trends
ionization energies decrease down a group, the electron is removed from the energy level furthest from the nucleus, nuclear charges increase but the effective nuclear charge is the same due to shielding of inner electrons so distance increases between electron + nucleus reducing attraction between them
decreases for negative ions groups 14-17, due to increase in nuclear charge across period, positive ions are smaller than negative ions
negative ions are larger than parent ions
ionization energy increases across a period, an increase in effective nuclear charge causes an increase in attraction between outer electrons and nucleus and makes it electrons difficult to move
Why are Electron Affinity values not available for noble gases?
as they don’t generally form negatively charged ions
As noble gases are unreactive
as they don't have the ability to form bonds with other atoms
as they are neglible
electronegativity
a measure of ability of atom to repel electrons in a covalent bond
a measure of ability of atom to attract electrons in a covalent bond
measure of repulsion between nucleus + outer-electrons (bonding electrons)
measure of attraction between nucleus + outer-electrons (bonding electrons)
a measure of ability of atom to attract electrons in an ionic bond
an element with high electronegativity has - electron pulling power
weak
strong
why does electronegativity increase across the period
due to an increase in nuclear charge resulting in increased attraction between the nucleus and bond electrons
due to a decrease in nuclear charge resulting in increased attraction between the nucleus and bond electrons
due to an increase in nuclear charge resulting in a decreased attraction between the nucleus and bond electrons
due to an increase in nuclear charge resulting in increased attraction between the nucleus and bonding electrons of other elements
highest value of electronegativity
manganese
caesium
flourine
francium
lowest value of electronegativity
manganese
caesium
flourine
francium
Properties of Ionization Energies
measured directly
properties of atoms in a molecules
derived indirectly from experimental bond energy data
property of gaseous atoms
elements with high ionization energy have the most exothermic electron affinities
Properties of Electronegativity
measured directly
properties of atoms in a molecules
derived indirectly from experimental bond energy data
property of gaseous atoms
elements with high electronegativity have the most exothermic electron affinities
Melting points of different elements depend on their...
bonding
electron affinity
structure
electronegativity
ionization energy
Chemical Properties are determined by the elements...
effective nucleir charge
ionization energy
melting point
electron configuration
Characteristics of Noble Gases
they’re colourless gases
diatomic; exist as two atoms
monatomic; exist as single atoms
very unreactive
in group 18
the lack of reactivity of noble gases is due to...
them not usually forming negative ions as they have the highest ionization energy
them not usually forming positive ions as they have the highest ionization energy
easily gain/lose electrons thus making the energy release neglible
them not forming negative ions as extra electrons have to be added to the outer energy level shell where they’d experience neglible effective nuclear force with protons shielded by the equal number of inner electrons
with exception of _____ noble gases all have complete valence energy levels with eight electrons
neon
helium
argon
xenon
noble gases all have complete valence energy levels with ____ electrons
4
7
8
10
The term “ (a) ” describes the fact that many atoms in molecules are most stable when the valence shell contains effectively eight electrons
reactivity ____ down group
increases
decreases
the reactivity of elements in other groups can be explained by.....
stable complete electron energy levels
unstable complete electron energy levels
stable incomplete electron energy levels
unstable incomplete electron energy levels
Why are alkali metals stored in oil?
to ensure the preservation of their properties
to prevent contact with air and water
to maintain the metals properties
metals thrive in oil based substances
Physical Properties of Alkali Metals
good conductors of electricity + heat
low densities
high densities
grey shiny surfaces when freshly cut with a knife
very reactive metals
Chemical Properties of Alkali Metals
good conductors of electricity + heat
unreactive metals
similar chemical properties to noble gases
form ionic compounds with non-metals
very reactive metals
Why are alkali metals able to conduct heat and electricity
due to the mobility of their inner electrons
due to their high densities
due to their low densities
due to the mobility of their outer electron
Alkali metals react with water to produce:
nitrogen
hydrogen
carbonate
metal nitrate
metal hydroxide
What happens when you drop lithium in water?
