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WorksheetsIB Chemistry HL Review
Total questions: 140
Worksheet time: 4hrs 31mins
What compound is formed when lithium reacts with selenium?
LiSe
Li2Se
LiSe2
Li2Se2
Which molecule contains a bond angle of approximately 120°?
CH4
C2H2
C2H4
C2H6
Which compound does not form hydrogen bonds between its molecules?
CH3NH2
CH3COCH3
CH3COOH
CH3CH2OH
Which is the best description of the bonding present in silicon dioxide, SiO2?
Each silicon atom forms four single covalent bonds to oxygen atoms.
Each silicon atom forms two double covalent bonds to oxygen atoms.
Each silicon atom forms two single covalent bonds to oxygen atoms.
Each silicon atom forms four double covalent bonds to oxygen atoms.
Which statement best describes the intramolecular bonding in HCN(l)?
Electrostatic attractions between H+ and CN- ions
Only van der Waals’ forces
Van der Waals’ forces and hydrogen bonding
Electrostatic attractions between pairs of electrons and positively charged nuclei
Metal M has only one oxidation number and forms a compound with the formula MCO3. Which formula is correct?
MNO3
MNH4
MSO4
MPO4
Which molecule has the shortest bond between carbon atoms?
C2H6
C2H4
C2H2
C2H4Cl2
What is the bond angle in the H3O+ ion?
104°
107°
109°
120°
Which molecule contains a dative covalent (coordinate) bond?
HCN
H2O2
CO2
CO
Which structure has delocalized electrons?
O3
CO
HCN
CO2
What is the formula of magnesium fluoride?
Mg2F3
Mg2F
Mg3F2
MgF2
What is the shape of the ammonia molecule, NH3?
Trigonal planar
Trigonal pyramidal
Linear
V-shaped (bent)
Which molecule is polar?
CH2Cl2
BCl3
Cl2
CCl4
Which compound has a covalent macromolecular (giant covalent) structure?
MgO
Al2O3
P4O10
SiO2
Which molecule has an octahedral shape?
SF6
PCl5
XeF4
BCl3
Which compound forms hydrogen bonds in the liquid state?
C2H5OH
CHCl3
CH3CHO
(CH3CH2)3N
Which molecule has a non-bonding (lone) pair of electrons on the central atom?
BF3
SO2
CO2
SiF4
The number of electrons in the valence shell of elements A and B, are 6 and 7 respectively. What is the formula and type of bonding in a compound formed by these elements?
A2B, covalent
AB2, covalent
A2B, ionic
AB2, ionic
Which species does not contain delocalized electrons?
CH3CH2O-
CH3CO2-
O3
NO3-
What is the formula of the ionic compound formed when calcium and nitrogen react together?
Ca2N3
Ca3N2
Ca5N2
Ca2N5
Diamond, C60 fullerene and graphite are allotropes of carbon. Which statements are correct about these allotropes?
I. In diamond each carbon is held in a tetrahedral arrangement.
II. In C60 fullerene each carbon is held in a trigonal arrangement.
III. In graphite each carbon is held in a tetrahedral arrangement.
I and II only
I and III only
II and III only
I, II and III
Which species contain dative covalent bonds?
I. CO
II. NH3
III. H3O+
I and II only
I and III only
II and III only
I, II and III
Which compounds have an ionic lattice structure in the solid state?
I. Silicon dioxide
II. Sodium fluoride
III. Ammonium nitrate
I and II only
I and III only
II and III only
I, II and III
Which statements are correct about hydrogen bonding?
I. It is an electrostatic attraction between molecules.
II. It is present in liquid ammonia.
III. It is a permanent dipole-permanent dipole attraction.
I and II only
I and III only
II and III only
I, II and III
Which non-metal forms an oxide XO2 with a relative molecular mass of 60?
C
N
Si
S
4.00 mol of a hydrocarbon with an empirical formula of CH2
has a mass of 280 g. What is the molecular formula of this compound?
C2H4
C3H6
C4H10
C5H10
Which are likely to be reduced when an experiment is repeated a number of times?
Random errors
Systematic errors
Both random and systematic errors
Neither random nor systematic errors
The molar mass of a compound is approximately 56 g
mol−1. Which formula is possible for this compound?
NaNO3
AgOH
MgO
KOH
Which compound has the empirical formula with the largest mass?
C2H6
C2H4
C2H2
C3H6
What is the coefficient for O2(g) when the equation for the combustion of 1 mole of pentane is balanced?
C5H12(g) + _ O2(g) --> _ CO2(g) + _ H2O(g)
5
6
8
16
A student recorded the volume of a gas as 0.01450 dm3. How many significant figures are there in this value?
3
4
5
6
What is the maximum mass, in g, of magnesium oxide that can be obtained from the reaction of oxygen with 2.4 g of magnesium?
