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Quizz 12

Total questions: 124

Worksheet time: 45mins

Name
Class
Date
1.

Q2. The melting and boiling point along 2nd and 3rd period

a)

A. Increases from left to right

b)

B. Decrease from left to right

c)

C. increases upto group IVA and then decreases

d)

D. decreases up to group IV A and then increases

2.

Q.11 Which pair of transition elements shows abnormal electronic configuration?

a)

A. Sc and Zn

b)

C. Cu and Sc

c)

B. Zn and Cu

d)

D. Cu and Cr

3.

Q.12 In which of the following pairs, the radius of the second atom is smaller than that of the first atom

a)

A. Mg, Na

b)

B. Sr, Ca

c)

C. N, P

d)

D. Cl, Br

4.

Q.13 Which property of the first six continuously increases numerically?

a)

A. Atomic radius

b)

C. First ionization energy

c)

B.Maximum oxidation state in oxide

d)

D. Melting point

5.

highest oxidation state of manganese is

a)

+7

b)

-7

c)

+6

d)

+4

6.

highest oxidation state in all transition elements is

a)

+8

b)

+7

c)

+5

d)

+1

7.

which of the foloowing are responsible for the color developed in transition metal compounds?

a)

s - orbital

b)

p orbital

c)

d - orbital

d)

f - orbital

8.

all 3d elements show an oxidation state of

a)

+1

b)

+2

c)

+3

d)

0

9.

stability of Cu metal is due to ___ filling of d-orbital?

a)

half

b)

completely

c)

partially

d)

quarterly

10.

which of the elements has 7 electrons in d subshells?

a)

zn

b)

cobalt

c)

copper

d)

iron

11.

the element with the highest binding energy is

a)

V

b)

T

c)

So

d)

Cr

12.

Which pair of transition elements show abnormal eletronic configuration

a)

Copper and scandium

b)

Scandium and Zinc

c)

Zinc and copper

d)

Copper and chromium

13.

Transaction compounds which occur as try positive ions have no

a)

4s electron

b)

3p electrons

c)

3S electrons

d)

To a se electrons

14.

in (ti(h2o)3+ Which colour is transmitted

a)

Yellow

b)

Blue and red

c)

Blue and yellow

d)

Red and yellow

15.

Number of unpaired electrons are maximum in

a)

V + 3

b)

MN + 2

c)

Fe + 3

d)

cr + 3

16.

When light is exposed to a Transition Element then the electrons jump from lower orbitals to higher orbitals in

a)

Orbitals of s subshell

b)

Orbitals of d subshell

c)

Orbitals of P sub shell

d)

Orbitals of different shelles

17.

Which of the following D blocks element and show the highest oxidation number in its compounds

a)

Chromium

b)

Manganese

c)

Copper

d)

Iron

18.

Oxidation state of transition elements is usually

a)

Variable

b)

Single

c)

Constant

d)

Infinite

19.

At which Oxidation State copper achieves electronic configuration of zinc + 2

a)

00

b)

+ 2

c)

+ 1

d)

+ 3

20.

Which of the following is a typical transition metal

a)

Scandium

b)

yttrium

c)

Radium

d)

Cobalt

21.

Which of the following is a non typical transition metal

a)

Chromium

b)

Zinc

c)

Manganese

d)

Iron

22.

What is the sequence of electron pick up and removal from the 4S orbital in a transition metal in the 3D seroes

a)

Enter first and leaves after 3D electrons removal

b)

Enters after 3D electrons leaves after 3D electrons

c)

Enters after 3d electrons leaves first

d)

Enters first leaves first

23.

Which one pair has the same Oxidation State of iron

a)

Feso4 and fecl4

b)

Fecl4 and fecl3

c)

Fe2so43 and feso4

d)

Feso4 and fecl2

24.

The number of unpaired electrons present in fe ions is

a)

+1

b)

+2

c)

+5

d)

0

25.

Energy difference of D orbitals varies from

a)

Atom to atom

b)

ion to ion

c)

electron to electron

d)

Proton to proton

26.

And the electronic configuration of chromium one electron from 4S subtitle is transferred to three D subshell because

a)

The half filled 3D subshell is more stable than the four electrons having d subshell

b)

The 3D orbital is of lower energy than 4S

c)

The 4S orbital is of equal energy to 3D orbital

d)

6 unpaired electrons make chromium more paramagnetic

27.

