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Topic 9 Redox

Total questions: 86

Worksheet time: 6hrs 16mins

Name
Class
Date
1.

The following occurs when metal X is added to Y sulfate solution and Z sulfate solution. (X, Y and Z represent metal elements but not their symbols.)

X (s) + YSO4 (aq) → XSO4 (aq) + Y (s)

X (s) + ZSO4 (aq): no reaction

What is the order of increasing reactivity?

a)

X < Y < Z

b)

Y < X < Z

c)

Z < Y < X

d)

Z < X < Y

2.

Which is the species oxidized and the oxidizing agent in the reaction?

MnO2 (s) + 4HCl (aq) → MnCl2 (aq) + Cl2 (g) + 2H2O (l)

a)

A

b)

B

c)

C

d)

D

3.

Which species contains nitrogen with the highest oxidation state?

a)

NO3

b)

NO2

c)

NO2

d)

N2O

4.

Which compound contains sulfur with an oxidation state of +6?

a)

SO2

b)

H2S

c)

H2SO3

d)

H2SO4

5.

Which is correct for the reaction?

P4 (s) + 3H2O (l) + 3OH (aq) → PH3 (g) + 3H2PO2 (aq)

a)

A

b)

B

c)

C

d)

D

6.

Which represents a reduction?

a)

SO3 to SO42−

b)

Mn2O3 to MnO2

c)

H2O2 to OH

d)

CrO42− to Cr2O72−

7.

Which equation shows oxygen undergoing reduction?

a)

2F2 + O2 → 2F2O

b)

Na2O + H2O → 2NaOH

c)

H2O2 + 2HI → 2H2O + I2

d)

2CrO42− + 2H+ ⇌ Cr2O72− + H2O

8.

Which coefficients correctly balance this redox equation?

aFe2+(aq) + MnO4(aq) + bH+(aq) →

cFe3+(aq) + Mn2+(aq) + dH2O(l)

a)

A

b)

B

c)

C

d)

D

9.

Which element has the same oxidation number in both species?

a)

C in C2H4 and CO2

b)

H in H2O and NaH

c)

S in SO42−and SO3

d)

O in H2O2 and H2O

10.

Which can describe oxidation?

a)

Loss of hydrogen

b)

Decrease in oxidation number

c)

Gain of electrons

d)

Loss of oxygen

11.

What are the oxidation states of chromium in (NH4)2Cr2O7 (s) and Cr2O3 (s)?

a)

A

b)

B

c)

C

d)

D

12.

Which of the following is a redox reaction?

a)

3Mg (s) + 2AlCl3 (aq) → 2Al (s) + 3MgCl2 (aq)

b)

SiO2 (s) + 2NaOH (aq) → Na2SiO3 (aq) + H2O (l)

c)

KCl (aq) + AgNO3 (aq) → AgCl (s) + KNO3 (aq)

d)

2NaHCO3 (aq) → Na2CO3 (aq) + CO2 (g) + H2O (l)

13.

What is the order of decreasing reactivity of the metals (most reactive first)?

Zn(s) + Sn2+(aq) → Zn2+(aq) + Sn(s)

Cu(s) + Zn2+(aq) → No Reaction

Sn(s) + Cu2+(aq) → Sn2+(aq) + Cu(s)

Ag(s) + Cu2+(aq) → No Reaction

a)

Zn > Cu > Sn > Ag

b)

Sn > Zn > Ag > Cu

c)

Ag > Cu > Zn > Sn

d)

Zn > Sn > Cu > Ag

14.

What is the oxidation half-equation in the redox reaction?

2S2O32–(aq) + I2(aq) → S4O62–(aq) + 2I(aq)

a)

I2(aq) + 2e → 2I(aq)

b)

2I(aq) → I2(aq) + 2e

c)

2S2O32–(aq) → S4O62–(aq) + 2e

d)

S4O62–(aq) + 2e → 2S2O32–(aq)

15.

Which of the following does not react with dilute HCl(aq)?

a)

Na2CO3

b)

Cu

c)

Zn

d)

CuO

16.