2.4
3.0
4.0
5.6
Which would be the best method to decrease the random uncertainty of a measurement in an acid-base titration?
Repeat the titration
Ensure your eye is at the same height as the meniscus when reading from the burette
Use a different burette
Use a different indicator for the titration
What is the sum of the coefficients that would balance this equation?
__ MnO2 + __ HCl → __ MnCl2 + __ Cl2 + __ H2O
6
7
9
10
What volume of carbon dioxide, in dm3 under standard conditions, is formed when 7.00 g of ethene (C2H4, Mr=28.1) undergoes complete combustion?
C2H4 + 3O2 --> 2CO2 + 2H2O
(22.4 × 28.1) / 7.00
(22.4 × 7.00) / 28.1
(2 × 22.4 × 7.00) / 28.1
(2 × 22.4 × 7.00) / 28.1
What is the total number of nitrogen atoms in two mol of NH4NO3?
4
6.02 × 1023
1.20 × 1024
2.41 × 1024
On analysis, a compound with molar mass 60 gmol−1 was found to contain 12 g of carbon, 2 g of hydrogen and 16 g of oxygen. What is the molecular formula of the compound?
CH2O
CH4O
C2H4O
C2H4O2
Density can be calculated by dividing mass by volume. 0.20±0.02 g of a metal has a volume of 0.050±0.005 cm3. How should its density be recorded using this data?
4.0 ± 0.025 gcm−3
4.0 ± 0.8 gcm−3
4.00 ± 0.025 gcm−3
4.00 ± 0.8 gcm−3
What is the coefficient of Fe3O4 when the following equation is balanced using the lowest whole numbers?
__ Al(s) + __ Fe3O4(s) → __ Al2O3(s) + __ Fe(s)
2
3
4
5
What is the mass, in g, of one molecule of ethane, C2H6?
3.0 × 10−23
5.0 × 10−23
30
1.8 × 1025
Which molecular formula is also an empirical formula?
PCl3
C2H4
H2O2
C6H12O6
How many significant figures are there in 0.00370?
2
3
5
6
A sample of element X contains 69% of 63X and 31% of 65X. What is the relative atomic mass of X in this sample?
63.0
63.6
65.0
69.0
What is the sum of the coefficients when the following equation is balanced using whole numbers?
___ Fe2O3(s) + ___ CO(g) → ___ Fe(s) + ___ CO2(g)
5
6
8
9
A student heated a solid in a crucible. The student measured the mass of the solid and crucible before and after heating and recorded the results.
Mass of crucible and solid before heating = 101.692 g
Mass of crucible and solid after heating = 89.312 g
What value should the student record for the mass lost in grams?
12.4
12.38
12.380
12.3800
What is the sum of all coefficients when the following equation is balanced using the smallest possible whole numbers?
__ C2H2 + __ O2 → __ CO2 + __ H2O
5
7
11
13
How many molecules are present in a drop of ethanol, C2H5OH, of mass 2.3×10−3 g?
(L = 6.0 × 1023 mol−1)
3.0 × 1019
3.0 × 1020
6.0 × 1020
6.0 × 1026
A burette reading is recorded as 27.70 ± 0.05 cm3. Which of the following could be the actual value?
I. 27.68 cm3
II. 27.78 cm3
III. 27.74 cm3
I and II only
I and III only
II and III only
I, II and III
Which sample has the greatest mass?
1 mol of SO2
2 mol of N2O
2 mol of Ar
4 mol of NH3
The relative molecular mass of a gas is 56 and its empirical formula is CH2. What is the molecular formula of the gas?
CH2
C2H4
C3H6
C4H8
What is the sum of the coefficients for the equation when balanced using the smallest possible whole numbers?
__ N2H4(g) + __ O2(g) → __NO2(g) + __ H2O(g)
5
6
7
8
A piece of metallic aluminium with a mass of 10.044 g was found to have a volume of 3.70 cm3. A student carried out the following calculation to determine the density.
Density (gcm−3) = 10.044 / 3.70
What is the best value the student could report for the density of aluminium?
2.715 gcm−3
2.7 gcm−3
2.71 gcm−3
2.7146 gcm−3
Which contains the greatest mass of chloride ions?
0.3 mol NaCl
0.2 mol CaCl2
0.1 mol FeCl3
0.1 mol ZnCl2
What is the formula for the compound formed by calcium and nitrogen?
CaN
Ca2N
Ca2N3
Ca3N2
The electron arrangement of sodium is 1s22s22p63s1. How many occupied main electron energy levels are there in an atom of sodium?
1
3
10
11
How many protons, neutrons and electrons are there in the species 26Mg2+ ?