Stability of copper metal is due to the filling of the orbital

a)

Half

b)

Completely

c)

Partially

d)

Quarterly

28.

Which of the following pair has the same number of electrons in the d subshell

a)

SC + 3, ti+3

b)

MN + 2., fe + 3

c)

Ti + 3, V + 3

d)

CR + 3. Co + 2

29.

Which of the following compound is expected to be coloured

a)

Na2so4

b)

Zncl2

c)

Mgf2

d)

Cuf2

30.

which one of the following is the correct geometry of (mncl4)-2

a)

square planar

b)

trigonal bipyramid

c)

tetrahedral

d)

octahedral

31.

Which of the following has a complete D subshell in cationic as well as atomic state

a)

zinc

b)

Titanium

c)

Manganese

d)

Scandium

32.

Zinc has

a)

Zero unpaired electrons

b)

5 unpaired electrons

c)

3 unpaired electrons

d)

One unpaired electron

33.

DD transition cannot be observed in

a)

Chromium

b)

Copper

c)

Manganese

d)

zinc

34.

The location of transition elements is between

a)

Lanthanides and actinides

b)

Chalcogens and halogens

c)

S and p block elements

d)

D and f block elements

35.

Which one of these possesses maximum number of unpaid electrons

a)

MN + 2

b)

CU + 2

c)

Fe + 3

d)

Both MN + 2 and fe + 3

36.

The correct electronic configuration of MN is

a)

(ar) 3d3 4s2

b)

(ar) 3d4 4s2

c)

(ar) 3d 4s2

d)

(ar) 3d5 4s2

37.

Oxidation number of Manganese in (MnO4 ) -2

a)

+ 7

b)

7

c)

+ 6

d)

-6

38.

The element which gains electronic configuration of a noble gass at + 3 oxidation state is

a)

Vanadium

b)

Scandium

c)

Titanium

d)

Chromium

39.

In complex compounds the oxidation number

a)

greek numerals

b)

English

c)

Latin

d)

Roman

40.

The oxidation number of Central metal atom in (ni(co)4)

a)

0

b)

2

c)

4

d)

6

41.

Which Complex show zero Oxidation state of the transition metal?

a)

(fe(co)5)

b)

(k3(fe(cn)6)

c)

(k3(fe(cn)5)

d)

(cu(nh3)4)so4

42.

Zinc does not show variable oxidation

a)

Its D subShell is incomplete

b)

It's d subshell is complete

c)

Its relatively soft metal

d)

It has to electrons in its outermost shell

43.

At which Oxidation state does copper achieve a noble gas configuration

a)

0

b)

+1

c)

+2

d)

+3

44.

Number of electrons involved in DD transition of (ti(h2o)3+

a)

1

b)

2

c)

3

d)

4

45.

The colour transition metal complexes is due to

a)

DD transition

b)

Ionization

c)

Paramagnetic nature of transition elements

d)

Loss of electron

46.

Which of the following compounds is expected to be the catalyst for manufacturing of plastics

a)

V2o5

b)

Cr2o3

c)

Ticl 4

d)

Ethanol

47.

the compound which has a ring in its structure is called

a)

chelate

b)

monodenatte

c)

ligand

d)

hydrate

48.

k2(cu(cn)4) which one is correct

a)

potassium tetra cyano cupperate

b)

ligand is positibely charged

c)

co-ordination number is 2

d)

central atom is part of anionic sphere

49.

the geometry of (fe(co)5) is

a)

pyramidal

b)

octahedral

c)

bi pyramidal

d)

square planar

50.

What is the nature of coordination sphere

a)

Anionic

b)

cationic

c)

neutral

d)

all

51.

sum of the charges present of the central metal atom ion and the charge on the ligandsis called

a)

Coordination number

b)

Coordination sphere

c)

Oxidation number

d)

Charge on coordination sphere

52.

Which transition metal cells as a catalyst for oxidation of alkanes

a)

Cobalt

b)

Copper

c)

Zinc

d)

Iron

53.

The catalyticability of transition metals comes from

a)

Vacant D orbitals

b)

Vacant p subshell

c)

High charge density of cations

d)

Variable valency

54.

which electronic configuration can have the possibility of A Plus 7 Oxidation State

a)

(ar) 3d5 4s2

b)

(ar) 3d6 4s 2

c)

(ar) 3d5 4s1

d)

(ar) 3d10 4s2

55.

