Worksheetschem organic hw2
Total questions: 151
Worksheet time: 3hrs 46mins
What is a functional group?
Group of atoms that give specific characteristics to a molecule
Group of molecules that give specific characteristics to an atom
Group of molecules that make up a group of atoms
Group of atoms that give specific characteristics to an element
What functional group is -OH
Hydroxyl
Carboxyl
Amino
Carbonyl Ketone
Classify the compound based on the functional group present.
alkane
alkene
alkyne
Identify the functional groups present in this compound.
amine
amide
ether
ester
hydroxyl group
amine group
Isomers are organic compounds having same ______ formula and different _______ formula .
(a)
Every homologoue member differ by (a) group
Alkynes are (a) bonded compounds
Alkene are (a) compounds
The formula CH3 can represent an anion, a cation or a free radical. Species with molecular formula CH3 can act as an electrophile, a free radical or a nucleophile depending on the number of outer shell electrons on the central carbon atom. How many outer shell electrons must be present for CH3 to act in these different ways ?
A
B
C
D
Which diagram gives the skeletal formula of
2-chloropentan-3-ol ?
A
B
C
D
Which reaction is not an electrophilic addition ?
A
B
C
D
Which of these always applies to a nucleophile
A
B
C
D
Which molecules would be present in the mixture produced by the photochemical chlorination of methane ?
1) Hydrogen
2) Hydrogen Chloride
3) dichloromethane
A
B
C
D
A
B
C
D
A
B
C
D
Which pair of homologous series have the same C:H ratio in their general formula
1) Aldehydes and Ketones
2) Carboxylic acids and esters
3) Alkenes and Ketones
A
B
C
D
A
B
C
D
A
B
C
D
A
B
C
D
A
B
C
D
What functional group is found in the following molecule:
halide
hydroxide
carboxyl
amide
Which compound belongs to the alkene family?
C2H2
C2H4
C6H6
C6H14
Name the following molecule:
1,3-dimethyl-2-ethyl butan-1-ol
2,4-dimethyl-3-ethyl pentan-1-ol
2,4-dimethyl-3-ethyl butan-4-ol
3-ethyl-4-methyl pentan-2-ol
Name the following molecule:
3,3-dimethyl butan-1-ol
3,3-methyl butan-1-ol
2,2-dimethyl butan-4-ol
3,3,3-trimethyl propan-1-ol
A molecule of 2,3 dimethyl hexane would have how many TOTAL carbons?
6
7
8
9
Name this: (CH3)2CClCCl(CH3)2
2,3-dichloro-2,3-dimethybut-2-ene
3,4-dichlorohex-3-ene
3,4-dichlorohexane
2,3-dichloro-2,3-dimethylbutane
Name this organic molecule.
Name this organic molecule.
Name this organic molecule.
Name this organic molecule.
Name this organic molecule.
Name this organic molecule.
Name this organic molecule.
Name this organic molecule.
Name this organic molecule.
Name this organic molecule.
Name this organic molecule.
2-2,chloro butane
Where would amines be found in organic chemistry?
fat
carbohydrate
alcohol
protein
Select the correct name of the following formula. C6H11NH2
Hexanamine
Hexene
Hexenol
Hexenamine
React propanoic acid with NH3 to produce:
propanamine
methanamide
propanamide
N-propanamide
React propanoic acid with NH3 to produce:
propanamine
methanamide
propanamide
N-propanamide
Which reactants you need to obtain the compound in the image?
butanoic acid and methanamine
butanoic acid and ammonia
butanal and methanamine
butanoic acid and methanol
Oxidate heptanal to obtain:
heptanone
heptanoic acid
heptanol
heptene
Oxidate the compund in the image
pentanal
pentanoic acid
Not possible
3-pentanol
What is the IUPAC name of the product from the reaction of butanol and methanol?
methoxy butane
butanoic acid + H2O
1,5-pentanodiol
water
What is the product of the reduction of the compund in the image
3-methyl butanol
3-methyl-3-butanol
3-methyl butanoic acid
3-methyl butanone
Halogenate 2-pentene with bromine, what is the product?
