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WorksheetsAP MCQ-alooza
Total questions: 125
Worksheet time: 3hrs 8mins
Which of the following has the glassware from most (top) to least (bottom) precise?
Beaker
Graduated cylinder
Burette
Burette
Graduated cylinder
Beaker
Graduated cylinder
Beaker
Burette
Graduated cylinder
Volumetric flask
Beaker
Given the following: 42.07% Na, 18.89% P, and 39.04% O, determine the empirical formula.
NaPO2
Na2PO3
Na3PO4
NaPO4
1s22s22p63s2
What element has the following mass spec data?
Sulfur
Nitrogen
Oxygen
Carbon
Based on the mass spec data, which Iron isotope is the most abundant?
Fe-54
Fe-56
Fe-57
Fe-58
The PES spectrum below is for the element _______________.
O
Ne
N
F
What does the 4th peak from the left represent?
The 2s electrons
The 3d electrons
The 2p electrons
The 3s electrons
Which peak (or peaks) correspond to the valence electrons?
The peak at 1
The peaks at 1 and 2.05
The peak at 239
The peaks at 239 and 22.7
Which of the following pairs of elements could NOT react to form an ionic compound?
Carbon and Oxygen
Potassium and Fluorine
Silver and Oxygen
Aluminum and Chlorine
Which of the following is NOT a property of ionic compounds?
They conduct electricity when molten
They conduct electricity when in solution
They have high boiling points
They are insoluble in water
In this molecule, Carbon has a formal charge of ____ and Nitrogen has a formal charge of _____.
0, 0
1, 0
0, -1
-1, 0
What type of alloy is this?
Interstitial
Substitutional
What is the bond angle in BF3?
90
120
109.5
180
What is the hybridization of carbon in CH4?
sp3
sp
sp2
Count the number of sigma and pi bonds in this molecule:
13 sigma, 1 pi
14 sigma, 2 pi
1 sigma, 14 pi
2 sigma, 13 pi
When a molecular solid melts or boils, which breaks?
Intermolecular forces
Intramolecular bonds
Chromatography separates mixtures based on what property?
particle size
intermolecular forces
boiling points
state of matter
In paper chromatography, if water is the mobile phase, what kind of substance will move up the farthest?
polar substance
non polar substance
List the 4 Intermolecular forces from weakest to strongest
hydrogen bonding, ion-dipole, london dispersion, dipole dipole
london dispersion, hydrogen bonding, ion-dipole, dipole dipole
london dispersion, dipole dipole, hydrogen bonding, ion-dipole
dipole dipole, hydrogen bonding, ion-dipole, london dispersion
“More polarizable” refers to which Intermolecular Force?
hydrogen bonding
london dispersion
dipole dipole
The dotted line is a representation of a hydrogen bond.
True
False
Name a property that decreases as Intermolecular Forces increase.
Vapor pressure
Conductivity
Melting point
Solubility
What is an example of a covalent network solid?
Salt
Diamond
Sugar
Water
What type of alloy is made when the radii of one element are similar in size with the other element making up the alloy?
interstitial
substitutional
What causes gas pressure?
large space between the molecules
random motion of particles
collisions with the walls of the container
The more molar mass a gas has, the_________________ it moves
faster
slower
Real gases behave most like an ideal gas at what conditions of temperature and pressure?
High T, Low P
High P, Low T
High V, Low T
Under STP, how many liters is 1 mol?
1 L
11.2 L
22.4 L
6.02 x 1023 L
Which of the following will be the least soluble in water?
CH3CH2CH2OH
CH3OH
CH3CH2OH
None of them are soluble in water.
They are all equally soluble in water.
What is a limiting reactant?
The reactant that runs out first
The reactant that has the lowest mass
The reactant with the smallest coefficient
The reactant with the lowest molar mass
1.What type of reaction is this?
3O2 + 2FeCl3 --> 2Fe2O3 + 3Cl2
Single Displacement
Decomposition
Double Displacement
Combustion
What formula do we use for dilution calculations?
M1V1=M2V2
D=m/V
V1=M2
Total Volume/Partial Volume
What is the oxidation number of P in PO43-?
0
4
5
-2
What is the oxidation number of N in NO21-?
0
-1
2
3
Which of the following represents the net ionic equation for the precipitation reaction between sodium carbonate and magnesium sulfate?