Which of the following shows only +2 oxidation state

a)

Scandium

b)

Copper

c)

Zinc

d)

Cobalt

56.

the octahedral geometry of complexes (co(nh3)6) 3+ has hybridization

a)

sp3d

b)

sp3d2

c)

spd4

d)

sp2d3

57.

copper is a transition metal. its atomic number is 29. in which oxidation state does it have a partially filled orbital in d subshell?

a)

Cu

b)

Cu2+

c)

Cu+

d)

Cu-

58.

the anomalous E of cu and cr is due to

a)

color of ions of the metals

b)

variable valency

c)

stability associated with the EC

d)

tendency to form complex formation

59.

the paramagnetic behaviour is due to presence of

a)

bond pairs

b)

lone pairs

c)

unpaired electrons

d)

paired electrons

60.

which has the same charge on central metal atom as coordination sphere?

a)

k4(fe(cn6)

b)

(co(no2)2(nh3)3)

c)

(cu(nh3)4)so4

d)

(mncl4)-2

61.

the IUPAC name of na3(co(no2)6) is

a)

sodium hexanitroso cobaltate (III)

b)

sodium cobaltnitrate III

c)

sodium hexanitro cobalt III

d)

sodium hexa nitro cobaltate III

62.

potassium dichrometae is used as an oxidizing agent in redox titrations. during reactions Cr(VI) and Cr(III). the color shift is

a)

green to colorless

b)

colorless to pink

c)

pink to colorless

d)

orange to green

63.

the geometry of complexes depends upon the type of ___ taking place in the valence shell of tge central metal atom

a)

protonation

b)

hybridization

c)

deprotonation

d)

dissociation

64.

oxidation state of Mn in KMno4 , K2 MnO4, MnO2, MnSO4

a)

7

6

2

4

b)

7

6

4

2

c)

6

7

2

4

d)

4

6

7

2

65.

the total number of transition elements is

a)

58

b)

30

c)

48

d)

25

66.

valence shell ec of Cu2+ is

a)

5d6

b)

3d9

c)

3d8

d)

3d7

67.

what is the color of Zn+2, Ti+4 ?

a)

green, orange

b)

pink

c)

colorless

d)

deep green, blue

68.

18. f orbital hybridization. Which of the following type of orbital hybridization shows square planar geometry?

a)

A) sp3

b)

B) dsp2

c)

C) dsp3

d)

D) d2sp3

69.

4. Which of the following is the correct electronic configuration of gold (atomic number of Au = 79)?

a)

A) [54 Xe] 4f14 5d10 6s1

b)

B) [54 Xe] 4f14 5d° 6s?

c)

C) [54 Xe]4f14 5d9 6s2

d)

D) [s4 Xe]4fı 5d10 6s2

70.

3. Mark the incorrect statement about transition elements of 3d-series:

a)

A) All the elements show +2 oxidation state

b)

B) They show variable oxidation because of the involvement of the unpaired d-electrons in addition to s-electrons

c)

C) Fe+3 ion is more stable than Fe+2 ion

d)

D) First four elements in the highest oxidation state use all of the s and d electrons for bonding

71.

2. All of the following transition elements show variable oxidation state EXCEPT:

a)

fe

b)

cr

c)

zn

d)

cu

72.

1. Which of the following is correct formula for general electronic configuration of d-block elements?

a)

A) (n-1)d1-10ns 1-2

b)

B) (n-1)d 10 ns2

c)

C) (n-1)d1-5 ns 1-2

d)

D) (n-1)d1-10 ns2

73.

8. Correct name of [Pt(OH)2(NH2)4]SO4 is:

a)

A) Tetraammine dihydroxo-platinum (IV) sulphate

b)

B) Dihydroxo tetraammine-platinum (V) sulphate

c)

C) Tetra-ammine dihydroxo-platinum (II) sulphate

d)

D) Dihydroxo tetraammine-platinum (IV) sulphate

74.

7. Transition elements mostly show

a)

A) Linear

b)

B) Trigonal bipyramid

c)

C) Square planar

d)

D) Octahedral

75.

6. Which of the following complex ions shows tetrahedral geometry?

a)

A) [MnCl4]2

b)

B) [Cu(NH3)4]+2

c)

C) [Fe(CN)6]4

d)

D) [Tf6]-2

76.

