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WorksheetsStates of Matter
Total questions: 50
Worksheet time: 25mins
R.J Clausius deduced an equation for the pressure of an ideal gas from the
postulates of kinetic theory. This equation is called kinetic equation, the correct
mathematical form of it is
PV= 1/2mNc- 2
PV= 1/3mNc- 2
PV = nRT
pv=1/3Nc-2
Which of the following is equal to –12°C temperature
285 K
–261 K
–12 K
261 K
If 50cm3 of a gas in a syringe at 15°C is heated to 50°C and the piston of syringe is
allowed to move outwards against constant atmospheric pressure, the new volume ofthe hot gas will be _______
50cm3
44cm3
40cm3
56cm3
Select the correct formula for determination of molecular mass from ideal equation(W and m are used for mass of gas)
.M = MPW/
RT
M = WRT/
PV
M= MRT/
PV
both b and c
At 17°C, a sample of H2 gas occupies 125cm3. What would be the volume at 307°C by keeping pressure constant
125cm3
250cm3
415cm3
350cm3
Volume of a gas at STP is 10 dm3, at what temperature its volume will become
30dm3, keeping pressure constant
3°C
819°C
3K
819K
A real gas behaves ideally at
High pressure, low temperature
High pressure, high temperature
Low pressure, high temperature
Low pressure, low temperature
At constant temperature volume of the given mass of a gas is directly proportional
to the inverse of pressure exerted on it, is called
General gas law
Charles’s law
Boyle’s law
Avogadro’s law
If temperature and pressure of 4dm3 of hydrogen is reduce to half, then new volumeof gas will be
8dm3
4dm3
6dm3
2dm3
Which of the following is more ideal gas at 100 C temperature and constant
pressure?
He
N2
H2
CO2
Density of gas will increase with
Rise in temperature
Rise in volume
Increase in pressure
Decrease in pressure
For a given mass with initial volume ‘V’, if pressure is reduced to one half and
absolute temperature is increased two times. The volume will become
2V^2
V/4
4V
6V
Gases are considered to be composed of minute discrete particles called
Atoms
Molecules
Ions
Elements
Which of the following types of motions are present in triatomic molecule?
Translational
Rotational
Vibrational
All of these
The molecules of which gas has highest average kinetic energy at 25°C
CO2
O2
CH4
All have same
CO2 will show more non-ideal behaviour at
17°C
0°C
100°C
273°C
Critical temperature of O2, N2, H2 and CO2 are –118.8°C, –147.1°C, –239.9°C and
31.1°C respectively. Which gas among following is most ideal
H2
O2
CO2
N2
The molar volume of N2 is maximum at
273 K and 2 atm
273^o1 atm
0^oC and 2 atm
STP
Which of the following does not favors the increasing of vapor pressure?
Increasing temperature
Increasing surface area
Decreasing intermolecular forces
All of these
Water has high heat of vaporization due to extensive _______
Covalent bonds
Ion dipole forces
Hydrogen bonding
Debye forces
Factor on which evaporation depends but vapour pressure does not
Temperature
Surface area
Intermolecular forces
Nature of liquid
Which of the following is true?
HF has strongest hydrogen bond and higher boiling point than water
HF has strongest hydrogen bond and has low boiling point than water
HF has strongest hydrogen bond and has boiling point equal to water
None is true
Ice is less dense than water at
25°C
4°C
0°C
2°C
Acetone and chloroform are soluble in each other due to
Intermolecular hydrogen bonding
Instantaneous dipole
Ion-dipole interaction
All of the above
NH3 show a maximum boiling point among hydride of VA group elements due to
Very small size of nitrogen
Lone pair of e– present on nitrogen
Enhanced electronegative character of nitrogen
Pyramidal structure of NH3
The liquid which has maximum rate of evaporation at same temperature.
CCl4
C2H5OH
CH3COCH3
H2O2
When the external pressure is increased from 23.7 torr to 700 torr, the boiling point
of water increases from.
0°C to 98°C
25°C to 100°C
69°C to 98°C
25°C to 98°C
The substance that contains London dispersion forces only
Phenol
Benzene
Acetone
Chloroform
The hexagonal type empty spaces are present in the structure of ice. This is due to
hydrogen bonding present between______ atom of one water molecule and________atom of other water molecule
H,H
H,N
H,O
O,O
In which of the following pairs of liquids, the first liquid has higher vapour pressure
than the other liquid at the same temperature with the different surface area
Dimethyl ether and acetone
Ethanol and Ammonia
Water and HF
Water and n-hexane
Which one of the following arrangements usually represents the correct order of
increasing strength?
H-Bonding, London dispersion force, Dipole-Dipole force
London dispersion force, Dipole-Dipole force, H-bonding
London dispersion force, H-Bonding, Dipole-Dipole force
Dipole-Dipole force, London dispersion force, H-bonding
At boiling point of a liquid, its vapour pressure becomes
Greater than external pressure
Less than external pressure
Equal to external pressure
No relationship
Which of the following is pseudo solid?
Graphite
Rubber
NaCl
All of these
Which of the following factors affect the shape of an ionic solid
Electrostatic forces of attraction
Radius ratio
Poor conductivity
All of these
To form a crystal lattice of NaCl, each Na+ion is surrounded by
6 Cl
6 Cl+
6Cl°
6 Cl–
The amount of energy released when gaseous ions of opposite charges combine to give one mole of a crystalline ionic compound is known as
Bond energy
Potential energy
Lattice energy
Kinetic energy
The existence of an element in different crystalline forms is called
Polymorphism
Isomorphism
Anisotropy
Allotropy
The molecules of I2
Simple cubic crystal
Body centered cubic crystal
Face centered cubic crystal
Hexagonal close pack crystal
The molecules of sucrose form the
A. B.
C. D.
Ionic crystals
Molecular crystals
Covalent crystals
Metallic structure
Which of the following is non-polar molecular solid with strongest intermolecular
forces?
Ice
Iodine
Glucose
Graphite
Molecular solids have
Ionic bond
Metallic bond
Covalent bond
Van der Waal’s forces
Type of attractive forces in dry ice
Ionic bond
Coordinate covalent bond
Covalent bond
London dispersion forces
Which of the following statements is correct about ionic solids?
They have definite geometric shape
They are non-directional in nature
They do not exist in the form of molecules due to their ionic nature
All of these
The corner located Na+ ion in the unit cell of NaCl is shared among ______ unit cells
4
8
6
10
I – I bond distance in crystal of iodine is
271.5 pm
266.6 pm
4.9 pm
9.6 pm
Which of the following are generally poor conductors of electricity?
Ionic solids
Covalent solids
Metallic solids
Molecular solids
Crystalline solids in which the particles forming the crystals are positively and
negatively charged ions are called `
Ionic solids
Covalent solids
Metallic solids
Molecular solids
The ratio between increase in volume with rise of temperature as suggested by
Charles’s law:
A
B
C
D
According to kinetic molecular theory, average speed of gas molecules and
molecular mass of gas have _______ relationship
A
B
C
D
A
B
C
D