Which element is reduced in the following decomposition?

(NH4)2Cr2O7(s) → N2(g) + Cr2O3(s) + 4H2O(g)

a)

N

b)

H

c)

Cr

d)

O

17.

Which of the following is not a redox reaction?

a)

CH4(g) + Cl2(g) → CH3Cl(g) + HCl(g)

b)

C(s) + O2(g) → CO2(g)

c)

2CO(g) → CO2(g) + C(s)

d)

CH3COOH(aq) + NaOH(aq) → CH3COONa(aq) + H2O(l)

18.

Consider the above half-equations:

Which statement is correct for the reaction between KMnO4 (aq) and KI (aq) in acidic conditions?

a)

MnO4 reduces I to I2.

b)

I reduces MnO4 to Mn2+.

c)

The colour changes from brown to purple.

d)

MnO4 is oxidized to Mn2+.

19.

Which change represents oxidation?

a)

HClO4 to HClO3

b)

N2 to NH3

c)

N2O to NO

d)

SO42− to SO32−

20.

A reaction takes place when a rechargeable battery is used:

Pb(s) + PbO2(s) + 4H+(aq) + 2SO42−(aq) →

2PbSO4(s) + 2H2O(l)

Which statements are correct?

I. H+ is reduced

II. The oxidation state of Pb metal changes from 0 to +2

III. PbO2 is the oxidising agent

a)

I and II only

b)

I and III only

c)

II and III only

d)

I, II and III

21.

Which compounds can be reduced?

I. C2H4

II. CH3COOH

III. CH3CHO

a)

I and II only

b)

I and III only

c)

II and III only

d)

I, II and III

22.

Which experimental methods could be used to observe the progress of the following reaction?

Cr2O72-(aq) + 6I-(aq) + 14H+(aq) →

2Cr3+(aq) + 3I2(aq) + 7H2O(l)

I. Change in colour

II. Change in mass

III. Change in electrical conductivity

a)

I and II only

b)

I and III only

c)

II and III only

d)

I, II and III

23.

Applying IUPAC rules, what is the name of MnO2?

a)

Magnesium(II) oxide

b)

Manganese(II) oxide

c)

Magnesium(IV) oxide

d)

Manganese(IV) oxide

24.

Which is a correct statement for the reaction below?

2MnO4-(aq) + 6H+(aq) + 5NO2-(aq) →

2Mn2+(aq) + 5NO3-(aq) + 3H2O(l)

a)

MnO4- is the reducing agent and the oxidation number of Mn increases.

b)

MnO4- is the oxidizing agent and the oxidation number of Mn decreases.

c)

NO2- is the reducing agent and the oxidation number of N decreases.

d)

NO2- is the oxidizing agent and the oxidation number of N increases.

25.

Which represents a redox reaction?

a)

NaH(s)+H2O(l)→NaOH(aq)+H2(g)

b)

CaCO3(s)→CaO(s)+CO2(g)

c)

CuCl2(aq)+K2S(aq)→CuS(s)+2KCl(aq)

d)

HCl(aq)+NH3(aq)→NH+4CL(aq)

26.

Which species can oxidize ethanol to ethanoic acid?

a)

I

b)

Fe

c)

O2

d)

Acidified K2Cr2O

27.

What are the oxidation states of each element in K2CrO4?

a)

A

b)

B

c)

C

d)

D

28.

What is the coefficient for I when the following equation is balanced using the smallest possible whole numbers?

IO3(aq)+ ___ I(aq)+ ___ H+(aq)→ ___ I2(aq)+ ___ H2O(l)

a)

1

b)

2

c)

3

d)

5

29.

Which represents a redox reaction?

a)

NaH(s)+H2O(l)→NaOH(aq)+H2(g)

b)

CaCO3(s)→CaO(s)+CO2(g)

c)

CuCl2(aq)+K2S(aq)→CuS(s)+2KCl(aq)

d)

HCl(aq)+NH3(aq)→NH+4Cl−(aq)

30.