pentane
2,3-dibromopentane
3,3-dibromopentane
2,2-dibromopentane
What kind of alcohol is obtained from the reduction of a ketone?
primary
tertiary
secondary
not possible
Hydrolyze heptyl propanoate to obtain:
propanol + heptanol
propanoic acid + H2O
propanal + heptanol
propanoic acid + heptanol
Dehydrate the compound in the image
2-butanone
1-butene
butanoic acid
2-butene
The product of reacting propene with hydrochloric acid (HCl) is:
2-chloropropane
2-chloropropene
2-chloropropyne
chloropropane
To produce the compound in the image
react 2-butene with HF
react 2-butyne with 2F2
react 2-butyne with 2HF
react 2-butene with 2F2
What is the product of partial hydrogenation of 3-hexyne?
3-hexene
hexanol
3-hexanol
hexane
a) What catalyst is needed for hydrogenation?
b) What is needed for halogenation?
a) Pt, Pd or Ni
b) UV ligth
a) H+
b) Heat
a) [O]
b) Heat
a) [-O]
b) H+
Which of the following is formed when an alcohol is dehydrated?
A. Aldehyde
B. Ketone
C. Alkene
D. Amine
The reaction of water with alkene to produce an alcohol is a/an ______ reaction.
A. Addition
B. Condensation
C. Combustion
D. Saponification
The organic starting materials for the preparation of an ester could be_________
A. a ketone and alcohol
B. water and oxygen
C. an acid and alcohol
D. alkane and aldehyde
Hydrolysis (saponification) of a fat would yield_____________.
A. water and alkene
B. ketone and aldehyde
C. ethanol and acid
D. glycerol and soap
This type of isomerism occurs when different compounds are formed due to the different arrangements of their atoms leading to different functional groups.
A. chain
B. functional
C. positional
D. geometric
What is the "ending" used in alcohols?
al
ol
oilo
alco
Select the correct name or names of the following structure
CH3-CH2-CH2-CH2-CH2-CH2-CH=O
Heptanaldehido
1 Heptanoal
7 Hetanoaldehido
Heptanal
What is the functional group of an ester ?
R-O=C
|
C-R'
R - C = O
|
O - R'
R-C=O
|
C
R-C=O
|
C-R'
Choose the correct option that represent the following structure
O
||
C-C-C-C-C-C-C
is a mistake
4 heptanona
heptanona
4 heptona
In the reaction, which answer represents the product X?
Reagent needed to change an alcohol to an alkene
concentrated H2SO4
KOH (alc)
water/dilute H2SO4
Cr2O72-/H+
Which reagent is needed to change CH3CH=CH2 to CH3CHClCH3
Cl2 (aq)
HCl
SOCl2
PCl3
Type of reaction (unbalanced).
CH3CH2OH → CH3COOH
oxidation
elimination
addition
substitution
What is the name of this compound?
ethanol
ethanal
ethanone
methanal
What is the name of this compound?
propan-2-al
propanane
propanone
propanal
Which compound is a structural isomer of Z-but-2-ene?
butane
E-but-2-ene
cyclobutane
methylbut-2-ene
Which equation is a propagation step in the conversion of trichloromethane into tetrachloromethane by reaction with chlorine in the presence of ultraviolet light?
CHCl3 + Cl2 ⟶ CCl4 + HCl
●CCl3 + ●Cl ⟶ CCl4
CHCl3 + ●Cl ⟶ CCl4 + ●H
●CCl3 + Cl2 ⟶ CCl4 + ●Cl
How many structural isomers are there with the molecular formula C3H6BrCl?
4
5
6
7
How many different alkenes are formed when 2-bromo-3-methylbutane reacts with ethanolic potassium hydroxide?
2
3
4
5
An organic compound is found to contain 40.0% carbon, 6.7% hydrogen and 53.3% oxygen.Which of the following compounds could this be?
