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VSEPR theory and polarity practice

Total questions: 54

Worksheet time: 46mins

Name
Class
Date
1.
What is the VSEPR theory used to predict?
a)
Bond Strength
b)
Polarity
c)
Molecular Shape
d)
Electronegativity
2.
Which of the following shapes has an unshared pairs of electrons on the central atom? 
a)
Bipyramidal
b)
Bent
c)
Trigonal Planar
d)
Tetrahedral
3.

Which molecule would have this molecular geometry?

a)

BF3

b)

CH4

c)

PCl5

d)

CO2

4.
Who could this molecule be?
a)
CH4
b)
CO2
c)
PCl5
d)
BF3
5.
Who could this be? 
a)
CO2
b)
NH3
c)
H2S
d)
CH4
6.

Is this molecule polar?

a)

Yes

b)

No

7.

Is this molecule polar?

a)

No, there are four things around the central atom.

b)

Yes, the dipole moment (+-->)would point to the purple area that represents the unbonded pair of electrons.

8.
What is the the shape of this molecule according to VSPER theory?
a)
Linear
b)
Tetrahedral
c)
Trigonal Planar
d)
Trigonal pyramidal
9.
Choose the correct shape for this molecule:
a)
Trigonal planar
b)
Trigonal pyramidal
c)
Tetrahedral
d)
Linear
10.

Bond angle for bent. Look at your second reference chart.

a)

120o

b)

109.5o

c)

104.5o

d)

107o

11.
Pi bonds are formed by 
a)
side to side overlap of s orbitals
b)
end to end overlap of s orbitals
c)
side to side overlap of p orbitals
d)
end to end overlap of p orbitals
12.
How many sigma and pi bonds does this have?
a)
1 sigma and 1 pi
b)
2 sigma and 1 pi
c)
1 sigma and 2 pi
d)
2 sigma and 2 pi
13.
How many sigma and pi bonds does this have? 
a)
3 sigma and 2 pi
b)
5 sigma and 5 pi
c)
5 sigma and 0 pi
d)
0 sigma and 5 pi
14.
How many pi bonds are there in a single bond? 
a)
0
b)
1
c)
2
d)
3
15.

How many sigma bonds are in the following molecule?

a)

0

b)

1

c)

2

d)

3

16.

How many pi bonds are in the following compound?

a)

0

b)

1

c)

2

d)

3

17.

What is the hybridization of a linear molecule? Count the bonds and then figure out which hybrid gives you the same number of bonds.

a)

sp

b)

sp2

c)

sp3

d)

sp3d

18.

Which of the following bonds is least polar?

a)

C--O

b)

O--H

c)

S--Cl

d)

Br--Br

e)

I--F

19.

Which of the following molecules has a dipole moment? Remember that is when the molecule is polar. Write out the Lewis Dot and/or draw the 3D shape to figure this out.

a)

CO2

b)

SO2

c)

CH4

d)

I2

e)

none of these

20.

Of the following, which molecule has the largest bond angle based on their geometry and how far apart the attached atoms are?

a)

O3

b)

OF2

c)

HCN

d)

H2O

e)

more than one of these has equally large bond angles

21.
What is the shape of this molecule?
a)
Linear
b)
bent
c)
tetrahedral
d)
trigonal planar
22.
What is the shape of this molecule?
a)
Linear
b)
Bent
c)
Tetrahedral
d)
Trigonal Pyramidal
23.
What is the shape of this molecule?
a)
Linear
b)
Bent
c)
Tetrahedral
d)
Trigonal Planar
24.
Three pairs of electrons are shared in a
a)
Single bond
b)
Double bond
c)
Triple bond
25.

tetra

a)

six

b)

Four

c)

Five

d)

seven

26.
Bond angle for tetrahedral
a)
120o
b)
109.5o
c)
104.5o
d)
107o
27.
Bond angle for trigonal planar
a)
120o
b)
109.5o
c)
104.5o
d)
107o
28.
Bond angle for linear
a)
120o
b)
109.5o
c)
180o
d)
107o
29.

Does this molecule have polar bonds? Is the whole thing polar?

a)

Yes. No.

b)

Yes. Yes.

c)

No. Yes.

d)

No. No.

30.

Is this polar?

a)

No

b)

Yes, and you draw the dipole moment pointing toward the orange balls.

c)

Yes, and you draw the dipole moment pointing toward the purple areas.

d)

I can't tell because there are no atoms.