5. Transition elements show all of the following characteristic properties EXCEPT:

a)

A) They are good conductor of heat and electricity

b)

B) Those metals which form coloured compounds must have at least one unpaired electron in d-sub shell

c)

C) Their ions and compounds are coloured in the solid state only

d)

D) They act as a catalyst

77.

choose the ossible geometries for complexes with coordination number 6

a)

octahedral

b)

tetragonal

c)

square planar geometry

d)

trigonal prism

e)

linear

78.

14. Which of the following 3d-series elements shows the highest oxidation state in its compounds?

a)

A) Cr

b)

B) Cu

c)

C) Zn

d)

D) Fe

79.

13. 3d-series of transition elements contains elements in the range:

a)

A) Sc --- Zn

b)

B) La --- Hf

c)

C) Y ------Cd

d)

D) Ce ---- Lu

80.

12. The catalysts used for the following processes are correctly matched EXCEPT:

a)

A.

b)

B.

c)

C.

d)

D.

81.

11. In [Ti(H2O)6)]3+, ____ light is absorbed, while most of the blue and red lights are transmitted, therefore the solution of [Ti(H2O)6]3+ ions looks violet in colour. Violet is a complementary colour of yellow

a)

yellow

b)

green

c)

blue

d)

red

82.

10. In copper sulphate pentahydrate (CuSO4.5H2O), the number of water molecules attached with Cu+2 ion through coordinate covalent bond is:

a)

2

b)

3

c)

4

d)

5

83.

Which of the following transition elements has maximum number of unpaired electrons in its ground state?

a)

A) Mn

b)

B) Cr

c)

C) Fe

d)

D) Ni

84.

17. All of the following are monodentate ligands EXCEPT:

a)

A) OH

b)

B) CN

c)

C) CO

d)

D) N2H4

85.

16. The number of lone pair of electrons provided by the ligands to the central transition metal atom or ion is called:

a)

A) Oxidation number

b)

B) Coordination number

c)

C) Effective atomic number

d)

D) Coordination complex.

86.

15. Which of the following transition metal ions has five unpaired electrons in 3d sub-shell?

a)

A) Zn*2

b)

B) Sc+3

c)

C) Mn+2

d)

D) Cr+3

87.

37.In an octahedral geometry having coordination number 6, which of the following shows trans-position:

a)

A) 1-2

b)

B) 1-3

c)

C) 3-4

d)

D) 1-4

88.

22. Elements of 3d-series generally show which of the following stable oxidation states?

a)

A) +1, +2

b)

B) +2, +3

c)

C) +4, +5

d)

D) +6, +7

89.

21. Which of the following elements are used as a catalyst in the chemical reactions?

a)

A) Alkali metals

b)

B) Transition elements

c)

C) Alkaline earth metal

d)

D) Element which form border line compounds

90.

23. The correct formula of Tetraammine aqua bromocobalt (III) nitrate is:

a)

A) Co[Br(NH3)4(H2O)](NO3)2

b)

B) Co[Br(NH3)4(H2O)Br](NO3)2

c)

C) Co[Br(H2O)(NH3)4] (NO3)2

d)

D) Co[(NO)(NH3)4(H2O)Br](NO3)2

91.

24. Pair of transition elements which show abnormal electronic configuration in the first 3d-series are:

a)

A) Cr and Ni

b)

B) Fe and Ni

c)

C) Cr and Cu

d)

D) Cu and Co

92.

26. The central transition metal atom along with ligands is called:

a)

A) Complex ion

b)

B) Ligand

c)

C) Coordination sphere

d)

D) Complex compound

93.

28. Transition elements show all of the following properties EXCEPT:

a)

A) They are all metals in true sense

b)

B) They show variable oxidation state

c)

C) They have high melting and boiling points

d)

D) Their ionization energy is less than that of IIA group elements.

94.

29. Which of the following statements is correct about covalent radii in 3d-series of transition elements?

a)

A) It decreases continuously

b)

B) First it decreases then increases rapidly

c)

C) First it decreases in the start, constant in the middle and then increases at the end of series

d)

D) It remains almost constant in the series

95.

31. Which groups of transition elements are known as non-typical transition elements?

a)

A) IIB and IIIB

b)

B) IB and IVB

c)

C) IVB and VB

d)

D) VIB and VIIB

96.