Na2CO3 + MgSO4 --> MgCO3 + Na2SO4
2Na+ + CO3-2 + Mg+2 + SO4-2 --> Mg+2 + CO3-2 + 2Na+ + SO4-2
2Na+ + SO4-2 --> Na2SO4
CO3-2 + Mg+2 --> MgCO3
Chemical or physical change? H2O(l) → H2O(g)
Chemical
Physical
Boiling is an example of a __________
Physical change because bonds are broken
Physical change because IMFs are overcome
Chemical change because bonds are broken
Chemical change because IMFs are overcome
An acid is defined as a...
proton donor
proton acceptor
In the following example, CH3CH2COOH(aq) + H2O(l) ⇄ CH3CH2COO-(aq) + H3O+(aq) what would be considered a conjugate acid-base pair?
CH3CH2COOH(aq) and H2O(l)
CH3CH2COO-(aq) and H3O+(aq)
CH3CH2COO-(aq) and CH3CH2COOH(aq)
CH3CH2COOH(aq) and H3O+(aq)
Which of the following represent a Brønsted-Lowry conjugate acid-base pair?
HF and H2O
NaOH and H2O
HF and NaOH
HF and F-
which element, if any, is oxidized?
How many moles of oxygen are produced when 6.7 moles of KClO3 decompose completely?
How many moles of water can be produced if 8 moles H2 are used?
Percent yield=(________)÷(________)×100%
What is the unit for the rate constant (k) for 2nd order reactions?
s-1
M/s
M-1s-1
How does a catalyst speed up a reaction?
Adding more reactant
Providing a pathway that has a lower activation energy
Increasing the activation energy
Increasing binding energy
What are the 2 characteristics that an effective collision must have? SELECT TWO
Enough energy to overcome Ea
Molecules in the correct orientations
High enough temperature
Apporpriate intermediates present
What is the rate law for the reaction with this slow elementary step? A + A --> B + B
rate = k[A]2
rate = k[B]2
rate = k[A][B]
rate = k[A]
Which curve represents the most particles in this Maxwell-Boltzmann curve (# of particles vs. speed)?
Black (peak on the left)
Red (peak in the middle)
Blue (peak on the right)
They all have the same number of particles
How are the exponents n and m determined?
step 2: O3 + O → 2 O2
The oxygen atom (O) is considered to be a(n)...
Mechanisms in which one elementary step is followed by another are very common.
step 1: A + B → Q
step 2: B + Q → C
net reaction: A + 2B → C
Which of the following is false?
(CH3)3CBr(aq) + OH-(aq) → (CH3)3COH(aq) + Br-(aq)
What will the initial rate (in mol/L*s) be in Experiment 4?
What is the rate law for this reaction?
rate = k[X]0
rate = k[X]
rate = k[X]2
rate = -k[X]2
In an exothermic reaction, the sign of ΔH is ____ and the reaction feels ______
(-), hot
(+), hot
(-), cold
(+), cold
Freezing is an _________________________ process
Endothermic
Exothermic
Breaking bonds is _________________. Forming bonds is ______________________
endothermic, exothermic
exothermic, endothermic
According to Hess' Law, if you double the coefficients of a reaction, ΔH will ________________________
Stay the same
Double
Quadruple
Halve
According to Hess' Law, if you reverse a reaction, ΔH will ________________________
Change signs
Double
Be inversed
Halve
What are the units of ΔHrxn?
kJ
J
kJ/mol
J/mol
A temperature is placed in a calorimeter. A solid is dissolved in water in the calorimeter and the temperature of the thermometer increases. The dissolution reaction must be
endothermic
exothermic
Using bond energies to solve for enthalpy,
ΔH = Bond broken - bonds formed
undefined = Bond formed- bonds broken
undefined = products - reactants
undefined = reactants- products
2N2 + 3H2 --> 2NH3 + 46 kJ
How much energy would be produced if only 1 mol of nitrogen was reacted?
Which substance would experience the biggest temperature change if each sample absorbed the same energy?
100 grams of water
25 grams of water
5 grams of water
2500 grams of water
Is this reaction endothermic or exothermic?
H-H = 436
Cl-Cl = 242
H-Cl = 431
What is the enthalpy change for the decomposition of hydrogen chloride?