Ethanol
Ethanoic acid
Methanol
Methanoic acid
Which one of the following mechanisms is not involved in the reaction sequence below?
CH3CH3 → CH3CH2Cl → CH3CH2OH → CH2=CH2 → CH3CH2Br
electrophilic addition
electrophilic substitution
nucleophilic substitution
free-radical substitution
What is the correct systematic name for
2-bromo-3-methylpent-2-ene
2-bromo-3-ethylbut-2-ene
3-bromo-2-ethylbut-2-ene
4-bromo-3-methylpent-3-ene
What is the correct systematic name for
2-ethyl-3,4-dimethylpent-2-ene
4-ethyl-2,3-dimethylpent-3-ene
2,3,4-trimethylhex-3-ene
3,4,5-trimethylhex-3-ene
Chlorination of alkanes is an example of
Elimination reaction
Free radical substitution reaction
Nucleophilic substitution reaction
Electrophilic addition reaction
Isomerism that arises out of the difference in spatial arrangement of atoms or groups about the doubly bonded carbon atoms are called?
Structural Isomerism
Stereoisomerism
Geometrical Isomerism
Optical Isomerism
Which among the following does not exhibit geometric isomerism?
1-hexene
2-hexene
3-hexene
4-hexene
Which of the following is NOT true about nucleophiles?
donates an electron pair to an electrophile to form a chemical bond
all molecules or ions with a free pair of electrons or at least one pi bond can act as nucleophiles
nucleophile are Lewis acids by definition
a nucleophile becomes attracted to a full or partial positive charge
Which of the following statement is INCORRECT about electrophiles?
Electrophiles are positively charged or neutral species having vacant orbitals
The electrophiles are attacked by the most electron-populated part of one nucleophile
Electrophiles are Lewis base
Two optical isomers have the same
Empirical formula
Structural formula
Molecular formula
Which three compounds form part of a homologous series?
A. C2H2, C2H4, C2H6
B. CH3OH, C2H5OH, C3H7OH
C. CH3CH2CH2CH2OH, CH3CH2CH(OH)CH3, CH3CH(CH3)CH2OH
D. CH3CH2CHO, CH3COCH3, CH3CH2CH2OH
4. Which of the following contribute to the low reactivity of alkanes?
I. The relatively strong C-H bond
II. The very low polarity of the C-H and C-C bonds
III. The tetrahedral shape of the molecules
A. I and II only
B. I and III only
C. II and III only
D. I, II and III
7. Which compound will be the major organic product when hydrogen bromide is added to but-1-ene?
A. 1-bromobutane
B. 2-bromobutane
C. 1,2-dibromobutane
D. 1,1-dibromobutane
Which functional groups are present in a molecule of the anti-oxidant shown above?
I. phenyl
II. ether
III. hydroxyl
A. I and II only
B. I and III only
C. II and III only
D. I, II and III
Which functional group is present in the compound with the structure above?
A. Amine.
B. Carboxamide
C. Ketone
D. Nitrile
What major type of organic reaction is this?
Addition Reaction
Elimination Reaction
Substitution Reaction
Rearrangement Reaction
What major type of organic reaction is this?
Addition Reaction
Elimination Reaction
Substitution Reaction
Rearrangement Reaction
What two organic reactions took place in this reaction?
Addition and Elimination Reactions
Addition and Rearrangement Reactions
Addition and Substitution Reactions
Elimination and Substitution Reactions
What major type of organic reaction is this?
Addition Reaction
Elimination Reaction
Substitution Reaction
Rearrangement Reaction
Name the following molecule:
3,3-dimethyl-1-butanol
3,3-methyl-1-butanol
2,2-dimethyl-4-butanol
3,3,3-trimethyl-1-propanol
Which is the name of this compound?
3-ethyl-2,2-dimethylhex-3-yne
4-ethyl-5,5-methylhex-2-yne
4-butylhex-2-yne
4-ethyl-5,5-dimethylhex-2-yne
