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PRE-TEST 3 STATES OF MATTER & CHEMICAL EQUILIBRIUM

Total questions: 52

Worksheet time: 1hrs 18mins

Name
Class
Date
1.

What assumptions are made for the ideal gas equation?

a)

There is no attraction between the molecules of the gas.

b)

The volume occupied by the molecules is negligible.

c)

Both of the mentioned.

d)

None of the mentioned.

2.

The following statements are assumptions of the kinetic theory of gases EXCEPT

a)

Average kinetic energy of gas molecules is inversely proportional to the absolute temperature.

b)

The intermolecular forces between gas molecules are negligible.

c)

The molecules undergoes elastic collisions with one another.

d)

The volume of the atoms or molecules is negligible.

3.

Suppose you have two gases numbered 1 and 2.

Which equation represents make the most sense to calculate the total pressure exerted by both gases?

a)

Multiply their pressures :

Ptotal = P1 × P2

b)

Divide their pressures :

Ptotal = P1 ÷ P2

c)

Add their pressures :

Ptotal = P1 + P2

d)

Subtract their pressures :

Ptotal = P1 – P2

e)

Average their pressure :

Ptotal = (P1 + P2)/2

4.

The van der Waals equation is a modification of ideal gas equation. Which of the following is accounted for the modification?

a)

Volume and Pressure.

b)

Number of mole and Temperature.

c)

Position of the particles and kinetic energy.

d)

Surface area and density

5.

A substance that flows quickly has __________.

a)

low viscosity

b)

high viscosity

6.

Which of the following liquids is viscous?

a)

honey

b)

water

c)

soy sauce

d)

cooking oil

7.

"The measure of the resistance to the flow of a liquid"

This statement is explain about __________ of liquids

a)

compressibility

b)

viscosity

c)

surface tension

d)

diffusion

8.

What is the cause of the surface to TIGHTEN  like an ELASTIC FILM?

a)

equal

intermolecular force

b)

balanced intermolecular force

c)

unbalanced intermolecular force

9.

Which model represents a LOWER Vapor Pressure?

a)

A

b)

B

10.

Factors affecting vapour pressure:

i. Strength/type of attractive forces between liquid molecules

ii. Temperature

iii. Molecular mass 

iv. Size of liquid molecules

a)

i and ii only

b)

ii and iv only

c)

i, ii and iii

d)

i, ii, iii and iv

11.

Which substance has the weakest intermolecular forces?

a)

Substance A, boiling point of 75 °C

b)

Substance B, boiling point of 105 °C

c)

Substance C, boiling point of 25 °C

d)

Substance d, boiling point of 45 °C

12.

According to the reference table, what is the boiling point of ethanoic acid at 80 kPa?

a)

28 oC

b)

100oC

c)

111oC

d)

125oC

13.

Which liquid has the highest vapor pressure at 75oC?

a)

ethanoic acid

b)

ethanol

c)

propanone

d)

water

14.

At which temperature is the vapor pressure of ethanol equal to the vapor pressure of propanone at 35oC?

a)

35oC

b)

60oC

c)

82oC

d)

95oC

15.

Which is the correct statement for vapour pressure?

a)

Pressure exerted by the vapour molecules at equilibrium with its solid in a closed container

b)

Pressure exerted by the vapour molecules at equilibrium with its liquid in an opened container

c)

Pressure exerted by the vapour molecule at equilibrium with its liquid in closed container

d)

Pressure exerted by vapour molecule at equilibrium with its vapour in a closed container

16.

Why does a gas with a lower vapor pressure have a higher boiling point?

a)

the molecules need more energy to break free of their attractions to other molecules and change phase from liquid to gas

b)

the forces of attraction between the molecules are strong

c)

the substance has low volatility

d)

all of the answers are correct

17.
Liquids with weak intermolecular forces
a)
contain a lot of kinetic energy
b)
easily evaporate
c)
cannot diffuse
d)
freeze easily
18.