30. In moving from left to right in any transition series, the number of unpaired electrons increases upto groups:

a)

A) IIB and IIIB

b)

B) IVB and VB

c)

C) VB and VIB

d)

D) VIB and VIIB

97.

32. All of the following non-metals enter in the interstices of transition metals and impart useful features to them EXCEPT:

a)

A) H

b)

B) B

c)

C) N

d)

D) Br

98.

34. Which of the following transition metal ions shows the strongest paramagnetic behaviour?

a)

Fe+3

b)

Fe+2

c)

Mn+2

d)

Fe+1

99.

33. Mark the incorrect statement about the general characteristic features of 3d-series of transition metals:

a)

A) Binding energy depends on unpaired electrons

b)

B) M.Ps and B.Ps show irregular trend in 3d-series

c)

C) Diamagnetic substances are weekly repelled by the strong magnetic field

d)

D) lonic radii, changes in the ionic radii along the series are regular

100.

35. In alloy steels (substitutional alloys), which of the following transition metal cannot be substituted in place of iron:

a)

A) Cr

b)

B) Ni

c)

C) Mn

d)

D) Ti

101.

36. The type of structural isomerism which occurs when the counter ion (the ion outside the square bracket) is itself a potential ligand:

a)

A) lonization isomerism

b)

B) Coordination isomerism

c)

C) Coordination isomerism

d)

D) Solvate isomerism

102.

38. Coordination compounds show which of the following principal types of isomerism:

a)

A) Stereoisomerism

b)

B) Structural isomerism

c)

C) Both A and B,

d)

D) Neither A nor B

103.

8. In which compound, the oxidation state of Mn is highest:


a)

KMnO4

b)

MnO

c)

MnO2

d)

K2MnO4

104.

In pig iron the concentration of C-atom is


a)

0.12 --- 0.25%


b)

2.5 --- 4.5%


c)

2.0 --- 4.0%


d)

0.25 --- 2.5%

105.

When an active metal like Al comes in contact with less active element like Cu then it produces


a)

A.dry cell

b)

B.galvanic cell

c)

C.electrolytic cell

d)

D.a and b

106.

color of ni +2?

a)

green

b)

yellow

c)

pink

d)

blue

107.

color of ferrous and ferric ion?

a)

green, blue

b)

green, yellow

c)

yellow, green

d)

green, orage

108.

color of cu+2?

a)

blue

b)

pink

c)

red

d)

green

109.

color of V+3?

a)

green

b)

blue

c)

red

d)

pink

110.

color of cobalt +2

a)

pink

b)

yellow

c)

green

d)

blue

111.

what color is shown by Cr+3

a)

green

b)

blue

c)

colorless

d)

pink

112.

Group VIB of transition elements contains

a)

A) Fe, Ru, Os

b)

B) Mn, Te, Re

c)

C) Zn, Cd, Hg

d)

D) Cr, Mo, W    

113.

Type of hybridization in PCl5 is:

a)

sp3

b)

dsp3

c)

sp2

d)

dsp2

114.

The trace metal present in insulin is:

a)

iron

b)

zinc

c)

copper

d)

manganese

115.

4. Which of the following cation has maximum unpaired electrons:


a)

NI+2

b)

co+2

c)

Mn+2

d)

Fe+2

116.

The black image on an exposed and developed photographic film is composed of:


a)

Ag

b)

AgBr

c)

Ag[(SrO3)2]–

d)

Ag2O

117.

Iron obtained from blast furnace is known as

a)

Cast iron

b)

pig iron

c)

wrought iron

d)

steel

118.

lanthanides and actinides resemble in?


a)

Oxidation state

b)

electronic configuration

c)

Formation of complexes

d)

ionization state

119.

sodium thiosulphate is used in photography because of its

a)

reducing nature

b)

oxidizing nature

c)

complex forming behaviors

d)

reaction with light

120.

pure form of iron is

a)

grey iron

b)

wrought uron

c)

steel cast iron

d)

white cast iron

121.

one of the constituents of german silver is

a)

cu

b)

al

c)

ag

d)

mg

122.

Which one of these has the lowest % of carbon

a)

cast iron

b)

steel

c)

wrought iron

d)

all have the same percentage

123.

galvanization is deposition

a)

of zn on fe

b)

of ti on fe

c)

of al on fe

d)

ON FU ON FE

124.

matte is an impure substance of

a)

copper

b)

al

c)

zinc

d)

fe