floats
sinks
reacts slowly
releases hydrogen
keeps its shape
What happens when you drop sodium in water?
the heat produced is sufficient enough to ignite the hydrogen produced, which produces a lilac coloured flame and moves excitedly on surface
the heat produced is sufficient enough to melt the unreacted metal which forms small ball and moves around on the water's surface
reacts slowly
reacts vigorously
releases hydrogen
What happens when you drop potassium in water?
the heat produced is sufficient enough to ignite the hydrogen produced, which produces a lilac coloured flame and moves excitedly on surface
the heat produced is sufficient enough to melt the unreacted metal which forms small ball and moves around on the water's surface
reacts slowly
reacts very vigorously
releases hydrogen
halogens exist as...
monoatomic molecules
diatomic molecules
triatomic molecules
Physical Properties of Halogens
coloured
colourless
high densities
show gradual change from gases to solids
very reactive metals
Chemical Properties of Halogens
reactivity decreases down the group
reactivity increases down the group
form ionic compounds with metals and covalent compounds with other non-metals
form ionic compounds with non-metals and covalent compounds with metals
very reactive non-metals
halogens + group 1 → _______
hydrogen
ionic compounds
ionic halides
hydroxide
most vigorous attraction occurs between elements which are the _________ on periodic table
furthest apart
closest to each other
halogens form _____ salts w silver
soluble, causing a reaction which produces a hydrogen and hydroxide
soluble, causing a colour changing reaction that's useful in identifying the halide ion
insoluble, causing a build-up of solute at the bottom of the solution
insoluble, causing a precipitate that’s useful in identifying halide ion
smaller atomic radius means that...
the nucleus has a stronger attraction for electrons
the nucleus has a weaker attraction for electrons
_____ compounds are generally formed between metals and non-metals so oxides of elements Na-Al have _______
ionic, molecular ionic structures
covalent, giant covalent structures
covalent, molecular covalent structure
ionic, giant ionic structures
______ compounds formed between non-metals so oxides of phosphurus+sulfur+chlorine are ________
ionic, molecular ionic structures
covalent, giant covalent structures
covalent, molecular covalent structure
ionic, giant ionic structures
oxide of silicone (metalloid) gas has a _________
ionic, molecular ionic structures
covalent, giant covalent structures
covalent, molecular covalent structure
ionic, giant ionic structures
metallic elements which form ionic oxides are ______
basic
acidic
amphoteric
non-metal oxides that are covalent are ______
basic
acidic
amphoteric
aluminium oxide is ______
basic
acidic
amphoteric
Basic Oxides reacts with ________
water to produce acidic solutions
an acid to form a salt and water
acts as a base when reacting with acid, acts as an acid when reacts with alkalis
Acidic Oxides/non-metallic oxides react with ________
water to produce acidic solutions
an acid to form a salt and water
acts as a base when reacting with acid, acts as an acid when reacts with alkalis
Amphoteric Oxides ________
reacts with water to produce acidic solutions
reacts with an acid to form a salt and water
acts as a base when reacting with acid, acts as an acid when reacts with alkalis
Metals Have ______ Ionization Energies and Electronegativities than Non-Metals
lower
higher
Chemical Properties of Transition Metals
→ they form compounds with a variable oxidation state
→ they form a variety of complex ions
→ they form coloured compound
→ they act as catalysts when either elements or compounds
→ they have magnetic properties
→ they form compounds with a variable oxidation state
→ they form a few complex ions
→ they form colourless compounds
→ they act as catalysts when either elements or compounds
→ they have magnetic properties
→ they form compounds with a variable oxidation state
→ they form a few complex ions
→ they form coloured compounds
→ they act as catalysts with elements and not compounds
→ they don't have magnetic properties
→ they form compounds with a variable oxidation state
→ they form coloured compounds
→ they act as catalysts with elements and not compounds
→ they don't have magnetic properties
Which of the following is not a transition metal?