2 HCl --> H2 + Cl2
At equilibrium, rates of the forward and reverse reaction are...
The same
Not the same
At equilibrium, concentrations of reactants and products are
equal
constant
At what time does the system first reach equilibrium?
24s
40s
60s
80s
Which substance(s) would not be included in a equilibrium constant expression?
NaCl(s)
NaCl(aq)
NaCl(l)
NaCl(g)
If a K value is greater than 1,
more products are present at equilibrium
more reactants are present at equilibrium
If a K value is VERY large,
the reaction has essentially gone to completion
there are more reactants present at equilibrium
If K < Q, the reaction will proceed in the...
reverse direction to reach equilibrium
forward direction to reach equilibrium
When a reaction at equilibrium is reversed,
the K value's sign is flipped
the K value is divided by 2
the K value is inverted
To calculate the K of an overall reaction from individual reaction K values, the individual K values are
added
subtracted
multiplied
divided
Given the following equilibrium equation,
A (g) + 2B (g) ⇄ AB2 (g) ΔH > 0, which of the following changes will increase the amount of AB2 in the vessel?
Decreasing the temperature
Increasing the concentration of A
Removing a small amount of B
Decreasing the pressure
Given the following equilibrium equation,
A (g) + 2B (g) ⇄ AB2 (g) ΔH < 0, which of the following changes will decrease the amount of AB2 in the vessel?
Increasing the temperature
Increasing the concentration of A
Increasing the pressure
Adding a catalyst
In a Ksp expression, we always assume that the reactant is made up of
the solid precipitate
the aqueous ions
If Ksp >1, we say the salt is...
soluble
insoluble
If a common ion is present, the solubility of a salt
is increased
is decreased
will remain the same
([H3O] / [HA]) x 100 OR ([OH] / [B]) x 100
Equations for % Ionization
Equations for pH
Equations for nothing
If pH=3.70, [OH]=?. Is the solution acidic, basic, or neutral
5 x 10^-11
Acidic
2 x 10^-14
Acidic
11.5
Basic
14
Basic
If [H] = 1 x10^-7, pH= ?. Is the solution acidic, basic, or neutral
7
Neutral
2.3
Acidic
11.34
Basic
7.5
Basic
a buffer solution is made of mixture of aqueous methanoic acid, HCOOH, with aqueous sodium methanoate, NaHCOO.
the equilibrium reaction takes place in buffer solution is :
HCOOH ↔ HCOO- + H+
small amount of NaOH is then added to that buffer solution.
What reaction take places at the buffer solution to resist change of pH caused by addition of base?
HCOOH + H+ → HCOOH2
HCOO- + H+ → HCOOH
HCOOH + OH- → HCOO- + H2O
HCOO- + OH- → COO2- + H2O
Which has the HIGHEST entropy change?
1 --> 2 particles
gas --> liquid
solid --> gas
low to high temperature (same phase)
Which has a positive sign for S?
2Na (s) + Cl2 (g) --> 2NaCl (s)
H2O (g) --> H2O (l)
H+ (aq) + NO3- (aq) --> HNO3 (l)
CaCl2 (s) --> Ca2+ (aq) + 2Cl- (aq)
reaction is ALWAYS spontaneous
- H, - S
+ H, + S
+ H, - S
- H, + S
If a reaction occurs, then delta G is
negative
positive
can't tell
0
Thermodyncamically unfavorable reactions where cathode and anonde are in the same chamber; Power source needed but no salt bridge
Galvanic Cell
Electrolytic Cell
The answer is not here
If ΔG is zero
Favorable
Unfavorable
Equilibrium
An Increase in Q means an ______ in Ecell
Decrease
Increase
No Change
What is a cathode?
It is the electrode where oxidation takes place.
It is the electrode where reduction takes place.
It is an aqueous solution containing an electrode.
It is the salt bridge that connects half-cells.
What is an anode?
It is the electrode where oxidation takes place.
It is the electrode where reduction takes place.
It is an aqueous solution containing an electrode.
It is the salt bridge that connects half-cells.
A student is preparing solutions for a laboratory experiment by dissolving solid solutes in liquid solvents. Which action will increase the rate of solubility
lowering the temperature of the solvent
stirring the solute in the solution
increasing the pressure on the solution
increasing the particle size of the solute