Diamond cannot conduct electricity because

a)

diamond has the structure of a giant covalent molecule

b)

its carbon atoms form single covalent bonds

c)

all of its valence electrons are used in forming covalent bonds

d)

it has a higher melting point

19.

What are the forces acting on A and B?

a)

Both A and B are covalent bonds

b)

A is covalent bond, B is van der Waals

c)

Both A and B are van der Waals forces

d)

A is van der Waals, B is covalent bond

20.

This type of solid forms a regular repeating

three-dimensional structure called a crystal lattice. What type of solid is this?

a)

amorphous

b)

crystalline

c)

glass

d)

diamond

21.

Which statement describe about characteristic of crystalline solid?

a)

formed when liquid cooled rapidly

b)

occupy random position

c)

no orderly structure

d)

arranged in a define and orderly arrangement

22.

If the substance is originally at the temperature and pressure of point D, what changes must occur to reach the triple point?

a)

increase both temperature and pressure

b)

decrease both temperature and pressure

c)

increase temperature, decrease pressure

d)

increase pressure, decrease temperature

23.
What is point A?
a)
triple point
b)
critical point
c)
equilibrium point
d)
normal melting point
24.

How many phases exist at triple point?

a)

1

b)

2

c)

3

d)

4

25.
At 0.10 atm, what phase(s) can exist?
a)
solid, liquid or gas
b)
liquid or gas
c)
solid only
d)
gas only
26.
What is true regarding CO2 for temperatures above 31 °C?
a)
It can never be liquified.
b)
It decomposes.
c)
It has a high pressure.
d)
It is a plasma.
27.

Describe phase changes that occurs at letter B?

a)

Liquid to solid

b)

Liquid, solid-liquid equilibrium to solid

c)

Solid to liquid

d)

Vapour to liquid

28.

The pressure is increased on a sample of water at 0 °C from 0 mmHg to 800 mmHg. In order, what changes occur?

a)

Deposition then melting

b)

Sublimation then melting

c)

Condensation then freezing

d)

Deposition then freezing

29.

Water exists as a _____________ at 3 mmHg and 50 °C.

a)

Solid

b)

Liquid

c)

Gas

d)

Supercritical fluid

30.

Which of the following is true for a chemical reaction at equilibrium?

a)

Only the forward reaction stops

b)

Both the forward and reverse reactions stop

c)

The rates of the forward and reverse reactions are equal

d)

The rate constants, K, for the forward and reverse reactions are equal

31.

Which of the following are equal for a chemical system at equilibrium?

a)

The concentrations of reactants and products are equal

b)

The rate constants for the forward and reverse reactions are equal.

c)

The rate of the forward and reverse reaction as the equilibrium is achieved are equal.

d)

The time that a particular atom or molecule spends as a reactant and product are equal

32.

When equilibrium is achieved, the concentrations of products will ...

a)

Change continually because reversibility

b)

Change because there are no more reactants

c)

Not change because the limiting reagent is gone

d)

Not change because the forward and reverse rates are equal

33.
This symbol indicates that a reaction is ____________
a)
reversible
b)
irreversible
34.

Around what time does the reaction reach equilibrium?

a)

25 min

b)

45 min

c)

70 min

d)

80 min

35.

At what time on the graph will the reaction reach equilibrium?

a)

t1

b)

t2

c)

t3

d)

t4

36.

This graph shows how an equilibrium forming. 


The balanced equation is H2(g) + I2(g)  ⟺\Longleftrightarrow   2HI(g). 


WHICH GRAPH shows the same equilibrium forming from *pure* hydrogen iodide?

a)
b)
c)
d)
37.
2 NH3  →←  N2  +  3 H2
The Kc expression for the reaction is...
a)
Kc = [N2][H2]/[NH3]
b)
Kc = [N2][H2]3/[NH3]2
c)
Kc = [NH3]/[N2][H2]
d)
Kc = [NH3]2/[N2][H2]3
38.