Which is a redox reaction?

a)

[Cu(H2O4]2+(aq) + 4Cl(aq) → [CuCl4]2−(aq) + 4H2O(l)

b)

Ag+(aq) + Cl(aq) → AgCl(s)

c)

Zn(s) + 2HCl(aq) → ZnCl2(aq) + H2(g)

d)

2K2CrO4(aq) + 2HCl(aq) → K2Cr2O7(aq) + H2O(l) + 2KCl(aq)

31.

Which species of vanadium has a different oxidation number from the rest?

a)

VO2+

b)

VO−3

c)

V2O5

d)

VO2+

32.

Which statement is correct for the following reaction?

2ClO3(aq) + SO2(aq) + H+(aq) →

2ClO2(g) + HSO4 (aq)

a)

ClO3 is the oxidizing agent and it undergoes reduction.

b)

ClO3 is the reducing agent and it undergoes oxidation.

c)

SO2 is the oxidizing agent and it undergoes oxidation.

d)

SO2 is the reducing agent and it undergoes reduction.

33.

At which side of the equation are electrons, H+ ions and H2O needed to complete the half-equation?

MnO4(aq) → Mn2+(aq)

a)

A

b)

B

c)

C

d)

D

34.

What are the correct names for KMnO4 and K2Cr2O7, using oxidation numbers?

a)

Potassium permanganate and potassium dichromate

b)

Potassium manganate(IV) and potassium chromate(VII)

c)

Potassium permanganate(IV) and potassium dichromate(VII)

d)

Potassium manganate(VII) and potassium dichromate(VI)

35.

What are the correct oxidation numbers of chromium in Cr2O72− and manganese in KMnO4?

a)

A

b)

B

c)

C

d)

D

36.

Which species are the oxidizing and reducing agents in the following reaction?

SO32−(aq)+PbO2(s)+H2O(l)→SO42−(aq)+Pb(OH)2(s)

a)

A

b)

B

c)

C

d)

D

37.

What is the name of Co3(PO4)2?

a)

Cobalt(II) phosphite

b)

Cobalt(II) phosphate

c)

Cobalt(III) phosphite

d)

Cobalt(III) phosphate

38.

Consider the following reaction.

Sn(s)+4HNO3(aq)→SnO2(s)+4NO2(g)+2H2O(g)

Which statement is correct?

a)

HNO3 is the oxidizing agent because it undergoes oxidation.

b)

HNO3 is the reducing agent because the oxidation number of nitrogen changes from +5 to +4.

c)

Sn is the oxidizing agent because it undergoes reduction.

d)

Sn is the reducing agent because the oxidation number of tin changes from 0 to +4.

39.

Which statement is correct about a reducing agent?

a)

It is reduced by gaining electrons.

b)

It is oxidized by gaining electrons.

c)

It is oxidized by losing electrons.

d)

It is reduced by losing electrons.

40.

What is the correct increasing order of reactivity of the metals X, Y and Z based on the following information?

XCl2 + Y → YCl2X

ZCl2 + X → XCl2Z

YCl2 + Z → no reaction

a)

Z < X < Y

b)

Y < X < Z

c)

Z < Y < X

d)

X < Z < Y

41.

Which statement describes a reducing agent?

a)

It is reduced and gains electrons.

b)

It is reduced and loses electrons.

c)

It is oxidized and gains electrons.

d)

It is oxidized and loses electrons.

42.

Which is the oxidizing agent in the following reaction?

5SO2(g) + 2IO3(aq) + 4H2O(l) →

5SO42−(aq) + I2(aq) + 8H+(aq)

a)

SO2

b)

IO3

c)

H2O

d)

SO42−

43.

Consider the following reaction.

2Cr(OH)3(s) + 6ClO(aq) →

2CrO42−(aq) + 3Cl2 (g) + 2OH(aq) + 2H2O(l)


Which statement is correct?

a)

Cr(OH)3 is the oxidizing agent and the oxidation number of chromium changes from +3 to +6.

b)

Cr(OH)3 is the reducing agent and undergoes reduction.

c)

ClO is the oxidizing agent and the oxidation number of chlorine changes from +1 to 0.

d)

ClO is the reducing agent and the oxidation number of chlorine changes from –1 to 0.