copper
chromium
vanadium
zinc
why is zinc NOT considered to be a transition metal?
it is magnetic
only forms white compounds
it does have a partially filled d sub-level
Zinc only forms one ion
it does not have a partially filled d sub-level
a substance which alters the rate of reaction by providing an alternative reaction pathway with a lower activation energy
(a)
Which of the following is used in catalytic converters?
manganese hydroxide
platinum
phosphorus
palladium
gold
ferromagnetism
The property that allows a substance to become permanently magnetized when placed in a magnetic field; exhibited by iron, cobalt, and nickel and some of their alloys.
a type of induced magnetism, associated with unpaired electrons, that causes a substance to be attracted into the inducing magnetic field
a type of magnetism, associated with paired electrons, that causes a substance to be repelled from the inducing magnetic field
paramagnetism
The property that allows a substance to become permanently magnetized when placed in a magnetic field; exhibited by iron, cobalt, and nickel and some of their alloys.
a type of induced magnetism, associated with unpaired electrons, that causes a substance to be attracted into the inducing magnetic field
a type of magnetism, associated with paired electrons, that causes a substance to be repelled from the inducing magnetic field
diamagnetism
The property that allows a substance to become permanently magnetized when placed in a magnetic field; exhibited by iron, cobalt, and nickel and some of their alloys.
a type of induced magnetism, associated with unpaired electrons, that causes a substance to be attracted into the inducing magnetic field
a type of magnetism, associated with paired electrons, that causes a substance to be repelled from the inducing magnetic field
the type of magnetism of Iron (II) complex ion when containing a weak ligand
ferromagnetism
paramagnetism
diamagnetism
the type of magnetism of Iron (II) complex ion when containing a strong ligand
ferromagnetism
paramagnetism
diamagnetism
neutral ions or anions containing a non-bonding pair of electrons which can form co-ordinate covalent bonds with a metal ion to form a complex ion
(a)
ligands ____ be replaced by other ligands
can
cannot
the number of lone pairs bonded to the metal ion
(a)
compounds with coordination number of 6 have a ______ shape
linear
tetrahedal
octahedral
square planar
compounds with coordination number of 2 have a ______ shape
linear
tetrahedal
octahedral
square planar
factors affecting colour of transition metal complexes
identity of ligand
oxidation state
the electron configuration of the element
nature of transition element
stereochemistry of the complex
what you can find out about the complex using its colour
charge of metal ion
identity of ligand
oxidation state of metal ion
coordinate number
identity of metal ion
Why do transition metal complex ions show a colour
the metal ions have a corresponding colour corresponding to their strength
the ligands have a corresponding colour corresponding to their strength
because the splitting of the d-levels caused by the ligand corresponds to a certain wavelength therefore omitting a visible colour
because the splitting of the s-levels caused by the ligand corresponds to a certain wavelength therefore omitting a visible colour
big delta E means
big jump
small jump
big energy absorbed (higher colour)
small energy absorbed (lower colour)
small delta E means
big jump
small jump
big energy absorbed (higher colour)
small energy absorbed (lower colour)
more protons results in a _____ split
bigger
smaller
the smaller the oxidation state the _____ the split
smaller, (absorbs lower energy)
bigger, (absorbs higher energy)
high energy =
high frequency
low frequency
if red/orange light is absorbed the solution appears
red-orange
blue-green
red-yellow
blue-purple
which one is correct (lowest to highest energy)
Red →Orange → Yellow → Green→ Light Blue → Blue → Violet
Red →Yellow→ Orange → Green→ Blue → Light Blue → Violet
Red →Orange → Yellow → Green→ Blue → Light Blue → Violet
Violet →Orange → Yellow → Green→ Light Blue → Blue → Red
Weak ligands
NCS- to CO
I- to H2O
Strong ligands
NCS- to CO
I- to H2O
Strong ligands
NCS- to CO
I- to H2O
