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MIDTERM EXAM CE CHEM FOR ENGINEERS

Total questions: 50

Worksheet time: 2hrs 26mins

Name
Class
Date
1.
What are the coefficients when the equation is balanced?
a)
2 + 3 --> 2 + 3 + 4
b)
1 + 3 --> 1 + 3 + 2
c)
2 + 4 --> 2 + 3 + 2
d)
1 + 1 --> 1 + 1 + 1
2.
What are the coefficients when the equation is balanced?
a)
1 + 1 + 1 --> 2 + 1 + 3
b)
2 + 2 + 2 --> 4 + 2 + 3
c)
1 + 2 + 1 --> 2 + 2 + 3
d)
1 + 1 + 1 --> 1 + 1 + 1
3.
What element is being reduced?
a)
I
b)
H
H
c)
S
S
d)
O
O
4.
If in a reaction, copper is reduced; its number of electrons has:
a)
Increased
b)
Decreased
c)
Remained Constant
d)
Varies Randomly
5.
If an atom loses electrons during a chemical reaction, the atom was:
a)
Oxidized
b)
Reduced
c)
Neutralized
d)
Precipitated
6.
In the reaction
2Ca(s) + O2(g) --> 2CaO(s), calcium is __________
a)
Reduced
b)
Synthesized
c)
Oxidized
d)
None of the above
7.
     In the reaction Zn + H2O --> ZnO2 + H2
 which element, if any, is oxidized? 
a)
Zinc
b)
Hydrogen
c)
Oxygen
d)
None
8.
Another name for a "oxidation-reduction" reaction is
a)
chemical reaction
b)
neutralization reaction
c)
redox reaction
d)
nuclear reaction
9.
What substance is oxidized in the following reaction?
4Fe + 3O2 --> 2Fe2O3
a)
Iron
b)
Fluorine
c)
Oxygen
10.
Is calcium oxidized or reduced in the following reaction? 
2CaO--> 2Ca + O2
a)
Oxidized
b)
Reduced
11.

In which substance does sulfur have a negative oxidation number?

a)

CaSO4

b)

S

c)

SO2

d)

Na2S

12.

Which of the following species is the strongest oxidizing agent under standard-state conditions?

a)

Ag+(aq)

b)

H2(g)

c)

H+(aq)

d)

Cl2(g)

e)

Al3+(aq)

13.

Which statement is true for a spontaneous redox reaction carried out at standard-state conditions?

a)

red is always negative.

b)

cell is always positive.

c)

ox is always positive.

d)

red is always positive.

14.

Which is the incorrect statement about voltaic cells?

a)

Oxidation occurs at the cathode (positive electrode)

b)

Electricity is produced as the result of spontaneous exothermic chemical reactions

c)

Reduction occurs at the cathode (positive electrode)

d)

Voltaic cells are also called galvanic cells

15.

Explain the function of a salt bridge in a voltaic cell

a)

provides an electrical connection between the two half-cells to complete the circuit

b)

provides an pathway for electrons to flow to each of the half-cells

c)

allows ions to flow into or out of the half-cells to balance out the charges in the half-cells

d)

prevents the flow of the anions and cations from the salt used in the salt bridge to the two half-cells

16.

A voltaic cell made up from an iron half-cell and a copper half-cell is operated.

What is the correct overall equation for the reaction in this cell?

a)

Fe2+(aq) + Cu(s)

-> Fe(s) + Cu2+(aq)

b)

Fe(s) + Cu2+(aq)

-> Fe2+(s) + Cu(s)

c)

Fe2+(aq) + Cu2+(aq)

-> Fe(s) + Cu(s)

17.

In the standard notation for a voltaic cell, the single vertical line "|" represents:

a)

gas electrode

b)

a phase boundary

c)

a salt bridge

18.

In this voltaic cell notation:

Pt | H2(g) | H+(aq) || Fe3+(aq), Fe2+ (aq) | Pt

Why Fe3+(aq) and Fe2+ (aq) are separated by a comma instead of a single vertical line which represents phase boundary?

a)

they are in different phase

b)

the comma is a more representative notation

c)

they are in the same phase

19.

In an electrolytic cell the electrode at which the electrons enter the solution is called the ______ ; the chemical change that occurs at this electrode is called _______.

a)

 anode, oxidation

b)

anode, reduction

c)

cathode, oxidation

d)

cathode, reduction

20.

Pb + 2Ag+ → Pb+2 + 2Ag


The chemical species being reduced is

a)

Ag

b)

Pb

c)

Pb+2

d)

Ag+

21.
What unit of measurement do we use to measure electrical potential?
a)
Watts
b)
Volts
c)
Amps
d)
Ohms
22.
What reaction occurs at the anode?
a)
Ag+ + e- →Ag
b)
Ag → Ag+ + e-
c)
Ni2+ + 2e- → Ni
d)
Ni → Ni2+ + 2e-
23.
What is Eo for the following reaction?
a)
+0.85
b)
+0.51
c)
–1.53
d)
–1.87
24.
What is cell potential?
a)
0.67
b)
0.93
c)
1.47
d)
1.73
25.
What is the equation and cell potential?
a)
2Al3+ + 3Ni → 2Al + 3Ni2+ EO = 1.89 V
b)
2Al + 3Ni2+ → 2Al3+ + 3Ni EO = 1.89 V
c)
2Al3+ + 3Ni → 2Al + 3Ni2+ EO = 1.43 V
d)
2Al + 3Ni2+ → 2Al3+ + 3Ni EO = 1.43 V
26.

a)

-0.41V

b)

-0.27 V

c)

+0.27 V

d)

+0.41 V

27.

The relevant standard electrode potentials for this cell are shown below.