44.

What is the name of Cu2S?

a)

Copper(I) sulfide

b)

Copper(I) sulfate

c)

Copper(II) sulfide

d)

Copper(II) sulfate

45.

Consider the following reaction:

3(aq) + Cr2O72−(aq) + 2H+(aq) →

2Cr3+(aq) + 3SnO2(s) + H2O(l)


Which statement is correct?

a)

Sn2+ is the oxidizing agent because it undergoes oxidation.

b)

Sn2+ is the reducing agent because it undergoes oxidation.

c)

Cr2O72− is the oxidizing agent because it undergoes oxidation.

d)

Cr2O72− is the reducing agent because it undergoes oxidation.

46.

What is the correct decreasing order of reactivity of the metals X, Y and Z based on the following equations?

XCl + Y → YCl + X

YCl + Z → YCl + Z

ZCl + X → XCl + Z

a)

X > Y > Z

b)

Y > Z > X

c)

Z > Y > X

d)

Y > X > Z

47.

Which of the following redox reactions take place?

I. Cl2(aq) + 2NaI(aq) → I2(aq) + 2NaCl(aq)

II. Br2(aq) + 2NaI(aq) → I2(aq) + 2NaBr(aq)

III. I2(aq) + 2NaBr(aq) → Br2(aq) + 2NaI(aq)

a)

I and II only

b)

I and III only

c)

II and III only

d)

I, II and III

48.

Which species could be reduced to form NO2?

a)

N2O

b)

NO−3

c)

HNO2

d)

NO

49.

What happens to the manganese in the following reaction?

2MnO4(aq) + 5H2O2(aq) + 6H+(aq) →

2Mn2+(aq) + 8H2O(l) + 5O2(g)

a)

It is oxidized and its oxidation number increases.

b)

It is oxidized and its oxidation number decreases.

c)

It is reduced and its oxidation number increases.

d)

It is reduced and its oxidation number decreases.

50.

What happens to iodine when iodate ions, IO3, are converted to iodine molecules, I2?

a)

It undergoes reduction and its oxidation number changes from −1 to 0

b)

It undergoes oxidation and its oxidation number changes from −1 to 0

c)

It undergoes reduction and its oxidation number changes from +5 to 0

d)

It undergoes oxidation and its oxidation number changes from +5 to 0

51.

Consider the following reactions of three unknown metals X, Y and Z.

2XNO3(aq) + Y(s) → 2X(s) + Y(NO3)2((aq)

Y(NO3)2(aq) + Z(s) → No reaction

2XNO3(aq) + Z(s) → 2X(s) +Z (NO3)2((aq)


What is the order of increasing reactivity of the metals (least reactive first)?

a)

X < Y < Z

b)

X < Z < Y

c)

Z < Y < X

d)

Y < Z < X

52.

What is the correct order of reaction types in the following sequence?

a)

A

b)

B

c)

C

d)

D

53.

Consider the following reaction.

MnO4(aq) + 8H+(aq) + 5Fe2+(aq) →

Mn2+(aq) + 5Fe3+(aq) + 4H2O(l)


Which statement is correct?

a)

MnO4 is the oxidizing agent and it loses electrons.

b)

MnO4 is the reducing agent and it loses electrons.

c)

MnO4 is the oxidizing agent and it gains electrons.

d)

MnO4 is the reducing agent and it gains electrons.

54.

In which species does sulfur have an oxidation number of 0?

a)

SO3

b)

S8

c)

Na2SO4

d)

H2S

55.

What is the reducing agent in the reaction below?

2MnO4(aq) + Br(aq) + H2O(l) →

2MnO2(s) + BrO3(aq) + 2OH(aq)

a)

Br

b)

BrO3

c)

MnO4

d)

MnO2

56.

The following equations indicate reactions that occur spontaneously.

