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AP Chemistry Thou Shall Not Forget- Part 2

Total questions: 58

Worksheet time: 26mins

Name
Class
Date
1.

What type of alloy is made when the radii of the atoms are similar in size?

a)

interstitial

b)

substitutional

2.

This is a representation of a hydrogen bond.

a)

True

b)

False

3.

This is a representation of a hydrogen bond.

a)

True

b)

False

4.

Which atom has the negative dipole in this molecule?

a)

Hydrogen

b)

Fluorine

c)

Neither

5.

In this molecule, Carbon has a formal charge of ____ and Nitrogen has a formal charge of _____.

a)

0, 0

b)

1, 0

c)

0, -1

d)

-1, 0

6.

What is the formula for calculating % yield?

a)

actual/theoretical *100

b)

theoretical/actual *100

7.

What is a limiting reactant?

a)

The reactant that runs out first

b)

The reactant that has the lowest mass

c)

The reactant with the smallest coefficient

d)

The reactant with the lowest molar mass

8.

Combustion reactions produce what two substances?

a)

Water Vapor and Carbon Dioxide

b)

Carbon Dioxide and Oxygen

c)

Oxygen and Water Vapor

9.

As the electronegativity difference between 2 atoms increases, the polarity of the bond ____________________

a)

increases

b)

decreases

10.

What type of bond forms between hydrogen and chlorine?

a)

polar covalent

b)

non-polar covalent

c)

ionic

d)

hydrogen bond

11.

What type of alloy is this?

a)

Interstitial

b)

Substitutional

12.

dRT/P equals what quantity?

a)

Molar mass

b)

Volume

c)

Vapor pressure

d)

Mass

13.

What is the unit for the rate constant (k) for 1st order reactions?

a)

s-1

b)

M/s

c)

M-1s-1

14.

What is the oxidation number of P in PO43-?

a)

0

b)

4

c)

5

d)

-2

15.

What formula do we use for dilution calculations?

a)

M1V1=M2V2

b)

D=m/V

c)

V1=M2

d)

Total Volume/Partial Volume

16.

What order is this graph?

a)

Zero

b)

First

c)

Second

d)

Third

17.

What order is this graph?

a)

Zero

b)

First

c)

Second

d)

Third

18.

What is the oxidation number of N in NO21-?

a)

0

b)

-1

c)

2

d)

3

19.

The lewis structure on the ___________ is better because ________________

a)

left, formal charges are zero

b)

left, the formal charges equal -1

c)

right, formal charges are zero

d)

right, the formal charges equal -1

20.

If you quadruple the concentration and the rate quadruples, what order is this reaction?

a)

zero

b)

first

c)

second

21.

What is the electron configuration of Phosphorus?

a)

1s2 2s2 2p6 3s2 3p3

b)

1s2 2s2 2p6 3s2

c)

1s2 2s2 2p6 3s2 4p3

d)

1s2 2s2 2p6 3s2 3p5

22.

Which step of a reaction mechanism determines the rate?

a)

the slow step

b)

the fast step

c)

the first step

d)

the second step

23.

What order is the half life of Carbon14?

a)

Zero

b)

First

c)

Second

24.

1.What type of reaction is this?

3O2 + 2FeCl3 --> 2Fe2O3 + 3Cl2

a)

Single Displacement

b)

Decomposition

c)

Double Displacement

d)

Combustion

25.

What is the unit for the rate constant (k) for 2nd order reactions?

a)

s-1

b)

M/s

c)

M-1s-1

26.

How does a catalyst speed up a reaction?

a)

Adding more reactant

b)

Lowering the activation energy

c)

Increasing the activation energy

d)

Increasing binding energy

27.

___________ are produced in one step and used up in a later step and __________________ are present and unchanged in the reactants and the products

a)

intermediates, catalysts

b)

catalysts, intermediates

28.

If a “reaction profile” has a taller ‘hill’ (or activation energy) then the reaction is ____________________?

a)

Faster

b)

Slower

29.

What is the half life equation for a first order reaction?

a)

.693/k

b)

t-k

c)

k/.693

d)

rate = k[A]

30.

What are the 2 characteristics that an effective collision must have? SELECT TWO

a)

Enough energy to overcome Ea

b)

Molecules in the correct orientations

c)

High enough temperature

d)

Apporpriate intermediates present

31.