31.

IS this polar?

a)

No, there are 4 atoms attached.

b)

Yes, and you draw the dipole moment pointing toward the hydrogens because they are positive.

c)

Yes, and you draw the dipole moment toward the fluorine because it is very electronegative.

32.

Is this molecule polar?

a)

Yes, and you draw the dipole moment pointing between the white balls, the hydrogens.

b)

Yes, and you draw the dipole moment pointing between the green atoms, the fluorines.

c)

No, there are 4 atoms attached.

33.

Is this molecule polar?

a)

No, there are 4 atoms attached.

b)

Yes, and you draw the dipolement pointing toward the hydrogen.

c)

Yes, and you draw the dipole moment pointing in the middle of the bromines because they are more electronegative.

34.

In the middle is carbon. Is this molecule polar?

a)

Yes, and you draw the arrow (dipole moment) pointing between the Br because Br is more electronegative.

b)

Yes, and you draw the arrow (dipole moment) between a F and a Br to balance it out.

c)

Yes, and you draw the arrow (dipole moment) pointing between the Fs because F is more electronegative.

d)

No, there are 4 atoms attached and they are all very electronegative.

35.

What ways can you make a sigma bond? Click all that apply.

a)

S orbital to S orbital

b)

P orbital straight on to P orbital straight on

c)

P orbital parallel to P orbital

d)

S orbital to P orbital head on

36.

What is the strongest bond type?

a)

sigma

b)

Pi

37.
How many resonance structures for NO3- ion?
a)
1
b)
2
c)
3
d)
4
38.
What is the bond strength between N and O?
a)
N-O (Single bond)
b)
N=O (double bond)
c)
N Ξ O (Triple bond)
d)
N-O (between single and double bond)
39.
How many resonance structure for SO2 ?
a)
1
b)
2
c)
3
d)
4
40.
What is the bond strength between S and O?
a)
1
b)
1.5
c)
2
d)
3
41.

What is the picture showing?

a)

All of the resonance structures for carbonate.

b)

The formal charge on each atom in carbonate.

c)

The electronegativity for carbonate.

d)

The ionization energy for carbonate.

42.

Does this compound have a dipole moment?

a)

Yes

b)

No

43.

A nonpolar compound can only contain nonpolar bonds.

a)

True

b)

False

44.

We want to write the Lewis Diagram for the compound ClO3- (chlorine and oxygen). How many valence electrons are in this compound?

a)

28

b)

26

c)

27

d)

25

45.

molecule in which opposite ends have opposite electric charges

a)

cohesion

b)

nonpolar molecule

c)

solution

d)

polar molecule

46.

Opposite electrically charged areas _______________.

a)

repel each other

b)

attract each other

47.

A molecular geometry with 2 lone pairs and 2 bonding pairs is

a)

Tetrahedral

b)

Trigonal pyramidal

c)

Bent

d)

Linear

48.
Br & Br
a)
Ionic 
b)
Polar Covalent 
c)
Nonpolar Covalent 
49.

The two (2) factors that determine if a molecule is Polar or Non-polar:

a)

The atoms's ionization energy

b)

the type of atoms in the molecule

c)

The atom's oxidation number

d)

the shape of the molecule

50.
Define electronegativity
a)
ability to donate electron
b)
tendency to lose electron
c)
tendency to lose electron to its neighbor
d)
tendency of atom to attract shared electron to itself
51.
H2O is polar. Which statement is FALSE?
a)
Dipole moment is formed
b)
Partial separation of charges
c)
Net dipole moment
d)
Dipole moment cancel out each other
52.
CCl4 has polar bonds but is a non polar molecule. Why?
a)
bond polarity exist between atoms
b)
bond polarity between atoms cancel
c)
dipole moment exist between atoms in molecule
d)
difference in EN between C and Cl
53.

When you draw the direction of the dipole moment for the whole molecule (+-->) you draw the arrow pointing to what side?

a)

The negative end of the molecule

b)

The positive end of the molecule.

c)

The middle of the molecule.

54.
In this Lewis structure, the symbol above F means...
a)
electrons are being transferred to Fluorine
b)
electrons are less attracted to F than H
c)
electrons are more attracted to F than H
d)
Fluorine has formed a cation