Fe(s) + NiCl2(aq) → FeCl2(aq) + Ni(s)

Zn(s) + FeCl2(aq) → ZnCl2(aq) + Fe(s

Ni(s) + PbCl2(aq) → NiCl2(aq) + Pb(s)


Which is the increasing order of the reactivity of the metals?

a)

Fe < Ni < Zn < Pb

b)

Pb < Ni < Fe < Zn

c)

Ni < Zn < Pb < Fe

d)

Zn < Fe < Ni < Pb

57.

Which are redox reactions?

I. 2FeCl2 + Cl2 → 2FeCl3

II. Mg + 2HNO3 → Mg(NO3)2 + H2

III. H2O + SO3 → H2SO4

a)

I and II only

b)

I and III only

c)

II and III only

d)

I, II and III

58.

Metal M has only one oxidation number and forms a compound with the formula MCO3. Which formula is correct?

a)

MNO3

b)

MNH4

c)

MSO4

d)

MPO4

59.

Which species is oxidized in the following reaction?

2Ag+(aq) + Cu(s) → 2Ag(s) + Cu2+(aq)

a)

Ag+

b)

Cu

c)

Ag

d)

Cu2+

60.

Which list represents the halogens in increasing order of oxidizing strength (weakest oxidizing agent first)?

a)

Cl2 - I2 - Br2

b)

I2 - Br2 - Cl2

c)

I2 - Cl2 - Br2

d)

Cl2 - Br2 - I2

61.

What is formed at the electrodes during the electrolysis of molten sodium bromide?

a)

A

b)

B

c)

C

d)

D

62.

Where does oxidation occur in a voltaic cell?

a)

positive electrode and anode

b)

negative electrode and anode

c)

positive electrode and cathode

d)

negative electrode and cathode

63.

Which product will be obtained at the anode (positive electrode) when molten NaCl is electrolysed?

a)

Na (l)

b)

Cl (g)

c)

Cl2 (g)

d)

Na (s)

64.

Consider this electrochemical cell. What happens to the ions in the salt bridge when a current flows?

a)

Na+ ions flow to the zinc half-cell and SO42− ions flow to the copper half-cell.

b)

Na+ ions flow to the copper half-cell and SO42− ions flow to the zinc half-cell.

c)

Na+ and SO42− ions flow to the copper half-cell.

d)

Na+ and SO42− ions flow to the zinc half-cell.

65.

This reaction occurs in a voltaic (galvanic) cell.

Mg (s) + 2Ag+ (aq) → Mg2+ (aq) + 2Ag (s)

Which reaction takes place at each electrode?

a)

A

b)

B

c)

C

d)

D

66.

What are the products of electrolysis of concentrated aqueous sodium bromide?

a)

A

b)

B

c)

C

d)

D

67.

Which product will be obtained at the anode (positive electrode) when molten NaCl is electrolysed?

a)

Na (l)

b)

Cl (g)

c)

Cl2 (g)

d)

Na (s)

68.

Where does oxidation occur in a voltaic cell?

a)

positive electrode and anode

b)

negative electrode and anode

c)

positive electrode and cathode

d)

negative electrode and cathode

69.

The following reaction occurs in a voltaic (galvanic) cell.

Mg (s) + 2Ag+ (aq) → Mg2+ (aq) + 2Ag (s)

Which reaction takes place at each electrode?

a)

A

b)

B

c)

C

d)

D

70.

Which describes the flow of electrons in a voltaic cell?

a)

From the cathode (positive electrode) to the anode (negative electrode) through the external circuit

b)

From the anode (negative electrode) to the cathode (positive electrode) through the external circuit

c)

From the oxidizing agent to the reducing agent through the salt bridge

d)

From the reducing agent to the oxidizing agent through the salt bridge

71.

What are the products of electrolysis when molten calcium bromide is electrolysed using graphite electrodes?

a)

A

b)

B

c)

C

d)

D

72.

What are the products of the electrolysis of molten zinc bromide?

a)

A

b)

B

c)

C

d)

D

73.

What is the reaction type and major product at the anode (positive electrode) when molten sodium chloride is electrolysed using platinum electrodes?

a)

A

b)

B

c)

C

d)

D

74.

Which statements are correct for a voltaic cell?