Cr3+(aq) + 3e- ⇌ Cr(s) E= − 0.74 V

Ag+(aq) + e− ⇌ Ag(s) E = + 0.80 V

Calculate the emf of the cell shown in the diagram.

a)

+1.54 V

b)

-1.54 V

c)

+ 0.06 V

d)

- 0.06 V

28.

Calculate the cell potential of a galvanic cell that uses the two half equation below

Sn2+ + 2e- --> Sn4+ E0 = -0.14 V

Mg2+ + 2e- --> Mg E0 = -2.37 V

a)

-2.23 V

b)

-2.51 V

c)

+ 2.23 V

29.

Using the following standard reduction potentials

Fe3+(aq) + e --> Fe2+(aq) + e E0 = +0.77V

Ni2+ + 2e --> Ni E0 = -0.26V


Ni + 2 Fe3+ --> Ni2+ + 2 Fe2+

Calculate the standard cell potential for the above galvanic cell

a)

-1.8V

b)

+1.8V

c)

+0.51 V

30.

Which is the correct line notation for the cell?

a)

Ag+ I Ag II Ni I Ni2+

b)

Ag I Ag+ II Ni I Ni2+

c)

Ni I Ni2+ II Ag+ I Ag

d)

Ni2+ I Ni II Ag+ I Ag

31.

What would be the theoretical cell potential of the electrochemical cell

Ni I Ni2+ II Ag+ I Ag

Ag+ + e- \rightarrow  Ag Eo = + 0.80V

Ni2+ +2e- \rightarrow  Ni Eo= -0.25V

a)

1.05V

b)

-1.05V

c)

0.55V

d)

-0.55V

32.

How much energy is needed to raise the temperature of 5.0 grams of lead from 25°C to 35°C? [specific heat (c) = 0.129 J/(g•°C)]

a)

6.45 J/(g•°C)

b)

6.45 J

c)

16.1 J/(g•°C)

d)

d.16.1 J

33.
The specific heat(c) of copper is 0.39 J/g °C. What is the temperature change(∆t) when 100 Joules of heat(Q) is added to 20 grams?
a)
12.82 °C
b)
24.12°C
c)
351 °C
34.

The unit of specific heat capacity is...

a)

Jkg1Jkg^{-1}  

b)

JK1JK^{-1}  

c)

J°C1J\degree C^{-1}  

d)

Jkg1K1Jkg^{-1}K^{-1}  

35.

When a substance changes from solid to liquid it is known as

a)

Fusion

b)

Freezing

c)

Vaporization

d)

Condensation

36.

Which of the following is NOT a characteristic of Evaporation?

a)

Thermal energy is supplied by the surroundings

b)

Temperature remains constant

c)

No bubbles are formed in the liquid

d)

Takes place only at the liquid surfaces.

37.

I have 10kg of ice at -10˚C and I want to convert it all to water. The specific heat of ice is 2.1kJ/kg and the latent heat of fusion is 335kJ/kg. How much heat will I need?

a)

210kJ

b)

3350kJ

c)

210 + 3350 = 3560kJ

d)

210 + 3350 + 2100 = 5660kJ

38.

How much heat energy is required to melt 5 kg of ice? Specific latent heat of ice = 336 J/g.

a)

168 J

b)

1.68 x 103 J

c)

16.8 x 103 J

d)

1.68 x 106 J

39.
The specific heat(c) of copper is 0.39 J/g °C. What is the temperature change(∆t) when 100 Joules of heat(Q) is added to 20 grams?
a)
12.82 °C
b)
24.12°C
c)
351 °C
40.

A piece of aluminum with a mass of 20.0 grams is heated from 30 oC to 95 oC. If the specific heat of aluminum is 0.904 J/goC, how much heat is gained by the aluminum?

a)

1717.60 J

b)

1175.20 J

c)

963.68 J

d)

542.4 J

41.

What is material science?

a)

Focus is on how to translate or transform materials into useful devises or structures.

b)

Involves designing or engineering the structure-property correlations of a material to produce a predetermined set of properties.

c)

A branch of science that focuses on materials; interdisciplinary field composed of physics and chemistry.

d)

Relationship between the synthesis and processing, structure and properties of materials.

42.

These are the components of material science tetrahedron EXCEPT ...

a)

Performance

b)

Properties

c)

Processing

d)

Structure

e)

Characterization

43.

There are 5 classification of material science. Metal,.............,ceramics, composites, advanced material.

a)

A. Biomaterial

b)

B. Polymer

c)

C. Smart material

d)

D. Semiconductor

44.

These are the reasons why you need to study material science and engineering EXCEPT

a)

able to select the best material for certain application

b)

able to create a new material

c)

able to predict the properties of new found material

d)

able to select the most expensive material for certain application

45.

A good electrical and heat conductor, strong and ductile. This statement refers to :

a)

metal

b)

polymer

c)

ceramic

d)

glass

46.

These are the characteristics of polymeric materials EXCEPT

a)

Lightweight

b)

Low densities

c)

Good thermal insulator

d)

Good electrical conductor

47.

Copper, titanium and nickel are the ________________ materials.

a)

polymer

b)

metal

c)

semiconductor

d)

composites

48.

A group of crystalline inorganic materials characterized by good strength, especially in

compression, and high melting temperatures. Many ceramics have very good electrical and thermal

insulation behavior.

(a)  

49.

A group of materials formed from mixtures of metals, ceramics, or polymers in such

a manner that unusual combinations of properties are obtained (e.g., fiberglass).

(a)  

50.

A combination of at least two materials, one of which is a metal whose properties are different from its original form.

a)

Metalloid

b)

Ceramic

c)

Alloy

d)

Nanomaterial