What is the rate law for the reaction with this slow elementary step? A + A --> B + B

a)

rate = k[A]2

b)

rate = k[B]2

c)

rate = k[A][B]

d)

rate = k[A]

32.

What is the rate law for the reaction with this slow elementary step? A --> B + C

a)

rate = k[A]2

b)

rate = k[B]2

c)

rate = k[A][B]

d)

rate = k[A]

33.

What is the rate law for the reaction with this slow elementary step? A + 2B --> D + C

a)

rate = k[A]2

b)

rate = k[A][B]2

c)

rate = k[A][B]

d)

rate = k[A]

34.

What is NOT a way to speed up a reaction

a)

Add a catalyst

b)

Decrease the volume

c)

Increase the concentration of reactants

d)

Increase surface area of the solid

e)

Decrease the pressure

35.

Which curve represents the most particles in this Maxwell-Boltzmann curve (# of particles vs. speed)?

a)

Black (peak on the left)

b)

Red (peak in the middle)

c)

Blue (peak on the right)

d)

They all have the same number of particles

36.

Which curve in this Maxwell-Boltzmann distribution represents the highest proportion of particles moving the fastest (# of particles vs. speed)?

a)

Black (peak on the left)

b)

Red (peak in the middle)

c)

Blue (peak on the right)

d)

All particles are moving at the same speed

37.

Which curve in this Maxwell-Boltzmann distribution would represent the a gas with the highest molar mass?

a)

Black (peak on the left)

b)

Red (peak in the middle)

c)

Blue (peak on the right)

38.

What order of reaction has a half-life that does not change regardless of the initial concentration?

a)

Zero

b)

First

c)

Second

d)

Third

39.

Losing electrons is ________________, gaining electrons is ________________

a)

oxidation, reduction

b)

reduction, oxidation

40.

In an exothermic reaction, the sign of ΔH is ____ and the reaction feels ______

a)

(-), hot

b)

(+), hot

c)

(-), cold

d)

(+), cold

41.

In an endothermic reaction, the sign of ΔH is ____ and the reaction feels ______

a)

(-), hot

b)

(+), hot

c)

(-), cold

d)

(+), cold

42.

Freezing is an _________________________ process

a)

Endothermic

b)

Exothermic

43.

Vaporizing is an _________________________ process

a)

Endothermic

b)

Exothermic

44.

What are the coefficients?

a)

1; 2; 1; 2

b)

2; 1; 2; 1

c)

4; 2; 1; 4

d)

1; 4; 2; 2

45.

Breaking bonds is _________________. Forming bonds is ______________________

a)

endothermic, exothermic

b)

exothermic, endothermic

46.

ΔHrxn = ΔH_________________ − ΔH_________________

a)

products, reactants

b)

reactants, products

47.

According to Hess' Law, if you double the coefficients of a reaction, ΔH will ________________________

a)

Stay the same

b)

Double

c)

Quadruple

d)

Halve

48.

According to Hess' Law, if you reverse a reaction, ΔH will ________________________

a)

Change signs

b)

Double

c)

Be inversed

d)

Halve

49.

_____ Hydrogen-Hydrogen single bond/s are broken and _____ Carbon-Hydrogen single bond/s formed

a)

6; 8

b)

2; 8

c)

2; 10

d)

6; 10

50.

_____ Carbon-Carbon single bond/s are formed

a)

6

b)

2

c)

3

d)

10

51.

Bond enthalpy is the amount of energy is takes to break __________ of a bond.

a)

one mole

b)

one gram

c)

the activation energy

d)

the binding energy

52.

This reaction is ____________________ because energy is _____________

a)

endothemic, absorbed

b)

exothermic, released

c)

endothermic, absorbed

d)

endothermic, released

53.

There are two Carbon(graphite) in the final equation. We should ________ the ΔH of the first sub-reaction.

a)

Double

b)

Halve

c)

Take the inverse of

d)

Reverse the sign of

54.

We need to reverse one of the equations.

a)

True

b)

False

55.

Heat is measure in K or °C

a)

True

b)

False

56.

The particles under the purple curve (middle) have an average Kinetic Energy of 500K

a)

True

b)

False

57.

The particles under the purple curve (middle) all have a temperature of 500K

a)

True

b)

False

58.

What are the units of ΔHrxn?

a)

kJ

b)

J

c)

kJ/mol

d)

J/mol