I. A spontaneous redox chemical reaction produces electrical energy.

II. Oxidation occurs at the cathode (negative electrode).

III. Electrons flow from anode (negative electrode) to cathode (positive electrode).

a)

I and II only

b)

I and III only

c)

II and III only

d)

I, II and III

75.

What occurs at the anode (positive electrode) during the electrolysis of molten strontium bromide?

a)

Formation of bromine and oxidation

b)

Formation of bromine and reduction

c)

Formation of strontium and oxidation

d)

Formation of strontium and reduction

76.

A voltaic cell is constructed from zinc and copper half-cells. Zinc is more reactive than copper. Which statement is correct when this cell produces electricity?

a)

Electrons flow from the copper half-cell to the zinc half-cell.

b)

The concentration of Cu2+ (aq) increases.

c)

Electrons flow through the salt bridge.

d)

Negative ions flow through the salt bridge from the copper half-cell to the zinc half-cell.

77.

Which statement is correct for a voltaic but not for an electrolytic cell?

a)

An electrolyte is required.

b)

The anode is where oxidation occurs.

c)

Electrons flow from the negative electrode to the positive electrode.

d)

Electrons flow from the negative electrode to the positive electrode.

78.

Two half-cells are connected via a salt bridge to make a voltaic cell. Which statement about this cell is correct?

a)

Oxidation occurs at the positive electrode (cathode).

b)

It is also known as an electrolytic cell.

c)

Ions flow through the salt bridge.

d)

It requires a power supply to operate.

79.

A voltaic cell is made by connecting a copper half-cell,

Cu(s) ∣ Cu2+(aq), to an iron half-cell Fe(s) ∣ Fe2+(aq).

Which combination correctly identifies the positive electrode and the species being oxidized?

a)

Copper is the positive electrode; Iron is oxidized

b)

Copper is the positive electrode; Copper (II) ions are oxidized

c)

Iron is the positive electrode; Copper is oxidized

d)

Iron is the positive electrode; Copper (II) ions are oxidized

80.

Which statement about an electrolytic cell is correct?

a)

Chemical energy is converted to electrical energy.

b)

Electrons move through the electrolyte.

c)

The cathode is the negative electrode.

d)

The negative ions move towards the negative electrode.

81.

At which electrodes does oxidation occur in a voltaic cell and in an electrolytic cell?

a)

A

b)

B

c)

C

d)

D

82.

Zinc is more reactive than copper. In this voltaic cell, which species is reduced and in which direction do negative ions flow in the salt bridge?

a)

Cu2+ is reduced; negative ions flow from copper half-cell to zinc half-cell

b)

Cu2+ is reduced; negative ions flow from zinc half-cell to copper half-cell

c)

Zn2+ is reduced; negative ions flow from copper half-cell to zinc half-cell

d)

Zn2+ is reduced; negative ions flow from zinc half-cell to copper half-cell

83.

Which process occurs when a molten salt is electrolysed?

a)

The metal ion is oxidized and deposited on the negative electrode (cathode).

b)

The metal ion is reduced and deposited on the negative electrode (cathode).

c)

The metal ion is oxidized and deposited on the positive electrode (anode).

d)

The metal ion is reduced and deposited on the positive electrode (anode).

84.

Which species are produced at each electrode during the electrolysis of molten lead(II) bromide, PbBr2(l)?

a)

A

b)

B

c)

C

d)

D

85.

Which statements are correct for the electrolysis of molten lead(II) bromide, PbBr2(l)?

I. Pb2+ is reduced at the negative electrode (cathode).

II. Br is oxidized at the positive electrode (anode).

III. Bubbles of a brown gas are observed at the negative electrode (cathode).

a)

I and II only

b)

I and III only

c)

II and III only

d)

I, II and III

86.

Which are correct statements about a voltaic cell?

I. A spontaneous redox reaction occurs which converts chemical energy to electrical energy.

II. Oxidation occurs at the negative electrode (anode).

III. Electricity is conducted by the movement of electrons through the salt bridge.

a)

I and II only

b)

I and III only

c)

II and III only

d)

I, II and III