10 protons, 14 neutrons, 12 electrons
12 protons, 14 neutrons, 10 electrons
12 protons, 26 neutrons, 10 electrons
14 protons, 12 neutrons, 12 electrons
Which is the correct description of polarity in F2 and HF molecules?
Both molecules contain a polar bond.
Neither molecule contains a polar bond.
Both molecules are polar.
Only one of the molecules is polar.
1s22s22p63s23p64s23d10
1s22s22p63s2
Is this molecule polar or nonpolar?
polar
nonpolar
How many moles of water can be produced if 8 moles H2 are used?
What is the molecular shape and the hybridization of the nitrogen atom in NH3 ?
Molecular shape: tetrahedral
Hybridization: sp3
Molecular shape: trigonal planar
Hybridization: sp2
Molecular shape: trigonal pyramidal
Hybridization: sp2
Molecular shape: trigonal pyramidal
Hybridization: sp3
Which statement about sigma and pi bonds is correct?
Sigma bonds are formed only by s orbitals and pi bonds are formed only by p orbitals.
Sigma bonds are formed only by p orbitals and pi bonds are formed only by s orbitals.
Sigma bonds are formed by either s or p orbitals, pi bonds are formed only by p orbitals.
Sigma and pi bonds are formed by either s or p orbitals.
What type of bonding occurs between the metal ion and ligand in the complex ion
[Cu(H2O)6]2+?
metallic
ionic
hydrogen
dative covalent
Which is an essential feature of a ligand?
a negative charge
an odd number of electrons
the presence of two or more atoms
the presence of a non-bonding pair of electrons
The relative first ionisation energies of four elements with consecutive atomic numbers below 20 are shown on the graph.
One of the elements reacts with hydrogen to form a covalent compound with formula HX. Which element could be X?
A
B
C
D
Which of the following elements would have it's largest jump in successive ionization energies between removing it's 3rd and 4th electron?
Sodium
Aluminum
Phosphorous
Chlorine
The hybridization of the sulfur atom in XeF4 can best be described as:
sp3d2
sp3d1
sp3
sp2
Which statements are correct for ionic compounds?
I. Lattice energy increases as ionic radii increase.
II. Within the same group, the melting point of salts tends to decrease as the radius of the cation increases.
III. Solubility in water depends on the relative magnitude of the lattice energy compared to the hydration energy.
I and II only
I and III only
II and III only
II and III only
Which combination describes the PH4+ ion?
Tetrahedral; sp3 hybridization
Square Planar, sp3 hybridization
Tetrahedral, sp2 hybridization
Square Planar, sp2 hybridization
Which species have resonance structures?
I. Ozone, O3
II. Carbon dioxide, CO2
III. Benzene, C6H6
I and II only
I and III only
II and III only
I, II and III
Which does not show resonance?
PO43–
C6H6
C6H12
O3
Which is the first step in the CFC-catalysed destruction of ozone in UV light?
CCl2F2 → CClF2+ + Cl–
CCl2F2 → •CClF2 + Cl•
CCl2F2 → CCl2F+ + F–
CCl2F2 → •CCl2F + F•
Which statement is correct?
Sigma bonds are formed only by the combination of s atomic orbitals.
Pi bonds can be formed in the absence of sigma bonds.
Pi bonds are formed parallel to the axis between atoms.
Pi bonds are formed only by the combination of hybrid orbitals.
Ammonia is a stronger ligand than water. Which is correct when concentrated aqueous ammonia solution is added to dilute aqueous copper(II) sulfate solution?
The d-orbitals in the copper ion split.
There is a smaller splitting of the d-orbitals.
Ammonia replaces water as a ligand.
The colour of the solution fades.
What is the correct explanation for the colour of [Cu(H2O)6]2+?
Light is absorbed when an electron moves to a d orbital of higher energy.
Light is released when an electron moves to a d orbital of higher energy.
Light is absorbed when electrons move from the ligands to the central metal ion.
Light is absorbed when electrons move between d and s orbitals.
Which best explains why transition metal complexes are coloured?
As electrons return to lower energy levels, light of a certain colour is emitted, and the complementary colour is observed.
As electrons return to lower energy levels, light of a certain colour is emitted, so the complex appears to have the same colour.
As electrons are promoted to higher energy levels, light of a certain colour is absorbed, and the complementary colour is observed.
As electrons are promoted to higher energy levels, light of a certain colour is absorbed, so the complex appears to have the same colour.
Which species breaks the octet rule?
PCl3
BF4−
SCl4
NH4+
In which group do both compounds contain delocalized electrons?
C6H10, C5H10
Na2CO3, NaOH
NaHCO3, C6H6
NaHCO3, C6H12
Which species has bond angles of 90°?
AlCl4-
ICl4-
NH4+
SiCl4
Which ionic compound has the largest value of lattice enthalpy?
MgS
MgO
CaBr2
NaF