Heterogeneous equilibria refer to

a)

chemical equilibrium in which all the reactants and products are in different phases.

b)

chemical equilibrium in which all the reactants and products are in same phases.

c)

chemical equilibrium in which all the rate of forward reaction is equal to the rate of reverse reaction.

d)

chemical equilibrium in which all the rate of forward reaction is greater than the rate of reverse reaction.

39.

Homogeneous equilibria refer to

a)

chemical equilibrium in which all the reactants and products are in different phases.

b)

chemical equilibrium in which all the reactants and products are in same phases.

c)

chemical equilibrium in which all the rate of forward reaction is equal to the rate of reverse reaction.

d)

chemical equilibrium in which all the rate of forward reaction is greater than the rate of reverse reaction.

40.

All the systems below are homogeneous equilibria EXCEPT

a)

2PCl3 (g) + O2 (g) ⇌  2POCl3 (g )

b)

FeO (s) + CO (g ) ⇌       Fe(s) + CO2 (g )

c)

Ag+ (aq) + Fe2+ (aq) ⇌ Ag (s) + Fe3+ (aq)

d)

N2O4 (g) ⇌ 2NO2 (g)

41.

Which of the following statements is the BEST explains the heterogeneous equilibria?

a)

Concentration of solid and pure liquids are excluded from expression of K

b)

Concentration of solid and pure liquids are included from expression of K

c)

Concentration of reactants and products are the same

d)

Reactants and products are in same phase

42.

All the systems below are homogeneous equilibria EXCEPT

a)

2PCl3 (g) + O2 (g) ⇌  2POCl3 (g )

b)

FeO (s) + CO (g ) ⇌       Fe(s) + CO2 (g )

c)

Ag+ (aq) + Fe2+ (aq) ⇌ Ag (s) + Fe3+ (aq)

d)

N2O4 (g) ⇌ 2NO2 (g)

43.

For the graph, choose the CORRECT statement.

a)

The rate of reaction slowly increase

b)

The systems never reach equilibrium

c)

At equilibrium, more NO2 is present than N2O4.

d)

At start of reaction, only NO2 was present.

44.

The following reaction aA + bB produce cC + dD.

The realtion that determine the equilibirum constant, Kc is known as

a)

Law of active mass.

b)

Law of mass action.

c)

Law of chemical reactions.

d)

Law of conservation of mass.

45.
Which of the two graphs reaches equilibrium?
a)
The left one.
b)
The right one.
c)
Both of them.
d)
Neither.
46.

From the reaction, choose the CORRECT equilibrium constant, Kp.

a)
b)
c)
d)
47.

For the reaction, choose the CORRECT equilibrium constant, Kc.

a)
b)
c)
d)
48.

Figure show an experiment to study viscosity of different types of motor oil. Arrange the test tube according to increasing viscosity.

a)

P<Q<R<S

b)

S<R<Q<P

c)

Q<<R<S<P

d)

S<R<Q<P

49.

2CrO42- + 2H+→Cr2O72- + H2O


What will happen when OH- ions are added to the system? HINT: They remove the H+ ions.

a)

Position of equilibrium will shift to right and become more orange

b)

Position of equilibrium will shift to left and become more yellow

c)

Position of equilibrium will shift to right and become more yellow

d)

OH- ions will not react, and thus no change is seen.

50.

2SO2(g) + O2(g) ⇌ 2SO3(g) + Heat


Using a catalyst

a)

shift equilibrium right

b)

shift equilibrium left

c)

increase the rate of reaction

d)

have no change

51.

Le Chatelier's Principle states when a chemical system is _______ it reattains ________ by undergoing a net reaction that reduces the effect of the disturbance. From the list below, select the respective words that are missing.

a)

disturb, equilibrium

b)

pressure, net

c)

pressure, equilibrium

d)

pressure, rest

52.

Which of the following reaction will shift its equilibrium position to the right when the volume of the container is decreased? 

a)

A

b)

B

c)

C

d)

D